Asymmetric membranes of polytetrafluoroethylene and process for making
them
    74.
    发明授权
    Asymmetric membranes of polytetrafluoroethylene and process for making them 失效
    聚四氟乙烯的不对称膜及其制备方法

    公开(公告)号:US5653882A

    公开(公告)日:1997-08-05

    申请号:US440608

    申请日:1995-05-15

    Abstract: This invention relates to methods for preparing membranes of polyfluoroethylene (PTFE) and to the asymmetric membranes fabricated thereby. Such membranes are useful as separation and ultrafiltration membranes. The membranes are produced as a single layer. Method steps including contacting a substrate with a solution of PTFE in a perfluorinated cycloalkane solvent at a high temperature to cause a film of such solution to be coated on the substrate, removing the coated substrate from the solution and rapidly cooling it by contact with a second solvent, removing the coated substrate from the second solvent, drying the film, and optionally separating film from substrate.

    Abstract translation: 本发明涉及制备聚氟乙烯(PTFE)的膜的方法和由其制造的不对称膜。 这种膜可用作分离和超滤膜。 膜被制成单层。 方法步骤包括在高温下将基材与PTFE溶液在全氟化环烷烃溶剂中接触以使该溶液的膜涂覆在基材上,从溶液中除去涂覆的基材并通过与第二种 溶剂,从第二溶剂中除去涂覆的基材,干燥膜,以及任选地从基材上分离膜。

    Method for preparing microporous polyolefin shaped articles
    76.
    发明授权
    Method for preparing microporous polyolefin shaped articles 失效
    微孔聚烯烃成型制品的制备方法

    公开(公告)号:US5238623A

    公开(公告)日:1993-08-24

    申请号:US840291

    申请日:1992-02-24

    Abstract: A method for preparing a microporous polyolefin shaped article which includes the steps of (1) melt blending a polyolefin with an additive which is miscible with the polymer at the melt temperature of the blend but which phase separates on cooling to form a solution; (2) forming a shaped article from the solution; (3) cooling the shaped article by use of a patterned chill roll to provide areas on the surface of the article where the polymer mixture does not contact the chill roll; and (4) (a) removing at least a substantial portion of the compatible liquid; or (b) stretching the article in at least one direction sufficient to permanently attenuate the article and effect orientation of the polymer; or (c) a combination of (a) and (b) to form a microporous polyolefin shaped article. The article is of substantially uniform thickness and has a patterned surface. The patterned surface provides substantially skinless areas having high microporosity and skinned areas or reduced porosity.

    Abstract translation: 一种制备微孔聚烯烃成型制品的方法,其包括以下步骤:(1)将聚烯烃与在所述共混物的熔融温度下与所述聚合物混溶的添加剂熔融共混,但是所述相在冷却时分离形成溶液; (2)从溶液中形成成型制品; (3)通过使用图案化的冷却辊来冷却成形制品,以在制品的表面上提供聚合物混合物不接触冷却辊的区域; 和(4)(a)除去至少大部分的相容液体; 或(b)在足以使制品永久衰减并且影响聚合物取向的至少一个方向上拉伸制品; 或(c)(a)和(b)的组合以形成微孔聚烯烃成型制品。 该制品具有基本均匀的厚度并且具有图案化表面。 图案化的表面提供具有高微孔性和表皮区域或降低的孔隙率的基本上无皮肤区域。

    Microporous membranes of ultrahigh molecular weight polyethylene
    80.
    发明授权
    Microporous membranes of ultrahigh molecular weight polyethylene 失效
    超高分子量聚乙烯微孔膜

    公开(公告)号:US4828772A

    公开(公告)日:1989-05-09

    申请号:US192595

    申请日:1988-05-09

    Abstract: Microporous membranes and methods for producing such membranes from ultrahigh molecular weight polyethylene are described. The method employs extrusion of a solution of UHMW-PE and porogen through a forming die followed by thermal phase separation of polymer and porogen. Microporous structures are created by removing porogen. Microporous membranes produced include membranes with good permeability to air and water making them particularly useful as filtration media and water-resistance breathable membranes.

    Abstract translation: 描述了微孔膜和从超高分子量聚乙烯生产这种膜的方法。 该方法通过成形模挤出UHMW-PE和致孔剂溶液,然后热分解聚合物和致孔剂。 通过去除致孔剂产生微孔结构。 产生的微孔膜包括对空气和水具有良好渗透性的膜,使得它们特别用作过滤介质和耐水透气膜。

Patent Agency Ranking