公开(公告)号：KR1020050049124A

公开(公告)日：2005-05-25

申请号：KR1020030083004

申请日：2003-11-21

Applicant: 제일모직주식회사

Inventor： 강태곤 ,  임종철 ,  서경훈

IPC: C08L69/00

Abstract: 본 발명의 난연성 열가소성 수지조성물은 (A) 폴리카보네이트 수지 100 중량부; (B) 술폰산 금속염 0.01 내지 10 중량부; (C) 이산화티탄 100중량부에 대해서 알루미나(Al
2 O
3 )가 1% 이하로 표면개질된 특정 이산화티탄 2∼20 중량부; 및 (D) 평균 입자 크기가 0.05∼1000㎛이고, 밀도가 1.2∼2.3 g/㎤인 불소화 폴리올레핀계 수지 0.05∼5 중량부로 이루어지는 것을 특징으로 한다.

公开(公告)号：KR1020050034016A

公开(公告)日：2005-04-14

申请号：KR1020030069792

申请日：2003-10-08

Applicant: 제일모직주식회사

Inventor： 임종철 ,  서경훈 ,  소명섭

IPC: C08L69/00

Abstract: Provided is a flame retardant thermoplastic resin composition showing superior thermostability which uses specifically-treated rubber modified styrenes graft copolymer to improve thermostability of the resin composition largely, therefore it is useful in producing a computer housing requiring flame retardant property. The flame retardant thermoplastic resin composition showing superior thermostability comprises the components of:(A) 45-95wt% of polycarbonate resin;(B) 1-50wt% of specifically-treated rubber modified styrenes graft copolymer;(C) 0.5-50wt% of styrenes copolymer;(D) 1-30wt% of a phosphorous-series flame retardant agent; and (E) 0.05-5wt% of fluorinated polyolefins resin with 0.05-1000mum in average particle size and 1.2-2.3g/cm^3 in density by 100wt% of the sum of (A) to (D).

Abstract translation: 提供一种阻燃热塑性树脂组合物，其显示出优异的热稳定性，其使用特殊处理的橡胶改性苯乙烯接枝共聚物以大大改善树脂组合物的热稳定性，因此可用于生产需要阻燃性能的计算机外壳。 显示出优异的热稳定性的阻燃热塑性树脂组合物包括：（A）45-95重量％的聚碳酸酯树脂;（B）1-50重量％的经特殊处理的橡胶改性苯乙烯接枝共聚物;（C）0.5-50重量％ 苯乙烯共聚物;（D）1-30重量％的磷系阻燃剂; 和（E）0.05-5wt％的平均粒度为0.05-1000μm，密度为1.2-2.3g / cm 3的氟化聚烯烃树脂（A）至（D）的总和的100wt％。

公开(公告)号：KR100451838B1

公开(公告)日：2004-10-08

申请号：KR1020020006003

申请日：2002-02-02

Applicant: 제일모직주식회사

Inventor： 임종철 ,  홍상현 ,  양삼주

IPC: C08L69/00

Abstract: PURPOSE: Provided is a fire retardant polycarbonate-based resin composition which has excellent fire retardancy, mechanical strength, impact resistance, heat stability, workability, and appearance. CONSTITUTION: The composition comprises (A) 45-95 parts by weight of polycarbonate resin; (B) 1-50 parts by weight of rubber-modified vinyl graft copolymer; (C) 0-50 parts by weight of vinyl copolymer; (D) 1-25 parts by weight(based on the sum 100 parts by weight of the basic resin(A)+(B)+(C)) of mixture of organophosphorus compounds consisting of (d1) 1-60 wt% of cyclic phosphagen oligomer compound represented by formula 2 or a mixture thereof and 99-40 wt% of monomeric ester phosphate compound represented by formula 4 or mixture thereof(wherein R1 is any substituent of alkyl group, aryl group, alkyl-substituted aryl group, arylalkyl group, alkoxy group, aryloxy group, amino group, or hydroxyl group, k and m are 0, or an integer of 1-10, the alkoxy group or aryloxy group may be substituted with alkyl group, aryl group, amino group, or hydroxyl group, and so on, and R2 is C6-C30 dioxyaryl or alkyl-substituted C6-C30 dioxyaryl group derivative, n which represents a number of repeating unit is 0 or an integer of 1 or more, and an average value of n is 0.3-3, each of R3 and R4 is independently hydrogen atom, or an alkyl group such as methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, t-butyl, isobutyl, isoamyl, t-amyl, x is an integer of 1-3); and (E) 0.05-5 parts by weight (based on the sum 100 parts by weight of the basic resin(A)+(B)+(C)) of fluorinated polyolefin resin having an average particle size of 0.05-1,000 micrometer and a density of 1.2-2.3 g/cm¬3.

Abstract translation: 目的：提供具有优异的阻燃性，机械强度，耐冲击性，热稳定性，加工性和外观的阻燃聚碳酸酯基树脂组合物。 构成：该组合物包含（A）45-95重量份的聚碳酸酯树脂; （B）1-50重量份的橡胶改性的乙烯基接枝共聚物; （C）0-50重量份的乙烯基共聚物; （D）1-25重量份（基于100重量份碱性树脂（A）+（B）+（C））的有机磷化合物混合物的混合物，所述有机磷化合物由（d1）1-60重量％ 由式2表示的环状磷酸酯低聚物化合物或其混合物和99-40重量％由式4表示的单体磷酸酯化合物或其混合物（其中R1是烷基，芳基，烷基取代的芳基，芳基烷基 烷氧基，芳氧基，氨基或羟基，k和m为0或1-10的整数，烷氧基或芳氧基可以被烷基，芳基，氨基或羟基取代 基团等，并且R 2是C 6 -C 30二氧芳基或烷基取代的C 6 -C 30二氧芳基衍生物，表示重复单元的数目的n是0或1或更大的整数，并且n的平均值是0.3 -3，R 3和R 4各自独立地为氢原子或烷基如甲基，乙基，丙基，异丙基，丁基，仲丁基，t 丁基，异丁基，异戊基，叔戊基，x是1-3的整数）; 和（E）0.05-5重量份（基于100重量份的基础树脂（A）+（B）+（C））的平均粒径为0.05-1,000微米的氟化聚烯烃树脂和 密度为1.2-2.3g / cm 3; 3。

公开(公告)号：KR1020040061937A

公开(公告)日：2004-07-07

申请号：KR1020020088245

申请日：2002-12-31

Applicant: 제일모직주식회사

Inventor： 정인철 ,  이시춘 ,  임종철

IPC: C08L71/12 ,  C08K5/49

CPC classification number: C08L71/12 ,  C08J2300/22 ,  C08K5/523 ,  C08K5/5399 ,  C08L23/28 ,  C08L25/06 ,  C08L2201/02 ,  C08L2205/03

Abstract: PURPOSE: A flame retardant thermoplastic resin composition is provided, to improve the balance of flame retardancy, thermal stability, impact resistance, workability and appearance. CONSTITUTION: The thermoplastic resin composition comprises 100 parts by weight of a polyphenylene ether-based resin; 1-30 parts by weight of an organic phosphoric-based compound mixture which comprises 1-50 wt% of a cyclic phosphazene oligomer compound mixture comprising the cyclic phosphazene compounds of the formula I connected by a linking group having -R2- group and 50-99 wt% of a phosphoric acid ester compound of the formula II or a mixture of phosphoric acid ester compounds; 0.05-5 parts by weight of a fluorinated polyolefin-based resin having an average particle size of 0.05-1,000 micrometers and a density of 1.2-2.3 g/cm3; and optionally 0-40 parts by weight of a styrene-based impact modifier, wherein R1 is an alkyl, aryl, alkyl-substituted aryl, aralkyl, alkoxy, aryloxy, amino or hydroxyl group (wherein the alkoxy or aryloxy group can be substituted with an alkyl, aryl, amino or hydroxyl group); k and m are an integer of 0-10; R2 is an alkyl-substituted or unsubstituted C6-C30 dioxyaryl derivative; n is a number average degree of polymerization and is 0.3-3; R3, R4, R6 and R7 are independently an alkyl-substituted C6-C20 aryl group; R5 is an alkyl-substituted or unsubstituted C6-C20 aryl group; and l is a number average degree of polymerization and has an average number of 0-3.

Abstract translation: 目的：提供阻燃热塑性树脂组合物，以改善阻燃性，热稳定性，耐冲击性，可加工性和外观的平衡。 构成：热塑性树脂组合物包含100重量份的聚苯醚系树脂; 1-30重量份的含有1-50重量％环状磷腈低聚物化合物混合物的有机磷酸基化合物混合物，其包含通过具有-R 2 - 基团的连接基团连接的式I的环状磷腈化合物， 99重量％的式II的磷酸酯化合物或磷酸酯化合物的混合物; 0.05-5重量份平均粒度为0.05-1,000微米，密度为1.2-2.3克/厘米3的氟化聚烯烃基树脂; 和任选的0-40重量份的基于苯乙烯的抗冲改性剂，其中R 1是烷基，芳基，烷基取代的芳基，芳烷基，烷氧基，芳氧基，氨基或羟基（其中烷氧基或芳氧基可以被 烷基，芳基，氨基或羟基）; k和m是0-10的整数; R2是烷基取代或未取代的C6-C30二氧基芳基衍生物; n是数均聚合度，为0.3-3; R3，R4，R6和R7独立地是烷基取代的C6-C20芳基; R5是烷基取代或未取代的C6-C20芳基; l是数均聚合度，平均数为0〜3。

公开(公告)号：KR100439331B1

公开(公告)日：2004-07-07

申请号：KR1020010043333

申请日：2001-07-19

Applicant: 제일모직주식회사

Inventor： 이제흔 ,  임종철 ,  서경훈 ,  장영길

IPC: C08K5/521

Abstract: PURPOSE: Provided is a fire retardant thermoplastic resin composition using a diaryl morpholide phosphate compound as a fire retardant agent, which is excellent in fire-retardancy, mechanical properties, flowability, and work-ability and can be used for housings of electric and electronic products. CONSTITUTION: The fire retardant thermoplastic resin composition comprises: 100pts.wt. of a thermoplastic resin comprising at least one or two selected from the group consisting of a polycarbonate resin, an acryl resin, a vinyl aromatic resin, wherein the polycarbonate resin has a weight average molecular weight of 10,000-200,000; and 1-35pts.wt. of the diaryl morpholide phosphate represented by the formula(1), wherein x is 1 and R is aryl or alkyl-substituted aryl.

Abstract translation: 目的：提供一种使用磷酸二芳基酯化合物作为阻燃剂的阻燃热塑性树脂组合物，其具有优异的阻燃性，机械性能，流动性和可加工性，并且可用于电气和电子产品的外壳 。 构成：阻燃热塑性树脂组合物包含：100pts.wt。 的热塑性树脂，所述热塑性树脂包含选自由聚碳酸酯树脂，丙烯酸树脂，乙烯基芳族树脂组成的组中的至少一种或两种，其中所述聚碳酸酯树脂的重均分子量为10,000-200,000; 和1-35pts.wt。 的由式（1）表示的吗啉代磷酸二芳基酯，其中x是1且R是芳基或烷基取代的芳基。

公开(公告)号：KR1020040053621A

公开(公告)日：2004-06-24

申请号：KR1020020080788

申请日：2002-12-17

Applicant: 제일모직주식회사

Inventor： 윤종태 ,  임종철 ,  양삼주

IPC: C08L77/00 ,  B82B1/00 ,  B82Y30/00

CPC classification number: C08L77/00 ,  B82B1/008 ,  C08J2300/22 ,  C08K3/346 ,  C08K9/04 ,  C08L23/16 ,  C08L25/12 ,  C08L51/04 ,  C08L2205/02 ,  C08L2205/035

Abstract: PURPOSE: A nanocomposite resin composition is provided, to improve low temperature impact resistance in addition to room temperature impact resistance. CONSTITUTION: The composition comprises 40-55 parts by weight of a polyamide resin; 20-50 parts by weight of a graft copolymer obtained by graft polymerizing 25-77 parts by weight of a rubbery polymer, 40-90 parts by weight of an aromatic vinyl-based monomer and 10-60 parts by weight of a cyano vinyl-based monomer; 0-5 parts by weight of a copolymer obtained by polymerizing 40-90 parts by weight of an aromatic vinyl-based monomer, 10-60 parts by weight of a cyano vinyl-based monomer and 0-40 parts by weight of other vinyl-based monomer polymerizable with the two monomers; 1-25 parts by weight of an ethylene-propylene-based copolymer obtained by melt mixing 100 parts by weight of an ethylene-propylene rubber, 0-2 parts by weight of an organic peroxide and 0.1-10 parts by weight of a reactive monomer having an unsaturated carboxylic acid or acid anhydride group; 3-10 parts by weight of a maleimide-based copolymer obtained by copolymerizing 30-70 parts by weight of an aromatic vinyl-based monomer, 30-50 parts by weight of a maleimide-based monomer, 1-20 parts by weight of an unsaturated dicarboxylic anhydride monomer and 0-50 parts by weight of other copolymerizable monomer; and 1-20 parts by weight of a layered clay mineral organically treated by an alkyl ammonium compound.

Abstract translation: 目的：提供纳米复合树脂组合物，以提高耐室温耐冲击性的耐低温冲击性。 构成：组合物包含40-55重量份的聚酰胺树脂; 20-50重量份通过接枝聚合25-77重量份橡胶状聚合物，40-90重量份芳族乙烯基类单体和10-60重量份氰基乙烯基系单体得到的接枝共聚物， 单体; 通过聚合40-90重量份的芳族乙烯基类单体，10-60重量份的氰基乙烯基类单体和0-40重量份的其它乙烯基类单体，得到0-5重量份的共聚物， 与单体可聚合的单体; 通过将100重量份的乙烯 - 丙烯橡胶，0-2重量份的有机过氧化物和0.1-10重量份的反应性单体熔融混合得到的乙烯 - 丙烯基共聚物1-25重量份 具有不饱和羧酸或酸酐基团; 将3-10重量份通过共聚30-70重量份芳族乙烯基类单体，30-50重量份马来酰亚胺类单体，1-20重量份的马来酰亚胺类共聚物， 不饱和二羧酸酐单体和0-50重量份的其它可共聚单体; 和1-20重量份通过烷基铵化合物有机处理的层状粘土矿物。

公开(公告)号：KR100433573B1

公开(公告)日：2004-06-02

申请号：KR1020010062557

申请日：2001-10-11

Applicant: 제일모직주식회사

Inventor： 서경훈 ,  임종철 ,  양삼주

IPC: C08L69/00

Abstract: 본발명의난연성열가소성수지조성물은 (A) 폴리카보네이트수지 30-95 중량부; (B) (b) 스티렌, α-메틸스티렌, 할로겐또는메틸링-치환스티렌, C메타크릴산알킬에스테르류, C아크릴산알킬에스테르류, 아크릴로니트릴, 메타크릴로니트릴, 무수말레인산, C알킬또는페닐 N-치환말레이미드또는이들의혼합물 5-95 중량%를 (b)폴리오가노실록산/폴리알킬(메타)아크릴레이트고무복합체 5-95 중량%에그라프트중합하여얻은실리콘/아크릴레이트고무변성그라프트공중합체 1-50 중량부; (C) (c) 스티렌, α-메틸스티렌, 링-치환스티렌, C메타크릴산알킬에스테르류, C아크릴산알킬에스테르류또는이들의혼합물 50-95 중량%와 (c) 아크릴로니트릴, 메타크릴로니트릴, C메타크릴산알킬에스테르류, C아크릴산알킬에스테르류, 무수말레인산, C알킬또는페닐 N-치환말레이미드또는이들의혼합물 5-50 중량%를공중합하여제조되는비닐계공중합체 1-50 중량부; (D) 상기 (A)+(B)+(C)로이루어지는기초수지 100 중량부에대하여, 인산에스테르계화합물 1-30 중량부; 및 (F) 평균입자크기가 0.05-1000 ㎛이고, 밀도가 1.2-2.3 g/cm인불소화폴리올레핀계수지 0.05-5 중량부로이루어진다.

公开(公告)号：KR100405198B1

公开(公告)日：2003-11-12

申请号：KR1020010042711

申请日：2001-07-16

Applicant: 제일모직주식회사

Inventor： 임종철 ,  서경훈 ,  양삼주

IPC: C08L71/12

Abstract: PURPOSE: A flame-retardant thermoplastic resin composition is provided to furnish excellent flame-retardant, heat-resistant and impact-resistant properties and mechanical strength by comprising specified proportions of particular compounds including phosphazene compound. CONSTITUTION: The composition comprises (A) 100wt.% of polyphenylenether-based resin consisting of polyphenylenether resin or polyphenylenether and vinyl aromatic polymer; (B) (B1) 5-90wt.% of phosphazene compound and (B2) 1-30wt.% of organo phosphorous-based compound containing 95-10wt.% of phosphoric ester mopolide compound represented by formula 3(wherein x is 1 or 2; R1 is C6-C12 aryl or alkyl substituted C6-C12; R2 is C6-C12 aryl or alkyl substituted aryl derivative; n and m are each number average polymerization degree and average of n+m is 0-5); and (C) 0.05-5wt.% of fluoro polyolefine based resin having an average particle size of 0.05-1000 microns and a density of 1.2-2.3g/cm3. The phosphazene compound(B1) is a linear or a cyclic phosphazene compound represented by formulae 1 or 2(wherein R is selected from a group consisting of alkyl, aryl, alkyl substituted aryl, arylalkyl, alkoxy, aryloxy, amino or hydroxyl groups; k is an integer of 0-10; the alkoxy or aryloxy group can be substituted by alkyl, aryl, amino or hydroxyl groups).

Abstract translation: 目的：通过含有特定比例的特定化合物（包括磷腈化合物），提供阻燃热塑性树脂组合物以提供优异的阻燃性，耐热性和抗冲击性以及机械强度。 构成：组合物包含：（A）100重量％的由聚苯醚树脂或聚苯醚和乙烯基芳族聚合物组成的聚苯醚类树脂; （B）（B1）5-90重量％的磷腈化合物和（B2）1-30重量％的含有95-10重量％的由式3表示的磷酸酯多磷酸酯化合物（其中x为1或 2; R1为C6-C12芳基或烷基取代的C6-C12; R2为C6-C12芳基或烷基取代的芳基衍生物; n和m各自为数均聚合度，n + m的平均值为0-5）。 和（C）平均粒度为0.05-1000微米，密度为1.2-2.3克/厘米3的0.05-5重量％氟代聚烯烃基树脂。 磷腈化合物（B1）是由式1或2表示的直链或环状磷腈化合物（其中R选自由烷基，芳基，烷基取代的芳基，芳基烷基，烷氧基，芳氧基，氨基或羟基组成的组; k 是0-10的整数;烷氧基或芳氧基可以被烷基，芳基，氨基或羟基取代）。

公开(公告)号：KR1020030048191A

公开(公告)日：2003-06-19

申请号：KR1020010078058

申请日：2001-12-11

Applicant: 제일모직주식회사

Inventor： 임종철 ,  홍상현 ,  양삼주

IPC: C08L69/00

CPC classification number: C08L69/00 ,  C08J5/00 ,  C08J2300/22 ,  C08K5/523 ,  C08K5/5399 ,  C08L23/28 ,  C08L25/08 ,  C08L51/04 ,  C08L2201/02 ,  C08L2205/035

Abstract: PURPOSE: A flame retardant thermoplastic resin composition and a molded product prepared by using the composition are provided, to improve the flame retardancy, the heat resistance, the hot water resistance, the impact resistance, the stress cracking resistance, the heat stability and the workability. CONSTITUTION: The thermoplastic resin composition comprises 100 parts by weight of a resin component; 1-30 parts by weight of a mixture of organic phosphorus-based compounds comprising 5-95 parts by weight of the phosphoric acid ester morpholide compound monomer of the formula I and 5-95 parts by weight of the phosphoric acid ester-based oligomer of the formula II; and 0.05-5 parts by weight of a fluorinated polyolefin-based resin having an average particle size of 0.05-1,000 micrometers and a density of 1.2-2.3 g/cm3, wherein R1, R2, R3, R5 and R6 are independently an unsubstituted or alkyl-substituted aryl group of C6-C20; x is 1 or 2; and R4 is an unsubstituted or alkyl-substituted arylene group of C6-C30; and n has an average of 0.3-5. The resin component comprises 45-95 parts by weight of a thermoplastic polycarbonate resin; 1-50 parts by weight of the vinyl-based graft copolymer obtained by graft polymerizing 5-95 parts by weight of a monomer mixture comprising 50-95 parts by weight of styrene, α-methylstyrene, halogen or alkyl-substituted styrene, C1-C8 methacrylic acid alkyl ester, C1-C8 acrylic acid alkyl ester or their mixtures and 5-50 parts by weight of acrylonitrile, methacrylonitrile, C1-C8 methacrylic acid alkyl ester, C1-C8 acrylic acid alkyl ester, maleic anhydride, C1-C4 alkyl or phenyl N-substituted maleimide or their mixtures, onto 5-95 parts by weight of at least one polymer selected from the group consisting of butadiene rubber, acryl rubber, ethylene-propylene rubber, styrene-butadiene rubber, acrylonitrile-butadiene rubber, isoprene rubber, ethylene-propylene-diene terpolymer and polyorganosiloxane-polyalkyl(meth)acrylate rubber composite; and 0-50 parts by weight of vinyl-based copolymers or their mixture obtained by copolymerizing 50-95 parts by weight of styrene, α-methylstyrene, halogen or alkyl-substituted styrene, C1-C8 methacrylic acid alkyl ester, C1-C8 acrylic acid alkyl ester or their mixtures and 5-50 parts by weight of acrylonitrile, methacrylonitrile, C1-C8 methacrylic acid alkyl ester, C1-C8 acrylic acid alkyl ester, maleic anhydride, C1-C4 alkyl or phenyl N-substituted maleimide or their mixtures.

Abstract translation: 目的：提供阻燃热塑性树脂组合物和通过使用该组合物制备的模塑产品，以改善阻燃性，耐热性，耐热水性，耐冲击性，耐应力开裂性，热稳定性和加工性 。 构成：热塑性树脂组合物包含100重量份树脂组分; 1-30重量份的含有5-95重量份式I的磷酸酯吗啉化合物单体和5-95重量份磷酸酯系低聚物的有机磷系化合物的混合物 公式II; 和0.05-5重量份平均粒径为0.05-1,000微米，密度为1.2-2.3克/厘米3的氟化聚烯烃基树脂，其中R1，R2，R3，R5和R6独立地是未取代的或未取代的 C6-C20的烷基取代的芳基; x为1或2; R4是C6-C30的未取代或烷基取代的亚芳基; n平均为0.3-5。 树脂组分包含45-95重量份的热塑性聚碳酸酯树脂; 1-50重量份通过接枝聚合5-95重量份包含50-95重量份苯乙烯，α-甲基苯乙烯，卤素或烷基取代的苯乙烯的单体混合物获得的乙烯基类接枝共聚物，C1- C8甲基丙烯酸烷基酯，C1-C8丙烯酸烷基酯或它们的混合物，以及5-50重量份丙烯腈，甲基丙烯腈，C1-C8甲基丙烯酸烷基酯，C1-C8丙烯酸烷基酯，马来酸酐，C1-C4 烷基或苯基N-取代的马来酰亚胺或其混合物，在5-95重量份的至少一种选自丁二烯橡胶，丙烯酸橡胶，乙丙橡胶，苯乙烯 - 丁二烯橡胶，丙烯腈 - 丁二烯橡胶， 异戊二烯橡胶，乙烯 - 丙烯 - 二烯三元共聚物和聚有机硅氧烷 - （甲基）丙烯酸烷基酯橡胶复合材料; 和0-50重量份的乙烯基类共聚物或它们的混合物通过共聚合50-95重量份的苯乙烯，α-甲基苯乙烯，卤素或烷基取代的苯乙烯，C1-C8甲基丙烯酸烷基酯，C1-C8丙烯酸 丙烯腈，甲基丙烯腈，C1-C8甲基丙烯酸烷基酯，C1-C8丙烯酸烷基酯，马来酸酐，C1-C4烷基或苯基N-取代的马来酰亚胺或其混合物 。

公开(公告)号：KR1020030047384A

公开(公告)日：2003-06-18

申请号：KR1020010077860

申请日：2001-12-10

Applicant: 제일모직주식회사

Inventor： 임종철 ,  홍상현 ,  양삼주

IPC: C08L69/00

CPC classification number: C08L69/00 ,  C08J5/00 ,  C08J2300/22 ,  C08K5/5399 ,  C08L23/28 ,  C08L25/08 ,  C08L51/04 ,  C08L2201/02 ,  C08L2201/08 ,  C08L2205/035

Abstract: PURPOSE: A flame retardant-based thermoplastic resin composition and a molded product prepared by using the composition are provided, to improve the flame retardancy, the heat resistance, the hot water resistance and the mechanical properties. CONSTITUTION: The thermoplastic resin composition comprises 100 parts by weight of a resin component; 1-30 parts by weight of a mixture of organic phosphorus-based compounds comprising 5-95 parts by weight of the phosphoric acid ester morpholide compound of the formula 2 and 5-95 parts by weight of the phosphoric acid ester-based oligomer of the formula 3; and 0.05-5 parts by weight of a fluorinated polyolefin-based resin having an average particle size of 0.05-1,000 micrometers and a density of 1.2-2.3 g/cm3, wherein R1, R2, R3, R5 and R6 are independently an aryl group of C6-C20 or an alkyl-substituted aryl group of C6-C20; n has an average number of 0.3-5; and R4 is a group derived from the bisphenol A represented by the formula 4. The resin component comprises 45-95 parts by weight of a thermoplastic polycarbonate resin; 1-50 parts by weight of a rubber modified vinyl-based graft copolymer obtained by graft polymerizing (b1) 5-95 parts by weight of a monomer mixture comprising 50-95 parts by weight of styrene, α-methylstyrene, halogen or alkyl-substituted styrene, C1-C8 methacrylic acid alkyl ester, C1-C8 acrylic acid alkyl ester or their mixtures and 5-50 parts by weight of acrylonitrile, methacrylonitrile, C1-C8 methacrylic acid alkyl ester, C1-C8 acrylic acid alkyl ester, maleic anhydride, C1-C4 alkyl or phenyl N-substituted maleimide or their mixtures, onto (b2) 5-95 parts by weight of at least one selected from the group consisting of butadiene rubber, acryl rubber, ethylene-propylene rubber, styrene-butadiene rubber, acrylonitrile-butadiene rubber, isoprene rubber, ethylene-propylene-diene terpolymer and polyorganosiloxane-polyalkyl(meth)acrylate rubber composite; and 0-50 parts by weight of a vinyl-based copolymers or their mixture obtained by copolymerizing (c1) 50-95 parts by weight of styrene, α-methylstyrene, halogen or alkyl-substituted styrene, C1-C8 methacrylic acid alkyl ester, C1-C8 acrylic acid alkyl ester or their mixtures and (c2) 5-50 parts by weight of acrylonitrile, methacrylonitrile, C1-C8 methacrylic acid alkyl ester, C1-C8 acrylic acid alkyl ester, maleic anhydride, C1-C4 alkyl or phenyl N-substituted maleimide or their mixtures.

Abstract translation: 目的：提供阻燃剂型热塑性树脂组合物和使用该组合物制备的成型体，以提高阻燃性，耐热性，耐热水性和机械性能。 构成：热塑性树脂组合物包含100重量份的树脂组分; 1-30重量份的含有5-95重量份式2的磷酸酯吗啉化合物的有机磷基化合物与5-95重量份的磷酸酯类低聚物的混合物 公式3; 和0.05-5重量份的平均粒径为0.05-1,000微米，密度为1.2-2.3克/厘米3的氟化聚烯烃基树脂，其中R1，R2，R3，R5和R6独立地为芳基 的C6-C20或C6-C20的烷基取代的芳基; n的平均数量为0.3-5; 和R4是衍生自由式4表示的双酚A的基团。树脂组分包含45-95重量份的热塑性聚碳酸酯树脂; 1-50重量份通过接枝聚合获得的橡胶改性的乙烯基类接枝共聚物（b1）5-95重量份的单体混合物，其包含50-95重量份的苯乙烯，α-甲基苯乙烯，卤素或烷基 - 取代苯乙烯，C1-C8甲基丙烯酸烷基酯，C1-C8丙烯酸烷基酯或它们的混合物，和5-50重量份丙烯腈，甲基丙烯腈，C1-C8甲基丙烯酸烷基酯，C1-C8丙烯酸烷基酯，马来酸 酸酐，C 1 -C 4烷基或苯基N-取代的马来酰亚胺或它们的混合物，在（b2）5-95重量份的选自丁二烯橡胶，丙烯酸橡胶，乙烯 - 丙烯橡胶，苯乙烯 - 丁二烯中的至少一种 橡胶，丙烯腈 - 丁二烯橡胶，异戊二烯橡胶，乙烯 - 丙烯 - 二烯三元共聚物和聚有机硅氧烷 - （甲基）丙烯酸烷基酯橡胶复合材料; 和（c1）50-95重量份苯乙烯，α-甲基苯乙烯，卤素或烷基取代的苯乙烯，C1-C8甲基丙烯酸烷基酯，（甲基）丙烯酸烷基酯， C1-C8丙烯酸烷基酯或其混合物，（c2）5-50重量份丙烯腈，甲基丙烯腈，C1-C8甲基丙烯酸烷基酯，C1-C8丙烯酸烷基酯，马来酸酐，C1-C4烷基或苯基 N-取代的马来酰亚胺或它们的混合物。