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公开(公告)号：KR1020060040106A
公开(公告)日：2006-05-10
申请号：KR1020040089320
申请日：2004-11-04
Applicant: 주식회사 효성
CPC classification number: G02B6/02038 , B29D11/00663 , G02B1/045 , G02B6/02395
Abstract: 본 발명은 유연성이 향상된 그래디드 인덱스(Graded-Index)형 플라스틱 광섬유 모재 및 광섬유 제조 방법에 관한 것으로, 클래딩에 사용되는 굴절률이 상대적으로 낮은 제 1단량체와, 플라스틱 광섬유에 유연성을 증가시킬 수 있는 첨가제와, 개시제와, 연쇄이동제를 혼합하여 보호층 튜브를 형성하는 단계(S1); 상기 제 1단량체에 개시제와 연쇄이동제를 첨가하여 클래딩을 형성하는 단계(S2); 상기 제 1단량체와 상기 제 1단량체 보다 굴절률이 상대적으로 높은 제 2단량체를 6:4 내지 7:3으로 혼합한 후 상기 보호층 튜브에 투입하여 상온에서 500~5,000rpm으로 회전시켜 상기 보호층을 팽윤시키면서 혼합용액이 보호층 내부로 확산된 후 겔 상을 형성하는 단계(S3); 이를 다시 50~150℃ 온도에서 회전속도 500~5,000rpm으로 회전시키면서 중합시키는 단계(S4); 및 상기 제 1단량체와 상기 제 2단량체의 혼합비를 5:5 내지 0:10의 범위 내에서 제조된 혼합용액을 상기 보호층 튜브에 투입하여 다시 S3 과정과 S4 과정을 반복하되, 상기 제 2단량체를 점차로 증가시켜 팽윤과 확산을 반복하는 단계(S5);를 포함하는 것을 특징으로 한다. 본 제조방법에 의하면 광섬유의 유연성을 향상시켜줌으로써 기존의 플라스틱 광섬유에 비하여 유연성이 향상되고 외압에 의한 충격에 강한 특징이 있다.
모재, 그래디드-인덱스, 확산, 팽윤, 플라스틱 광섬유, 굴절률, 보호층-
82.发明公开1,1-비스하이드록시페닐-1-3,5-비스트리플로로메틸페닐-에탄단량체의 합성방법 및 이 단량체를 이용한폴리아릴렌에테르의 중합방법 失效使用1,1-BIS（4-羟基苯基）-1的1,1-二（4-羟基苯基）-1-（3,5-BIS（三氟甲磺酰基） - 苯基） - 乙烯和聚（亚甲基）ET- - （3,5-BIS（三氟甲基）苯基） - 乙基
公开(公告)号：KR1020050092918A
公开(公告)日：2005-09-23
申请号：KR1020040018104
申请日：2004-03-17
Applicant: 주식회사 효성
IPC: C07C39/367
Abstract: 본 발명은 불소를 함유한 1,1-비스하이드록시페닐-1-3,5-비스트리플로로메틸페닐-에탄 단량체 및 그의 제조방법 그리고 이 단량체로 중합한 폴리아릴렌에테르 및 그 제조방법에 관한 것으로 단량체는 하기 화학식 1로 표시되며, 폴리아릴렌에테르는 하기 화학식 2로 표시될 수 있다. 본 발명의 폴리아릴렌에테르는 높은 열적 안정성과 낮은 유전상수 및 낮은 광학손실을 가지므로 광소자 및 광학재료로 사용될 수 있다.
[화학식1]
[화학식 2]
(식 중, X는 없거나 C=O, S 또는 SO
2 이고, 여기서 n은 중합도로써 1∼100의 자연수이고, 본 발명에서 제공된 Bis-6F를 제외한 다이올(Diol)과 다이헬라이드(Dihalide)의 반복단위는 동일하거나 이종(異種)이어도 좋다.)-
公开(公告)号：KR200379550Y1
公开(公告)日：2005-03-18
申请号：KR2020040037697
申请日：2004-12-31
IPC: B01D63/08
CPC classification number: B01D63/08 , B01D69/06 , B01D69/10 , B01D2315/06 , C02F3/1273
Abstract: 본 고안은 흡입부와 평막의 각 부위와의 거리에 관계없이 평막 전체에 고른 흡입압력을 제공하여 막의 각 부위별 정수처리량이 동일해지도록 제어하는 수단이 구비되어 파울링의 정도를 막전체에 고르게 제공하고, 세정주기를 연장시키며, 결과적으로 사용수명을 연장시켜 주는 침지형 평막 모듈에 관한 것이다.
본 고안은 지지체(310)의 양면에 각각 스페이서용 부직포(320)와 평막(330)이 순차적으로 적층되는 침지형 평막 모듈(300)에 있어서, 상기 지지체(310)는, 내부 중앙 부분에 집수관(311)이 형성되고, 상기 형성된 집수관(311)을 중심으로 내부 양측에 수평방향으로 된 복수의 격벽(312)이 동일한 간격으로 형성되며, 상기 격벽(312)에 의해 지지체(310) 내부에 복수의 유로가 형성되고, 상기 집수관(311)과 맞닿는 복수의 유로의 중심방향 측면마다 면적이 상이한 복수의 유출부(313a,313b)가 형성되고, 유출부에 의해 유로와 집수관이 연결되는 것으로 내부에 형성된 격벽(312)의 사이마다에 위치되는 복수의 유입공(314)이 형성되어 이루어진다.-
公开(公告)号：KR1020050025770A
公开(公告)日：2005-03-14
申请号：KR1020030062602
申请日：2003-09-08
Applicant: 주식회사 효성
IPC: C08J5/12
CPC classification number: C08J5/24 , C08J5/12 , G02B6/02033 , G02B6/0288
Abstract: Provided is a production process of graded-index typed plastic optical fiber preform improving flexibility which adjusts content of an initiator and a chained mobilizer to minimize reduction of glass transition temperature influenced by adding a plasticizer, therefore it improves transmission rate. The production process of the graded-index typed plastic optical fiber preform improving flexibility comprises the steps of: (i) mixing a first monomer showing relatively low refractive index with the initiator, the chained mobilizer and the plasticizer and rotating the mixture in a glass tube at 50-150deg.C to prepare a polymer tube; (ii) lowering the temperature, mixing the first monomer and a second monomer showing higher refractive index than the first monomer with the initiator, the chained mobilizer and the plasticizer, rotating and swelling the mixture to form gel in the polymer tube at normal temperature and rotating the polymer tube to polymerize the mixture with raising the temperature to 70-100deg.C; and (iii) increasing the content of the second monomer with repeating the second step for several times to produce the plastic optical fiber with a hollow hole filled.
Abstract translation: 提供了渐变折射型塑料光纤预制件的生产工艺，其改善了引发剂和链状移动剂的含量的灵活性，以通过加入增塑剂来降低玻璃化转变温度的降低，从而提高透射率。 渐变折射型塑料光纤预制件改进柔性的生产工艺包括以下步骤：（i）将显示相对较低折射率的第一单体与引发剂，链状移动剂和增塑剂混合，并将混合物在玻璃管 在50-150℃下制备聚合物管; （ii）降低温度，将第一单体和第二单体与引发剂，链状移动剂和增塑剂混合，显示出比第一单体更高的折射率，在常温下将混合物旋转和溶胀以在聚合物管中形成凝胶， 旋转聚合物管使混合物聚合，升温至70-100℃; 和（iii）通过重复第二步骤数次来增加第二单体的含量，以制备填充有中空孔的塑料光纤。
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85.发明公开
公开(公告)号：KR1020040102543A
公开(公告)日：2004-12-08
申请号：KR1020030034045
申请日：2003-05-28
Applicant: 주식회사 효성
IPC: C08F283/06
Abstract: PURPOSE: Polyarylene ether sulfides having an aliphatic group substituted with fluorine are provided to improve the molecular flexibility, thus to improve processability, to reduce birefringence and to make the adjustment of refractive index convenient, thereby being suitably used as a light waveguide element with less light loss and excellent mechanical and chemical properties. CONSTITUTION: The polyarylene ether sulfides have a structure represented by formula 1, wherein X is a single bond, -CO- or -SO2-; Y is a single bond, -S-, -CO- or -SO2-; m is an integer of 1-12; Ar is at least one functional group selected from functional groups represented by formula 2; each of a, b, c and d is a number representing the polymerization degree, a is an integer of 1-100, b is an integer of 1-100, c is an integer of 0-100 and d is an integer of 1-100, wherein a+b=b+d is satisfied.
Abstract translation: 目的：提供具有被氟取代的脂族基团的聚亚芳基醚硫醚以提高分子柔性，从而提高加工性能，减少双折射并使折射率调节方便，从而适合用作光线较少的光波导元件 损失和优异的机械化学性能。 构成：聚亚芳基醚硫化物具有由式1表示的结构，其中X是单键，-CO-或-SO 2 - ; Y是单键，-S-，-CO-或-SO 2 - ; m为1-12的整数; Ar是选自由式2表示的官能团中的至少一个官能团; a，b，c和d中的每一个为表示聚合度的数，a为1-100的整数，b为1-100的整数，c为0〜100的整数，d为1的整数 -100，其中a + b = b + d。
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Patent Agency Ranking
公开(公告)号：KR100427504B1
公开(公告)日：2004-04-28
申请号：KR1020020045183
申请日：2002-07-31
Applicant: 주식회사 효성
IPC: G02B6/00
Abstract: PURPOSE: A method for manufacturing a mother material for use in a plastic photonic crystal fiber(P-PCF) is provided to be easily manufactured as well as to obtain various structure of the P-PCF by changing the thickness and the interval of the coating metal rod. CONSTITUTION: A method for manufacturing a mother material for use in a plastic photonic crystal fiber includes the steps of: preparing a mixed solution by adding an initiator and a chain transfer agent to a monomer for use a polymer having an excellent optical transmission characteristics; forming a syrup by using the mixed solution; inserting the syrup the glass tube as a bottom mold; assembling the top mold(10) having a plurality of metal rods(12) to the glass tube; and polymerizing the inserted syrup at a pressure of 4 -12kgf/cm2 and at a temperature of 70-180°C.
Abstract translation: 目的：提供一种制造用于塑料光子晶体光纤（P-PCF）的母材的方法，以便容易地制造，并且通过改变涂层的厚度和间隔来获得P-PCF的各种结构 金属棒。 本发明的目的在于提供一种制造用于塑料光子晶体光纤的母材的方法，该方法包括以下步骤：通过向单体中加入引发剂和链转移剂来制备混合溶液，以便使用具有优异光学透射特性的聚合物; 通过使用混合溶液形成糖浆; 将糖浆插入玻璃管作为底模; 将具有多个金属杆（12）的上模（10）组装到玻璃管; 以及在4-12kgf / cm2的压力和70-180℃的温度下使插入的糖浆聚合。
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公开(公告)号：KR1020040025332A
公开(公告)日：2004-03-24
申请号：KR1020020057260
申请日：2002-09-19
Applicant: 주식회사 효성
IPC: C07C323/21
Abstract: PURPOSE: A fluoro-substituted polyarylene ether sulfide compound is provided to reduce optical loss and double refraction index and to obtain an optical waveguide type optical device having excellent mechanical properties, heat resistance, chemical resistance and thermal stability. CONSTITUTION: The fluoro-substituted polyarylene ether sulfide compound is represented by the general formula I, wherein n is a polymerization degree and a natural number of 1-100, and the repeating units are the same or different, when n is 2 or more; and X is a substituent selected from the group consisting of the chemical formulae 1-4, and the compound comprises repeating units having a substituent selected from the group consisting of the chemical formulae 1-3, when the substituent is represented by the chemical formula 4.
Abstract translation: 目的：提供氟取代聚亚芳基醚硫醚化合物以减少光学损失和双折射率，并获得具有优异的机械性能，耐热性，耐化学性和热稳定性的光波导型光学器件。 构成：氟取代聚亚芳基醚硫醚化合物由通式I表示，n为聚合度，自然数为1-100，当n为2以上时，重复单元相同或不同; X是选自化学式1-4的取代基，该化合物包含具有选自化学式1-3的取代基的重复单元，当该取代基由化学式4表示时 。
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公开(公告)号：KR1020030065822A
公开(公告)日：2003-08-09
申请号：KR1020020005840
申请日：2002-02-01
Applicant: 주식회사 효성
IPC: G02B6/02
Abstract: PURPOSE: A light waveguide using fluorine-substituted polyimide is provided to increases a refractive index difference between a core and a clad by forming the core and the clad of the light waveguide using the fluorine-substituted polyimide whose refractive index is easily controlled. CONSTITUTION: According to the light waveguide comprising a core and a clad adjacent to the core which are formed with a polymer, the core and the polymide are fluorine-substituted polyimide respectively, and a refractive index of the polymer for forming the core is larger than that of the polymer for forming the clad. The refractive index difference between the polymer for forming the core and the polymer for forming the clad lies between 0.19% and 3.4% of the refractive index of the polymer for forming the core.
Abstract translation: 目的：提供使用氟取代的聚酰亚胺的光波导，通过使用易于控制折射率的氟取代的聚酰亚胺形成芯体和光波导的包层来增加芯和包层之间的折射率差。 构成：根据包含核心的光波导和与芯体相邻的包层，其形成有聚合物，芯和聚酰亚胺分别为氟取代的聚酰亚胺，并且用于形成芯的聚合物的折射率大于 用于形成包层的聚合物。 用于形成芯的聚合物和用于形成包层的聚合物之间的折射率差在用于形成芯的聚合物的折射率的0.19％至3.4％之间。
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公开(公告)号：KR1020030057800A
公开(公告)日：2003-07-07
申请号：KR1020010087884
申请日：2001-12-29
Applicant: 주식회사 효성
IPC: G02B6/00
Abstract: PURPOSE: A method for fabricating a plastic optical fiber is provided, which has a graded-refractive index with good refractive index distribution. CONSTITUTION: According to the method, a polymer tube is fabricated by mixing an initiator 0.01-0.4 wt% and a chain transfer catalyst 0.01-0.4 volume% to the first monomer having a relatively low refractive index and then inserting them into a glass tube and then rotating them with 50-150 and 500-5000 rpm. After mixing the first monomer and the second monomer having a relatively high refractive index with a volume ratio of 1/4 or 3/4 and then inserting them into the polymer tube, the polymer is swelled by rotating them in the atmosphere temperature with 500-5000 rpm. Then, the polymer is polymerized as rotating it with 500-5000 rpm in the temperature of 50-150 deg.
Abstract translation: 目的：提供一种制造塑料光纤的方法，其具有折射率分布良好的梯度折射率。 构成：根据该方法，通过将0.01-0.4重量％的引发剂和0.01〜0.4体积％的链转移催化剂与具有较低折射率的第一单体混合，然后将其插入玻璃管和 然后以50-150和500-5000 rpm旋转它们。 在体积比为1/4或3/4的第一单体和具有较高折射率的第二单体混合之后，将其插入聚合物管中时，聚合物在大气温度下旋转500- 5000转/分。 然后，聚合物在50-150度的温度下以500-5000rpm旋转聚合。
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公开(公告)号：KR1020030057799A
公开(公告)日：2003-07-07
申请号：KR1020010087883
申请日：2001-12-29
Applicant: 주식회사 효성
IPC: C07C39/24
Abstract: PURPOSE: Provided are a novel fluorine-containing monomer which can be used for polymerizing polyarylene ether having excellent thermal stability, as well as low optical loss and birefringence, and a method for producing the same. CONSTITUTION: The 1,1-bis(4-hydroxyphenyl)-1-pentafluorophenyl-ethane having a structure represented by formula 1, is produced by reacting pentafluoroacetophenone with phenol in methylene chloride by using trifluoromethane sulfonic acid as catalyst. Polyarylene ether formed by using 1,1-bis(4-hydroxyphenyl)-1-pentafluorophenyl-ethane, has high fluorine content and low hydrogen content, and thus shows low optical loss; and has a flexibility of ether bond and a branched phenyl group having hydrogen substituted with fluorine, and thus shows low birefringence.
Abstract translation: 目的：提供一种可用于聚合具有优异热稳定性的聚亚芳基醚以及低光损耗和双折射的新型含氟单体及其制备方法。 构成：具有式1所示结构的1,1-双（4-羟基苯基）-1-五氟苯基乙烷是通过使用三氟甲烷磺酸作为催化剂，使五氟乙酰苯与苯酚在二氯甲烷中反应制备的。 通过使用1,1-双（4-羟基苯基）-1-五氟苯基乙烷形成的聚亚芳基醚，具有高的氟含量和低的氢含量，因此表现出低的光损耗; 并且具有醚键的柔性和具有被氟取代的氢的支链苯基，因此显示低的双折射率。
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