Abstract:
신규한 고분자 전해질 물질로서, 폴리벤지이미다졸에 벤족사졸 단위를 도입한 폴리(벤지이미다졸-코-벤족사졸)을 제공한다. 해당 고분자 전해질 물질은 특히 인시츄로 인산 도핑되어 제조되는 경우라도 높은 프로톤 전도도를 가지면서도 기계적 특성이 동시에 우수하다. 따라서 고분자 전해질 막 연료전지 특히 고온 고분자 전해질 막 연료전지에서 기존의 인산 도핑된 폴리벤지이미다졸을 대체할 수 있다.
Abstract:
A novel alkyl chain modified sulfonated polyether sulfone copolymer and a manufacturing method thereof are provided. The alkyl chain modified sulfonated polyether sulfone copolymer has high thermal stability and mechanical stability, is economic, and has low methanol penetration, excellent proton conductivity, and excellent water absorption, thereby being useful for the commercialization of fuel cells such as a polymer electrolyte membrane fuel cell or a direct methanol fuel cell by replacing conventional Nafion.
Abstract:
PURPOSE: Polybenzimidazolium is provided to provide a polymer electrolyte with excellent performance and stability. CONSTITUTION: Polybenzimidazolium has a structure indicated in chemical formula 1 or chemical formula 2. In the chemical formulas, A is a direct bond or oxygen, B is a diacid group having 1-5 heteroatoms or diacid group containing nine or more carbon atoms, each of R1-R4 is independently hydrogen, a C1-6 alkyl group or aromatic substituent group, X- is anion selected from halogen, OH-, carbonate, hydrogen carbonate, sulfate, acetate, formate, methanolate and ethnolate, and n is an integer from 1 or more. [Reference numerals] (AA) R1 or unsubstituted; (BB, EE) R3 or unsubstituted; (CC) R2 or unsubstituted; (DD, FF) R4 or unsubsituted
Abstract:
PURPOSE: A manufacturing method of a polybenzimidazole-based polymer is provided to manufacture a polybenzimidazole-based polymer having excellent dimensional stability and mechanical strength even with excellent ion conductivity. CONSTITUTION: A manufacturing method of a polybenzimidazole-based polymer comprises a step of introducing electron withdrawing functional group into a benzimidazole-based polymer. The electron withdrawing functional group is one or more selected from a group consisting of carboxylic acid(-CO2H), cyan(-CN), fluorine (-F) and sulfonic acid. The benzimidazole-based polymer is a sulfonated poly(2,5-benzimidazole)based polymer. An electrolyte membrane comprises the polybenzimidazole-based polymer.