公开(公告)号：KR100255032B1

公开(公告)日：2000-05-01

申请号：KR1019980017681

申请日：1998-05-15

Applicant: 한국화학연구원

Inventor： 이영길 ,  장태선 ,  이규갑 ,  신채호 ,  조득희 ,  이동구

IPC: B01J27/185 ,  B01J27/19

Abstract: PURPOSE: Disclosed is a core-shell structured solid catalyst,£BinAaOx| £(100-z)%DdEeFefNigMomOy+z%SiO2|, for synthesis of nitrile compounds from the oxidation reaction of olefin or paraffin by the addition of ammonia. CONSTITUTION: The core-shell structured catalyst represented by£BinAaOx| £(100-z)%DdEeFefNigMomOy+z%SiO2|where A is one of boron, phosphorous, or molybdenum, D is an element having a valence of three, E is an element having a valence of two, and when m is 1, n, a, d, e, f, g, and z are 0.001-3, 0.001-3, 0.01-3, 0.01-3, 0.01-5, 0.1-5, and 0-90, respectively, is composed of core parts and shell parts. Core parts, which use silica as support and elements (E compositions) having a valence of two as active species such as Co, Mn, Mg, Ca, Cu, etc., and elements (D compositions) having a valence of three as active species such as Al, Ce, Cr, etc., are firstly prepared by the slurry method that a mixture of silica sol and salts containing an anion is heated and extracted to get a slurry at 3-5 pH by removal of solvent, and then dried and calcined at 200-700deg.C. Shell parts structure by the impregnation of salt solution,£BinAaOx|, on the core parts prepared by the slurry method. Here, acetate, citrate, nitric acid, or triphenyl may be used as salts for shell parts.

Abstract translation: 目的：公开了一种核 - 壳结构固体催化剂，BinAaOx | £（100-z）％DdEeFefNigMomOy + z％SiO2 |，用于通过加入氨从烯烃或石蜡的氧化反应合成腈化合物。 构成：由BinAaOx |代表的核 - 壳结构催化剂 £（100-z）％DdEeFefNigMomOy + z％SiO2 |其中A是硼，磷或钼之一，D是三价元素，E是二价元素，当m为1时 ，n，a，d，e，f，g和z分别为0.001-3,0.001-3,0.01-3,0.01-3,0.01-5,0.1〜5,0-90，由 核心零件和外壳零件。 使用二氧化硅作为活性物质如Co，Mn，Mg，Ca，Cu等的二氧化硅作为载体的元素（E组合物）和二价元素（E组合物），并且具有三价的元素（D组合物）作为活性物质 首先通过浆料法制备二氧化硅溶胶和含有阴离子的盐的混合物，通过除去溶剂在3-5℃下加热萃取以获得浆液，然后将其 干燥并煅烧200-700℃。 壳体部分结构通过浸渍盐溶液，BinAaOx |，通过浆料法制备的核心部件。 这里可以使用乙酸盐，柠檬酸盐，硝酸或三苯基醚作为壳部分的盐。

公开(公告)号：KR1019950017913A

公开(公告)日：1995-07-20

申请号：KR1019930029508

申请日：1993-12-24

Applicant: 한국화학연구원

Inventor： 이영길 ,  조득희 ,  장태선 ,  이동구 ,  신채호

IPC: C07C69/82

Abstract: 본 발명은 디메틸테레프탈레이트 증류잔사로부터 고순도의 4-카르복시벤즈알데히드를 제조하는 방법에 관한 것으로서, 더욱 상세하게는 디메틸테레프탈레이트(이하, DMT라함) 제조과정에서 필연적으로 배출되는 DMT 증류잔사로부터 복사기의 감광제, 형광표백제 또는 방부제의 제조에 있어서 중간체로 사용되는 4-카르복시벤즈알데히드(이하, 4-CBA라 함)을 고순도로 제조하는 방법에 관한 것이다.