公开(公告)号：EP2049579B1

公开(公告)日：2012-05-02

申请号：EP07729246.4

申请日：2007-05-17

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： PELLEGATTI, Giampaolo ,  SPATARO, Stefano ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni

IPC: C08F210/08 ,  C08F210/12 ,  C08F210/16

CPC classification number: C08F210/08 ,  C08F210/16 ,  C08F210/06 ,  C08F2500/03 ,  C08F2500/21 ,  C08F2500/12 ,  C08F210/14

Abstract: Butene-1 copolymers containing: a) from 1 to 7 % by mole of ethylene derived units, and b) from 3 to 20 % by mole of units derived from one or more alpha-olefin(s) having general formula H2C=CHR, wherein R is methyl or a linear or branched alkyl radical C3-C8; said copolymers having a molecular weight distribution with a ratio (I) of less than or equal to 4 and a (b)/(a) molar ratio of more than or equal to 2.3.

公开(公告)号：EP1565502B1

公开(公告)日：2012-04-18

申请号：EP03779841.0

申请日：2003-11-03

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MORINI, Giampiero ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni ,  BIGIAVI, Daniele ,  PELLICONI, Anteo ,  GARAGNANI, Enea ,  BAITA, Pietro

IPC: C08F210/08 ,  C08L23/02 ,  C08F4/656

CPC classification number: C08L23/04 ,  C08F10/00 ,  C08F210/08 ,  C08L23/14 ,  C08L23/22 ,  C08L2666/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F4/6465 ,  C08F210/06 ,  C08F2500/15 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/11 ,  C08F2500/20 ,  C08F210/16 ,  C08F2/001

Abstract: The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived characterized by the following properties: d) Product of the reactivity ratios rl·r2≤2; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.

Abstract translation: 本发明涉及含有高达40摩尔％乙烯和/或丙烯的丁烯-1共聚物，其特征在于以下性质：d）反应性比r1·r2＆nlE; 2的产物; e）全同立构五元组（mmmm）形式的丁烯-1单元含量> 98％; 和f）不存在4,1个丁烯单元的插入。

公开(公告)号：EP1805231B1

公开(公告)日：2010-03-31

申请号：EP05801351.7

申请日：2005-10-12

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： BACCI, Dino ,  MORHARD, Friederike ,  PIEMONTESI, Fabrizio ,  TONTI, Maria Silvia ,  VITALE, Gianni ,  MORINI, Giampiero ,  PELLICONI, Anteo

IPC: C08F10/08 ,  C08L23/18

CPC classification number: C08F10/08 ,  C08F110/08 ,  C08F210/08 ,  C08F2500/17 ,  C08F2500/20 ,  C08F2500/15 ,  C08F210/14 ,  C08F210/16 ,  C08F210/06

Abstract: Butene-1 (co)polymers characterized by the following properties: content of butene-1 units in the form of isotactic pentads (mmmm) from 25 to 55%; intrinsic viscosity [η] measured in tetraline at 135°C from 1 to 3dL/g; content of xylene insoluble fraction at 0°C from 3 to 60%; and a ratio ES2/ES1≥1, where ES1 is the boiling diethyl ether soluble fraction determined on the polymer as such and ES2 is the boiling diethyl ether soluble fraction determined after milling the polymer. The butene-1 (co)polymers show a good balance between processability and elastomeric behavior.

公开(公告)号：EP1948703B1

公开(公告)日：2009-04-29

申请号：EP06819401.8

申请日：2006-11-10

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： BACCI, Dino ,  FAIT, Anna ,  MORINI, Giampiero ,  PELLEGATTI, Giampaolo ,  PIEMONTESI, Fabrizio

IPC: C08F210/02

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/15 ,  C08F2500/11 ,  C08F2500/20

Abstract: Propylene-ethylene copolymers are flexible and show a very good balance between softness and mechanical properties in their crude state are obtained by solution polymerization in the presence of Ziegler-Natta catalysts. The said copolymers comprise from 10 to 50%wt of ethylene and are characterized by: product of the comonomer reactivity ratio r1 r2 =1.5; absence of 2,1 propylene insertions and tensile strength at break higher than 4 Mpa.

公开(公告)号：EP2049579A1

公开(公告)日：2009-04-22

申请号：EP07729246.4

申请日：2007-05-17

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： PELLEGATTI, Giampaolo ,  SPATARO, Stefano ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni

IPC: C08F210/08 ,  C08F210/12

CPC classification number: C08F210/08 ,  C08F210/16 ,  C08F210/06 ,  C08F2500/03 ,  C08F2500/21 ,  C08F2500/12 ,  C08F210/14

Abstract: Butene-1 copolymers containing: a) from 1 to 7 % by mole of ethylene derived units, and b) from 3 to 20 % by mole of units derived from one or more alpha-olefin(s) having general formula H2C=CHR, wherein R is methyl or a linear or branched alkyl radical C3-C8; said copolymers having a molecular weight distribution with a ratio (I) of less than or equal to 4 and a (b)/(a) molar ratio of more than or equal to 2.3.

公开(公告)号：EP1458661B1

公开(公告)日：2007-05-02

申请号：EP02796762.9

申请日：2002-12-20

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MORINI, Giampiero ,  PIEMONTESI, Fabrizio ,  CRISTOFORI, Antonio ,  MILANI, Stefania

IPC: C07B57/00 ,  C07C67/52 ,  C07C67/60 ,  C07C41/40 ,  C07C41/44 ,  C07C41/46

CPC classification number: C07B57/00

Abstract: Process for modifying the relative ratios of the components of a liquid starting mixture of specific diastereoisomers, containing at least two asymmetric carbon atoms comprising contacting said liquid mixture with a Lewis acid compound capable of co-ordinating said specific diastereoisomers and subjecting the resulting mixture to conditions such that a reaction product, having a molar ratio between its diastereoisomeric components different from the corresponding molar ratio in the said liquid starting mixture, becomes separated from the said liquid mixture, said process being carried out using an amount of said Lewis acid not enough to co-ordinate the total amount of the diastereoisomeric components of the liquid starting mixture. This method shows an excellent balance of efficiency and easiness of procedure that cannot be reached with the physical methods of diastereoisomers separation known in the art.