CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    83.
    发明公开
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化剂组分

    公开(公告)号:EP2601224A1

    公开(公告)日:2013-06-12

    申请号:EP11741457.3

    申请日:2011-08-04

    CPC classification number: C08F4/6494 C08F10/06 C08F4/6465 C08F4/651 C08F4/6543

    Abstract: A catalyst component for the polymerization of olefins comprising Mg, Ti and at least two electron donor compounds, one of which (A) belonging to specific diolesters and the other electron donor compound (B) being selected from aromatic monoesters of the following formula (B) in which R groups equal to or different from each other, are selected from C1-C15 hydrocarbon groups which can be also linked to form one or more cycles, m is an integer from 1 to 5 and R5 is a C1-C15 alkyl group, said electron donors A and B being in amounts such that the A/B molar ratio is lower than 20.

    Abstract translation: 用于烯烃聚合的催化剂组分包含Mg,Ti和至少两种电子给体化合物,其中一种(A)属于特定二酯,另一种给电子体化合物(B)选自下式(B)的芳族单酯 )其中R基团彼此相同或不同,选自可连接形成一个或多个循环的C 1 -C 15烃基,m是1至5的整数,R 5是C 1 -C 15烷基,所述电子给体A和B的量使得A / B摩尔比低于20。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS

    公开(公告)号:EP3448897A1

    公开(公告)日:2019-03-06

    申请号:EP17718105.4

    申请日:2017-04-24

    Abstract: The present disclosure provides a solid catalyst component obtainable by a process including: (a) a first step in which Ti(OEt)4, is reacted with a Mg based compound of formula MgCln(ORI)2-n, where n is from about 0.5 to about 1.5, RI is a C1-C10 alkyl groups, the Ti(OEt)4 and the Mg compound are used in amounts such that the Ti/Mg molar ratio is of about 0.2 to about 0.4, the reaction temperature is about 110 to about 130° C., and the reaction time is about 2 to about 5 hours; and (b) a subsequent step in which the product obtained in step (a) is reacted with a Ti compound of the formula Ti(ORI)4-yCly, where y is a number between 3 and 4.

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