公开(公告)号：US09126888B2

公开(公告)日：2015-09-08

申请号：US14299172

申请日：2014-06-09

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Ryan Hulse ,  Haluk Kopkalli ,  Hang T. Pham

IPC: C09K5/04 ,  C07C21/18 ,  C07C17/38 ,  C07C17/383 ,  C07C17/386 ,  C07C17/389

CPC classification number: C07C21/18 ,  C07C17/38 ,  C07C17/383 ,  C07C17/386 ,  C07C17/389

Abstract: Provided are azeotropic and azeotrope-like compositions of trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)) and water. Such azeotropic and azeotrope-like compositions are useful in isolating trans-1,3,3,3-tetrafluoropropene from impurities during production. Azeotropes of the instant invention are similarly useful in final compositions or for the manufacture of final compositions, such as blowing agent, propellants, refrigerants, diluents for gaseous sterilization and the like.

Abstract translation: 提供了反式-1,3,3,3-四氟丙烯（HFO-1234ze（E））和水的共沸和类共沸组合物。 这种共沸和类共沸组合物可用于在生产过程中从杂质中分离反式-1,3,3,3-四氟丙烯。 本发明的共沸物类似地可用于最终组合物或用于制造最终组合物，例如发泡剂，推进剂，制冷剂，用于气体灭菌的稀释剂等。

公开(公告)号：US20150018429A1

公开(公告)日：2015-01-15

申请号：US14502324

申请日：2014-09-30

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Ryan Hulse ,  Rajiv Ratna Singh ,  Martin R. Paonessa ,  Martin Cheney ,  Hang T. Pham ,  Mary Bogdan ,  Cliff Gittere

IPC: A62D1/00 ,  C09K3/00 ,  C09K21/08 ,  B01F17/00 ,  F28C3/08 ,  C08J9/14 ,  A01N29/02 ,  C10M131/04 ,  F28C3/00 ,  C09K5/04 ,  C09K3/30

CPC classification number: A62D1/0035 ,  A01N29/02 ,  A61L2/18 ,  A62D1/0057 ,  B01F17/0021 ,  B01F17/0035 ,  B01F17/0085 ,  C07C21/18 ,  C08G18/14 ,  C08G18/664 ,  C08G18/6674 ,  C08G18/7671 ,  C08J9/125 ,  C08J9/146 ,  C08J9/149 ,  C08J2201/022 ,  C08J2203/10 ,  C08J2203/162 ,  C08J2205/052 ,  C08J2207/04 ,  C08J2375/08 ,  C09K3/00 ,  C09K3/30 ,  C09K5/044 ,  C09K5/045 ,  C09K21/08 ,  C09K2205/10 ,  C09K2205/102 ,  C09K2205/108 ,  C09K2205/122 ,  C09K2205/126 ,  C09K2205/22 ,  C09K2205/24 ,  C09K2205/32 ,  C10M131/04 ,  C10M2211/022 ,  F25B1/00 ,  F25B31/002 ,  F28C3/005 ,  F28C3/08

Abstract: This invention relates to azeotrope-like compositions, methods and systems having utility in numerous applications, and in particular, uses for azeotrope-like compositions comprising effective amounts of the compound cis-1,1,1,4,4,4-hexafluoro-2-butene (Z-HFO-1336mzzm), which has the following structure: and another material selected from the group consisting of water, fluoroketones, alcohols, hydrochlorofluoroolefins, and combinations of two or more thereof. These compositions may be used in a wide variety of applications such as, blowing agents, refrigerants, heating agents, power cycle agents, cleaning agents, aerosol propellants, sterilization agents, lubricants, flavor and fragrance extractants, flammability reducing agents, and flame suppression agents.

Abstract translation: 本发明涉及在许多应用中有用的类共沸组合物，方法和系统，特别是涉及含有有效量的顺式-1,1,1,4,4,4-六氟 - 具有以下结构的2-丁烯（Z-HFO-1336mzzm）和选自水，氟代酮，醇，氢氯氟烯烃以及其两种或更多种的组合的另一种材料。 这些组合物可以用于各种应用中，例如发泡剂，制冷剂，加热剂，动力循环剂，清洁剂，气溶胶推进剂，灭菌剂，润滑剂，风味和香料萃取剂，可燃性还原剂和阻燃剂 。

公开(公告)号：US20140191153A1

公开(公告)日：2014-07-10

申请号：US14209040

申请日：2014-03-13

Applicant: Honeywell International Inc.

Inventor： Samuel F. Yana Motta ,  Mark W. Spatz ,  Ryan Hulse

IPC: C09K5/04

CPC classification number: C09K5/045 ,  C09K3/30 ,  C09K2205/126 ,  C09K2205/22

Abstract: Heat transfer compositions and methods wherein the compositions have a burning velocity (BV) of less than about 10 and a global warming potential (GWP) of less than about 400 comprising: (a) from, about 0 to about 50% by weight of HFC-32; (b) from about 50% to about 90% by weight of a compound selected from unsaturated —CF3 terminated propenes, unsaturated —CF3 terminated butenes, and combinations of these; and (c) from about 0 to about 25% by weight of a compound selected from HFO-1243zf, HFC-152a, and combinations of these, provided that the combination of components (a) and (c) together comprise at least about 10% by weight of the composition, and further provided that the amount of each of the components (a), (b) and (c) is selected to ensure that the BV of the composition is less than about 10 and the GWP of the composition is less than about 400.

Abstract translation: 传热组合物和方法，其中组合物具有小于约10的燃烧速度（BV）和小于约400的全球变暖潜能值（GWP），包括：（a）约0至约50重量％的HFC -32; （b）约50％至约90％重量的选自不饱和-CF 3封端的丙烯，不饱和-CF 3封端的丁烯及其组合的化合物; 和（c）约0至约25重量％的选自HFO-1243zf，HFC-152a及其组合的化合物，条件是组分（a）和（c）的组合在一起包含至少约10 组分（a），（b）和（c）中的每一种的量被选择以确保组合物的BV小于约10，组合物的GWP 小于约400。

公开(公告)号：US08541634B2

公开(公告)日：2013-09-24

申请号：US13740972

申请日：2013-01-14

Applicant: Honeywell International Inc.

Inventor： Ryan Hulse ,  Hang T Pham

IPC: C07C17/383 ,  C07C17/08 ,  C07C17/38 ,  B01F1/00 ,  B01D3/36 ,  C09K3/00 ,  C09K5/04 ,  C09K3/30 ,  C11D17/00

CPC classification number: C07C17/38 ,  A62D1/0057 ,  B01D3/36 ,  C01B7/191 ,  C07C21/18 ,  C09K3/30 ,  C09K5/044 ,  C11D7/5045

Abstract: Disclosed are azeotropic and azeotrope-like mixtures of (Z)-1-chloro-3,3,3-trifluoropropene (1233zd(Z)) and hydrogen fluoride. Such compositions are useful as an intermediate in the production of 1233zd(Z). The latter compound is useful as a nontoxic, zero ozone depleting fluorocarbon useful as a solvent, blowing agent, refrigerant, cleaning agent, aerosol propellant, heat transfer medium, dielectric, fire extinguishing composition and power cycle working fluid.

Abstract translation: 公开了（Z）-1-氯-3,3,3-三氟丙烯（1233zd（Z））和氟化氢的共沸和类共沸混合物。 这样的组合物可用作1233zd（Z）生产中的中间体。 后一种化合物可用作用作溶剂，发泡剂，制冷剂，清洁剂，气溶胶推进剂，传热介质，电介质，灭火组合物和动力循环工作流体的无毒，无臭氧消耗的碳氟化合物。