公开(公告)号：EP2669349B1

公开(公告)日：2014-06-04

申请号：EP13164559.0

申请日：2013-04-19

Applicant: Rohm and Haas Company

Inventor： Finch, William Christopher ,  Lee, Haksu ,  Rand, Charles James ,  Rodowki, Charles Damien ,  Weinstein, Barry

IPC: C09J179/02 ,  B27N3/00 ,  C03C25/32 ,  C09J103/02 ,  C08L3/02 ,  C08L79/02

CPC classification number: C08L79/02 ,  C08L3/02 ,  C09J103/02 ,  Y10T428/249921

Abstract: The present invention provides thermosetting aqueous binder compositions comprising one or more reducing sugar, one or more diprimary diamine or poly(primary amine), and from 7 to 45 wt.%, based on total solids, of one or more polysaccharide having a dextrose equivalent (DE) value of from 5 to 30. The compositions provide treated articles, such as fiberglass mat. The binders provide articles having a dramatically reduced binder weight loss upon cure and a reduction in cure energy needed to achieve early dry strength.

公开(公告)号：EP1741727B1

公开(公告)日：2012-10-24

申请号：EP06253281.7

申请日：2006-06-23

Applicant: Rohm and Haas Company

Inventor： Clamen, Guy ,  Finch, William C. ,  Weinstein, Barry

IPC: C08F8/14 ,  D04H1/64

CPC classification number: D04H1/645 ,  C03C25/47 ,  C08F8/14 ,  D04H1/4209 ,  D04H1/4218 ,  D04H1/4234 ,  D04H1/4242 ,  D04H1/4258 ,  D04H1/4282 ,  D04H1/4334 ,  D04H1/435 ,  D04H1/587 ,  D04H1/64 ,  D21H13/40 ,  D21H17/38 ,  F16D69/02 ,  Y10T428/24994 ,  Y10T442/20 ,  C08F20/06

Abstract: According to the present invention, water repellant curable compositions comprise: (i) one or more polyacid comprising at least two carboxylic acid groups, anhydride groups, or salts thereof; (ii) one or more polyol comprising at least two hydroxyl groups; (iii) one or more reactive waterproofing agent chosen from a C 5 to C 30 alk(en)yl 2-hydroxyethyl (alk(en))amide, C 5 to C 30 alk(en)yl bis(2-hydroxyethyl) amide, C 11 to C 30 alk(en)yl 2-hydroxyethyl (alk(en))amine, C 11 to C 30 alk(en)yl bis(2-hydroxyethyl) amine, C 11 to C 30 alk(en)yl tris(2-hydroxyethyl) amine, C 5 to C 30 alk(en)yl monoglyceride, C 5 to C 30 alk(en)yl monocarboxylate of a trihydric polyol, and mixtures thereof, and, (iv), optionally, one or more phosphorous-containing accelerator, wherein the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof to the total number of equivalents of said hydroxyl groups is from 1/0.01 to 1/3. The compositions provide concentrates dilutable with water to make thermosetting aqueous binder compositions. Further, the present invention provides methods of treating or contacting substrates chosen from a non-woven, woven and a composite, such as glass fiber substrates, with the thermosetting aqueous binder compositions, and drying and curing, as well as water resistant products produced thereby.

公开(公告)号：EP1584235B1

公开(公告)日：2012-10-24

申请号：EP05251894.1

申请日：2005-03-29

Applicant: ROHM AND HAAS COMPANY

Inventor： Ghosh, Tirthankar ,  Weinstein, Barry

IPC: A01N59/16 ,  A01N43/50 ,  A01N43/36 ,  A01N25/10

CPC classification number: A01N59/16 ,  A01N25/22 ,  C11D3/168 ,  C11D3/3776 ,  C11D3/48 ,  D06M11/83 ,  D06M15/263 ,  D06M15/3562 ,  D06M16/00 ,  D06M2101/32 ,  A01N25/10 ,  A01N43/50 ,  A01N2300/00 ,  A01N25/34

公开(公告)号：EP2395035A1

公开(公告)日：2011-12-14

申请号：EP11168583.0

申请日：2011-06-02

Applicant: Rohm and Haas Company ,  Dow Global Technologies LLC

Inventor： Bailey, Brad C. ,  Sammler, Robert L. ,  Timmers, Francis J. ,  Jeon, Hyun K. ,  Finch, William C. ,  Rand, Charles C. ,  Weinstein, Barry

IPC: C08G12/06 ,  C09J161/20 ,  C09J161/32 ,  C09J179/04

CPC classification number: C08L79/02 ,  C08G12/34 ,  C09J161/26 ,  C09J161/32

Abstract: The present invention provides thermosetting aqueous binder compositions of one or more cyclic enamine, including bis-enamines and di- or higher functional enamines, optionally containing a water soluble or dispersible or dispersible primary amine compound. The binders are at least substantially formaldehyde free, need no polycarboxylic or polycarboxylate component, and yet provide excellent hot wet tensile strength when cured for as little time as a minute or less in use.

Abstract translation: 本发明提供的一种或多种环烯胺，包括二 - 烯胺和二 - 或更高官能的烯胺热固性粘合剂组合物wässrige，任选地含有一种水溶性或可分散的或可分散的伯胺化合物。 的粘合剂是至少基本上不含甲醛的，没有必要的多元或多羧酸盐组分，并且还提供优异的热湿拉伸强度当固化时，因为没有时间在使用一分钟或更少。

公开(公告)号：EP2223940A1

公开(公告)日：2010-09-01

申请号：EP10152290.2

申请日：2010-02-01

Applicant: Rohm and Haas Company

Inventor： Kelly, Michael Dewayne ,  Weinstein, Barry ,  Lee, Haksu

IPC: C08B37/00 ,  C08L5/00 ,  C03C25/32

CPC classification number: C08L5/00 ,  C08B37/0006

Abstract: A curable aqueous binder composition comprising one or more amine reactant selected from the group consisting of: a protein, a peptide, an amino acid, an ammonium salt of a polycarboxylic acid, an ammonium salt of a (poly)hydroxy-(poly)carboxylic acid; one or more carbohydrate; and one or more emulsion polymer; and the use thereof as thermosetting binders. Also described are composite materials comprising the curable binder composition, and methods of application.

Abstract translation: 一种可固化水性粘合剂组合物，其包含一种或多种胺反应物，其选自：多元羧酸的蛋白质，肽，氨基酸，铵盐，（聚）羟基 - （多）羧酸的铵盐 酸; 一种或多种碳水化合物; 和一种或多种乳液聚合物; 及其作为热固性粘合剂的用途。 还描述了包含可固化粘合剂组合物和应用方法的复合材料。

公开(公告)号：EP2060561A1

公开(公告)日：2009-05-20

申请号：EP08168064.7

申请日：2008-10-31

Applicant: Rohm and Haas Company

Inventor： Banavali, Rajiv Manohar ,  Chheda, Bharati Dinkar ,  Weinstein, Barry

IPC: C07C291/02

CPC classification number: C07C291/02 ,  C10L1/22 ,  C10L1/23 ,  C10L10/00 ,  C10M133/22 ,  C10M2215/14 ,  C10N2230/10

Abstract: A method for producing a nitrone of formula (I)

wherein R is a branched alkyl group having from four to thirty carbon atoms; R 1 , R 2 , R 3 and R 4 independently are hydrogen or alkyl groups having from one to six carbon atoms from an imine having formula (II)

Abstract translation: 一种制备式（I）的硝酮的方法，其中R是具有4-30个碳原子的支链烷基; R 1，R 2，R 3和R 4独立地是氢或具有1至6个碳原子的具有式（II）的亚胺的烷基，

公开(公告)号：EP1584236A2

公开(公告)日：2005-10-12

申请号：EP05252122.6

申请日：2005-04-05

Applicant: ROHM AND HAAS COMPANY

Inventor： Cottrell, Stephanie N. ,  Ghosh, Tirthankar ,  Weinstein, Barry

IPC: A01N59/16 ,  A01N25/34 ,  A01N43/36 ,  A01N43/50 ,  D06M11/83 ,  D06M15/21

CPC classification number: A01N59/16 ,  Y10T442/2525 ,  Y10T442/277 ,  Y10T442/2861 ,  Y10T442/60 ,  A01N43/50 ,  A01N25/34 ,  A01N25/10 ,  A01N2300/00

Abstract: Treated fiber substrates and methods of making and using the same are disclosed. The disclosed treated fiber substrates provide persistent, durable, broad spectrum, antimicrobial activity. The treated fiber substrates may be used in a variety of materials to impart antimicrobial activity thereto.

Abstract translation: 处理过的纤维基材以及制备和使用它们的方法是游离缺失光盘。 盘处理游离缺失纤维基材提供持久，坚固耐用，广谱抗微生物活性。 经处理的纤维基底可以以各种材料可用于赋予其抗微生物活性。

公开(公告)号：EP1580199A1

公开(公告)日：2005-09-28

申请号：EP05251359.5

申请日：2005-03-07

Applicant: ROHM AND HAAS COMPANY

Inventor： Bromm, Karl Alen ,  Tang, Xun ,  Weinstein, Barry

IPC: C08F8/14

CPC classification number: C08F8/14 ,  C08F220/06 ,  C08F20/00

Abstract: A curable composition including a compound, containing as polymerized units, carboxylic acid groups, anhydride groups, or salts thereof, and a styrene, α-methyl styrene, butyl (meth)acrylate, methyl methacrylate, ethyl (meth)acrylate, mono-alkyl (meth)acrylamide, or di-alkyl (meth)acrylamide ethylenically unsaturated monomer having a solubility in water of less than 2 g/100 g water at 25°C; wherein the compound is either admixed with or copolymerized with a hydroxyl group-containing compound; the curable composition contains from about 3 to about 25 weight percent, based on the total weight of monomers in the curable composition, of the ethylenically unsaturated monomer; the ratio of the number of equivalents of the carboxylic acid groups, anhydride groups, or salts thereof to the number of equivalents of the hydroxyl groups is from about 1/0.01 to about 1/3, is provided. Also provided is a method for treating a substrate with the curable composition, articles prepared by the method of the invention.

公开(公告)号：EP1506977A1

公开(公告)日：2005-02-16

申请号：EP04254650.7

申请日：2004-08-02

Applicant: Rohm and Haas Company

Inventor： Blankenship, Robert Mitchell ,  Bromm, Karl Allen ,  Gappert, Griffin Melaney ,  Tang, Xun ,  Weinstein, Barry

IPC: C08J3/24 ,  C09J129/02 ,  C09J133/00 ,  C08G81/02

CPC classification number: C09D133/08 ,  C08L33/066 ,  C09D129/02 ,  C09D129/06 ,  Y10T428/31504 ,  Y10T428/31855

Abstract: A curable composition including a polymer comprising, as copolymerized units, a monomer having carboxylic acid groups, anhydride groups, or salts thereof, and at least one of certain hydroxyl group-comprising monomers wherein the ratio of the number of equivalents of the carboxylic acid groups, anhydride groups, or salts thereof to the number of equivalents of the hydroxyl groups is from about 1/0.01 to about 1/3, and wherein the carboxylic acid groups, anhydride groups, or salts thereof are neutralized to an extent of less than about 35% with a fixed base is provided. Also provided is a method for treating a substrate with the curable composition and a substrate bearing the cured composition.

Abstract translation: 一种包含聚合物的可固化组合物，其包含作为共聚单元的具有羧酸基团的单体，酸酐基团或其盐以及某些含羟基的单体中的至少一种，其中羧酸基团的当量数 ，酸酐基团或其盐与羟基当量的数目为约1 / 0.01至约1/3，并且其中羧酸基团，酸酐基团或其盐被中和至小于约 提供35％的固定基座。 还提供了一种用可固化组合物处理基材的方法和具有固化组合物的基材。

公开(公告)号：EP0785422B1

公开(公告)日：2005-01-05

申请号：EP97300222.3

申请日：1997-01-15

Applicant: ROHM AND HAAS COMPANY

Inventor： Fu, Zhenwen ,  Keller, Lorraine Holowach ,  Weinstein, Barry

IPC: G01N21/64 ,  C08F8/32

CPC classification number: G01N33/533 ,  C02F1/56 ,  C02F5/10 ,  C08F2/38 ,  C08F8/30 ,  C08F8/32 ,  C08F8/34 ,  C11D3/3769