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    Novel alpha-oxygenated or alpha-thiolated carboxylic acid penethylamide derivatives
    81.
    发明专利
    Novel alpha-oxygenated or alpha-thiolated carboxylic acid penethylamide derivatives 未知

    公开(公告)号：AU2002363599B2

    公开(公告)日：2006-09-28

    申请号：AU2002363599

    申请日：2002-11-15

    Applicant: SYNGENTA PARTICIPATIONS AG

    Inventor： ZELLER MARTIN ,  KRIZ MIROSLAV ,  LAMBERTH CLEMENS

    IPC: C07C235/34 ,  C07D237/08 ,  A01N20060101 ,  A01N37/18 ,  A01N37/36 ,  A01N37/38 ,  A01N37/42 ,  A01N41/10 ,  A01N41/12 ,  A01N43/00 ,  C07C20060101 ,  C07C231/02 ,  C07C237/20 ,  C07C317/22 ,  C07C323/22 ,  C07C323/58 ,  C07C323/63 ,  C07C327/44 ,  C07D213/24 ,  C07D213/60 ,  C07D215/06 ,  C07D215/08 ,  C07D237/10 ,  C07D239/26 ,  C07D239/28 ,  C07D241/12 ,  C07D241/14 ,  C07D261/08 ,  C07D261/10 ,  C07D277/20 ,  C07D277/22 ,  C07D277/32 ,  C07D307/38 ,  C07D307/56 ,  C07D307/78 ,  C07D317/50 ,  C07D317/62 ,  C07D319/18 ,  C07D333/06 ,  C07D333/26

    Abstract: The invention relates to ±-oxygenated or ±-thiolated carboxylic acid phenethylamide derivatives of the general formula I including the optical isomers thereof and mixtures of such isomers, wherein A stands for optionally substituted aryl or optionally substituted heteroaryl; X is oxygen or sulfur; Y is oxygen or sulfur; R 1 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, haloalkenyl, haloalkynyl or halocycloalkyl; R 2 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkyl-alkyl, alkoxy-alkyl, alkoxy-alkenyl, alkoxy-alkynyl, whereof all alkyl- alkenyl-, alkynyl-, or cycloalkyl-groups me be optionally substituted by halogen; or optionally substituted aryl-alkyl, optionally substituted aryl-alkenyl, optionally substituted aryl-alkynyl or optionally substituted aryloxy-alkyl; R 3 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkyl-alkyl, alkoxy-alkyl, alkoxy-alkenyl, alkoxy-alkynyl, whereof all alkyl- alkenyl-, alkynyl-, or cycloalkyl-groups me be optionally substituted by halogen; or is optionally substituted aryl-alkyl, optionally substituted aryl-alkenyl, optionally substituted aryl-alkynyl, optionally substituted aryloxy-alkyl, optionally substituted heteroaryl-alkyl, optionally substituted heteroaryl-alkenyl or optionally substituted heteroaryl-alkynyl; R 4 is alkyl, alkenyl, alkynyl, alkoxy-alkyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, alkanoyl, alkylamino, dialkylamino, alkoxycarbonyl, whereof all alkyl- alkenyl or alkynyl-groups me be optionally substituted by halogen; or is halogen, cyano, nitro, amino, formyl or carboxyl; R 5 is hydrogen, alkyl, alkenyl or alkynyl; n is an integer 0,1, 2, 3, or 4; B 1 represents a bridge member -(CR 10 R 11 ) q - or -(CHR 10 R 11 ) r -Z-(CR 12 R 13 ) s , wherein q is an integer 2, 3 or 4; r is an integer 0, 1, 2, 3; s is an integer 1, 2 or 3, provided that (r + s) is either 1, 2 or 3; Z is -O-, -S-, -SO- -SO 2 -, NR 6 -, -CO-, -OOC-, -COO-, -NR 6 -CO- or -CO-NR 6 - ; R 6 is hydrogen or alkyl ; R 10 , R 11 , R 12 and R 13 independently of each other are hydrogen or alkyl ; and B 2 is an alkylene bridge. These compounds possess useful plant protecting properties and may advantageously be employed in agricultural practice for controlling or preventing the infestation of plants by phytopathogenic microorganisms, especially fungi.

    NOVEL $G(A)-OXYGENATED OR $G(A)-THIOLATED CARBOXYLIC ACID PHENETHYLAMIDE DERIVATIVES
    85.
    发明专利
    NOVEL $G(A)-OXYGENATED OR $G(A)-THIOLATED CARBOXYLIC ACID PHENETHYLAMIDE DERIVATIVES 未知

    公开(公告)号：PL368419A1

    公开(公告)日：2005-03-21

    申请号：PL36841902

    申请日：2002-11-15

    Applicant: SYNGENTA PARTICIPATIONS AG

    Inventor： ZELLER MARTIN ,  LAMBERTH CLEMENS

    IPC: C07D237/08 ,  A01N37/18 ,  A01N37/36 ,  C07C231/12 ,  C07C235/34 ,  C07C253/30 ,  C07C255/59 ,  C07C319/20 ,  C07C323/62 ,  C07C327/44 ,  C07D213/30 ,  C07D213/61 ,  C07D215/14 ,  C07D237/12 ,  C07D239/26 ,  C07D239/30 ,  C07D241/12 ,  C07D261/08 ,  C07D277/24 ,  C07D307/42 ,  C07D307/44 ,  C07D317/54 ,  C07D319/18 ,  C07D333/16

    Abstract: The invention relates to α-oxygenated or α-thiolated carboxylic acid phenethylamide derivatives of general formula (I) including the optical isomers thereof and mixtures of such isomers, wherein A stands for optionally substituted aryl or optionally substituted heteroaryl; X is oxygen or sulfur; Y is oxygen or sulfur; R1, is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, haloalkenyl, haloalkynyl or halocycloalkyl; R2 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, alkoxy-alkyl, alkoxy-alkenyl, alkoxy-alkynyl, whereof all alkyl- alkenyl-, alkynyl-, or cycloalkyl-groups may be optionally substituted by halogen; or optionally substituted aryl-alkyl, optionally substituted aryl-alkenyl, optionally substituted aryl-alkynyl or optionally substituted aryloxy-alkyl; R3 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkyl-alkyl, alkoxy-alkyl, alkoxy-alkenyl, alkoxy-alkynyl, whereof all alkyl- alkenyl-, alkynyl-, or cycloalkyl-groups may be optionally substituted by halogen; or is optionally substituted aryl-alkyl, optionally substituted aryl-alkenyl, optionally substituted aryl-alkynyl, optionally substituted aryloxy-alkyl, optionally substituted heteroaryl-alkyl, optionally substituted heteroaryl-alkenyl or optionally substituted heteroaryl-alkynyl; R4 is alkyl, alkenyl, alkynyl, alkoxy-alkyl, alkoxy, alkenyloxy, alkenyloxy, alkylthio, alkanoyl, alkylamino, dialkylamino, alkoxycarbonyl, whereof all alkyl- alkenyl or alkynyl-groups may be optionally substituted by halogen; or is halogen, cyano, nitro, amino, formyl or carboxyl; R5 is hydrogen, alkyl, alkenyl or alkynyl; n is an integer 0, 1, 2, 3, or 4; B, represents a bridge member —CR10R11—, wherein R10 and R11 independently of each other are hydrogen or alkyl; and B2 is an alkylene bridge. These compounds possess useful plant protecting properties and may advantageously be employed in agricultural practice for controlling or preventing the infestation of plants by phytopathogenic microorganisms, especially fungi.

    86.
    发明专利
    未知

    公开(公告)号：ES2219090T3

    公开(公告)日：2004-11-16

    申请号：ES99961032

    申请日：1999-12-01

    Applicant: SYNGENTA PARTICIPATIONS AG

    Inventor： ZELLER MARTIN ,  JEANGUENAT ANDRE ,  LAMBERTH CLEMENS

    IPC: A01N41/06 ,  C07B61/00 ,  C07C303/34 ,  C07C303/38 ,  C07C303/40 ,  C07C307/06 ,  C07C311/06 ,  C07C311/11 ,  C07C323/12 ,  C07C311/00

    Abstract: The invention relates to alpha-sulfin- and alpha-sulfonamino acid amides of the general formula Iincluding the optical isomers thereof and mixtures of such isomers,whereinn is a number zero or one;R1 is C1-C12alkyl, C1-C12alkyl substituted with C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylsulfonyl, C3-C8cycloalkyl, cyano, C1-C6alkoxycarbonyl, C3-C6alkenyloxycarbonyl or C3-C6alkynyloxycarbonyl; C3-C8cycloalkyl; C2-C12alkenyl; C2-C12alkynyl; C1-C12haloalkyl; or a group NR12R13 wherein R12 and R13 are each independently of the other hydrogen or C1-C6-alkyl, or together are tetra- or penta-methylene;R2 and R3 are each independently hydrogen; C1-C8alkyl; C1-C8alkyl substituted with hydroxy, mercapto, C1-C4alkoxy or C1-C4alkylthio; C3-C8alkenyl; C3-C8alkynyl; C3-C8cycloalkyl; C3-C8cycloalkyl-C1-C4alkyl; or the two groups R2 and R3 together with the carbon atom to which they are bonded form a three- to eight-membered hydrocarbon ring;R4, R5, R6 and R7 are each independently hydrogen or C1-C4alkyl;R8 is C1-C6alkyl, C3-C6alkenyl or C3-C6alkynyl;R9 and R10 are each independently hydrogen or C1-C4alkyl; andR11 is either in whereinR14, R,15, R16 and R17 are each independently hydrogen or C1-C4alkyl,X is oxygen, sulfur or -NR18-, wherein R18 is hydrogen or C1-C4alkyl, andA is optionally substituted mono- or polycylic aryl or heteroaryl, andto the preparation of those substances and to agrochemical compositions comprising at least one of those compounds as active ingredient. The invention relates also to the preparation of compositions and to the use of the compounds or of the compositions in controlling or preventing the infestation of plants by phytopathogenic microorganisms, especially fungi.

    87.
    发明专利
    未知

    公开(公告)号：ES2217194T3

    公开(公告)日：2004-11-01

    申请号：ES01980366

    申请日：2001-09-10

    Applicant: SYNGENTA PARTICIPATIONS AG

    Inventor： NUNINGER COSIMA ,  ZELLER MARTIN

    IPC: C07C311/06 ,  A01N37/18 ,  A01N37/22 ,  A01N37/34 ,  A01N37/50 ,  A01N41/06 ,  A01N43/36 ,  A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N43/56 ,  A01N43/828 ,  A01N43/84 ,  A01N47/14

    Abstract: It has now been found that the use of: A) a N-sulfonyl-valine-amide of formula (I) wherein R1 is hydrogen, C1-4alkyl, C3-6cycloalkyl or halophenyl, and R2 is C1-4alkyl; in association with B) either compounds of formulae II to XII is particularly effective in combating or preventing fungal diseases of crop plants. These combinations exhibit synergistic fungicidal activity. Prominent examples for the compounds of formulae II to XII are: acibenzolar-S-methyl, azoxystrobin, chlorothalonil, cymoxanil, dimethomorph, fluazinam, fludioxonil, imazalil, S-imazalil, mancozeb, metalaxyl, metalaxyl-M, picoxystrobin, pyraclostrobin (BAS 500F) and trifloxystrobin.

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