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公开(公告)号:JPH0243261A
公开(公告)日:1990-02-13
申请号:JP19401688
申请日:1988-08-02
Applicant: TORAY INDUSTRIES
Inventor: KUBO YASUSHI , KADOI AKIRA , MATSUOKA HIDEO
Abstract: PURPOSE:To obtain the title composition excellent in impact resistance, heat resistance and flow by blending an aromatic polythioether sulfone resin, with a silicic filler and a fibrous filler. CONSTITUTION:This composition is constituted of 30-90wt.% aromatic polythioether sulfone resin having repeating units of the formula, an inherent viscosity of, desirably, 0.2-0.7 (solvent: N-methylpyrrolidone, concentration: 0.5g/dl, temperature: 25 deg.C), desirably treated with an acid (e.g., an aqueous acetic acid solution at a pH of 4) or washed with hot water and having an Na content
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公开(公告)号:JPH01118571A
公开(公告)日:1989-05-11
申请号:JP27651187
申请日:1987-10-30
Applicant: TORAY INDUSTRIES
Inventor: KUBO YASUSHI , MATSUOKA HIDEO , KADOI AKIRA
Abstract: PURPOSE:To obtain the above composition of excellent adhesion to metal without detriment to its flow, by mixing a polyphenylene sulfide resin with a specified isocyanate compound. CONSTITUTION:100pts.wt. polyphenylene sulfide resin (A) treated with an acid, washed with hot water or an organic solvent (e.g., N-methylpyrrolidone) or having an Na content
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公开(公告)号:JP2003165535A
公开(公告)日:2003-06-10
申请号:JP2001361867
申请日:2001-11-28
Applicant: TORAY INDUSTRIES
Inventor: HAMAGUCHI MITSUSHIGE , MATSUOKA HIDEO , KOBAYASHI KAZUHIKO
IPC: B65D6/14 , B29C45/16 , B29C65/02 , B29K23/00 , B29K67/00 , B29L22/00 , B32B1/02 , B32B27/32 , B32B27/36 , C08L23/00 , C08L67/00
Abstract: PROBLEM TO BE SOLVED: To provide a multilayer hollow container having the high degree of freedom of a container design and having favorable barrier properties, interlaminar adhesion, and mechanical characteristics, and a method for manufacturing the multilayer hollow container. SOLUTION: The multilayer hollow container has a barrier layer which is formed of a resin composition consisting of (a) a polyolefin resin and (b) a polyester resin, and a thermoplastic resin layer which is formed of a thermoplastic resin other than the resin composition forming (c) the barrier layer. The multilayer hollow container has a welded portion at a part of the hollow container, and the strength of the welded portion is 60% or more of that of a non-welded portion. COPYRIGHT: (C)2003,JPO
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公开(公告)号:JP2003127304A
公开(公告)日:2003-05-08
申请号:JP2001329953
申请日:2001-10-26
Applicant: TORAY INDUSTRIES
Inventor: MATSUOKA HIDEO , HAMAGUCHI MITSUSHIGE , KOBAYASHI KAZUHIKO
IPC: B65D1/00 , B29C45/16 , B29K23/00 , B29K77/00 , B29K81/00 , B29L22/00 , B32B1/02 , B32B27/34 , B65D1/09 , C08L77/00 , C08L81/02
Abstract: PROBLEM TO BE SOLVED: To provide a hollow multi-layer container having barrier properties, which is excellent in degree of freedom in design of a container, barrier properties, interlayer bonding properties and mechanical properties. SOLUTION: The hollow multi-layered container has a thermoplastic resin layer made up of (a) a polyphenylene sulfide resin, (b) a barrier layer formed of a resin composition made up of polyamide resin, (c) a thermoplastic resin layer made up of a thermoplastic resin other than a resin composition forming the barrier layer, wherein the hollow multi-layer container having barrier properties has a welding part in one part thereof with the strength of the welding part being 60% or more of that of the non-welded part.
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公开(公告)号:JP2002241546A
公开(公告)日:2002-08-28
申请号:JP2001045923
申请日:2001-02-22
Applicant: TORAY INDUSTRIES
Inventor: MATSUOKA HIDEO , HAMAGUCHI MITSUSHIGE , KOBAYASHI KAZUHIKO
Abstract: PROBLEM TO BE SOLVED: To obtain a member for fuel treatment for controlling reduction in properties such as toughness, molding processability, etc., being essential characteristics of a polyolefin resin, having specifically improved characteristics of permeation resistance of chemical and gas, preferably useful for a fuel container for automobile, etc., and auxiliary parts uses such as a connection part, a piping, etc., thereof. SOLUTION: This member for fuel treatment is characterized in that the member comprises a resin composition composed of (a) 55-80 vol.% of a polyolefin resin and (b) 45-20 vol.% of an ethylene-vinyl alcohol copolymer and forms a phase structure where (b) the ethylene-vinyl alcohol copolymer forms a matrix phase (continuous phase) and (a) and polyolefin resin forms a dispersion phase in a resin phase separation structure observed by an electron microscope.
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公开(公告)号:JP2002069273A
公开(公告)日:2002-03-08
申请号:JP2000254754
申请日:2000-08-25
Applicant: TORAY INDUSTRIES
Inventor: HAMAGUCHI MITSUSHIGE , MATSUOKA HIDEO , KOBAYASHI KAZUHIKO
Abstract: PROBLEM TO BE SOLVED: To provide a resin structure and a molded article which have resistance to gas and/or liquid permeability even under high humidity and, in addition, have excellent properties on absorbing water by preventing the change in dimension and the deterioration of the mechanical properties such as rigidity due to moisture absorption. SOLUTION: The resin structure is constituted by a resin composition substantially comprising (a) a polyester resin and (b) a polyphenylene sulfide resin(PPS resin) at a specific ratio and, simultaneously, the PPS resin layer being allowed to have a special structure such as a continuous phase and a belt-shaped dispersion phase as the resin phase separation structure to be observed in the resin composition by an electron microscope.
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公开(公告)号:JP2001302918A
公开(公告)日:2001-10-31
申请号:JP2000311404
申请日:2000-10-12
Applicant: TORAY INDUSTRIES
Inventor: MATSUOKA HIDEO , HAMAGUCHI MITSUSHIGE , KOBAYASHI KAZUHIKO
IPC: B65D1/00 , B29C45/00 , B29C47/04 , B32B27/00 , B32B27/34 , B65D1/09 , C08J5/00 , C08K3/00 , C08L77/00 , C08L81/02
Abstract: PROBLEM TO BE SOLVED: To provide a thermoplastic resin structure having gas and/or liquid permeation resistances even in use under high humidity and, in addition, excellent properties upon water absorption which have inhibited lowering in mechanical properties such as change in dimension and rigidity by moisture absorption, a laminated structure which gives a plastic container and a tubular body having excellent barrier properties, durability, and molding processability as well, and also provide its use. SOLUTION: The thermoplastic resin structure is composed substantially of a resin composition comprising (a) 5-80 vol.% polyamide resin and (b) 95-20 vol.% polyphenylene sulfide resin and, at the same time, forms a phase structure such that the polyphenylene sulfide resin (b) comes to a matrix phase (a continuous phase) and the polyamide resin (a) comes to a dispersion phase in the resin phase separation structure to be observed by an electron microscope.
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公开(公告)号:JP2001019823A
公开(公告)日:2001-01-23
申请号:JP19236699
申请日:1999-07-06
Applicant: MITSUI CHEMICALS INC , TORAY INDUSTRIES
Inventor: TODO AKIRA , MATSUNAGA SHINYA , MATSUOKA HIDEO , MIYAMOTO KAZUKI , KOBAYASHI KAZUHIKO
Abstract: PROBLEM TO BE SOLVED: To obtain a resin composition which can give moldings excellent in impact strength, gloss, solvent resistance, and water absorption by mixing a cycloolefin resin with a graft-modified cycloolefin resin, an elastomer, and a polyamide in a specified ratio. SOLUTION: This composition comprises 0-59.5 pts.wt. (A) cycloolefin resin, 0.5-60 pts.wt. (B) cycloolefin resin graft-modified with an unsaturated carboxylic acid or its derivative, 2-30 pts.wt. (C) elastomer modified with an unsaturated carboxylic acid or its derivative and having a tensile modulus of 0.01-200 MPa, and 20-60 pts.wt. (D) polyamide in which there is a specified difference between the concentrations of specified types of terminal groups and which is represented by formula I. Component A is at least one member selected from a ring-opening polymer of a single cycloolefin, represented by formula II, a ring-opening polymer of at least two cycloolefins, products obtained by the hydrogenation of them, and an ethylene/cycloolefin copolymer. In formula I, R1 to R18, Ra, and Rb are each hydrogen, a hydrocarbon group, or the like; n and q are each 0 or 1; and m is 0 or a positive integer.
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公开(公告)号:JP2000327912A
公开(公告)日:2000-11-28
申请号:JP26547799
申请日:1999-09-20
Applicant: TORAY INDUSTRIES , MITSUI CHEMICALS INC
Inventor: MATSUOKA HIDEO , MIYAMOTO KAZUKI , OKITA SHIGERU , TODO AKIRA , MATSUNAGA SHINYA
Abstract: PROBLEM TO BE SOLVED: To produce the subject structure excellent in low water absorptivity, dimensional stability when absorbing moisture, rigidity, toughness and moldability and useful for automotive parts, electrical and electronic parts, etc., by including a polyamide resin and a polyolefin. SOLUTION: This structure is obtained by including (A) 55-80 vol.% of a polyamide resin (e.g. nylon 6 resin) and (B) 45-20 vol.% of a polyolefin. The polyolefin forms a matrix phase and the polyamide resin forms a dispersed phase in the phase separation structure of the structure observed under an electron microscope. Furthermore, a fibrous or a nonfibrous inorganic filler or both in an amount of 1-150 pts.wt. based on 100 pts.wt. of the sum of the components A and B are preferably contained. The polyolefin is preferably a modified polyolefin prepared by modifying polypropylene with an unsaturated carboxylic acid anhydride (e.g. maleic anhydride). The ratio of the melt viscosity of the components A to B under conditions of =1.5.
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公开(公告)号:JPH11343404A
公开(公告)日:1999-12-14
申请号:JP15339398
申请日:1998-06-02
Applicant: TORAY INDUSTRIES
Inventor: MATSUOKA HIDEO , OKITA SHIGERU
IPC: C08J5/12 , B29C65/06 , B29K77/00 , B29K105/06 , C08K3/32 , C08K5/02 , C08K5/49 , C08K7/14 , C08L77/00
Abstract: PROBLEM TO BE SOLVED: To obtain a flame retardant nylon resin composition excellent even in characteristics essential to nylon resins such as moldability, heat resistance, toughness and oil, gasoline and abrasion resistances in equilibrium and suitable for vibration welding. SOLUTION: This component comprises (B) a phosphorus-based flame retardant and/or a halogen-based flame retardant having >=1,000 number-average molecular weight calculated by a gel permeation chromatography(GPC) in an amount of 0.1-50 pts.wt. based on (A) 100 pts.wt. of a nylon resin, (C) glass fibers in an amount of 10-150 pts.wt. based on (A) 100 pts.wt. of the nylon resin and (D) a flame retardant assistant in an amount of 0-50 pts.wt. based on (A) 100 pts.wt. of the nylon resin therein and further has the characteristics thereof within the following ranges: [LOI improvement ratio] × [welding strength retention ratio] >=1.00 and 1.05
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