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公开(公告)号:JPS63120168A
公开(公告)日:1988-05-24
申请号:JP26365286
申请日:1986-11-07
Applicant: UBE INDUSTRIES
Inventor: YAMAMURA TAKETAMI , ISHIKAWA TOSHIHIRO , SHIBUYA MASAKI
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公开(公告)号:JPS62297426A
公开(公告)日:1987-12-24
申请号:JP13929886
申请日:1986-06-17
Applicant: UBE INDUSTRIES , TOYOTA CENTRAL RES & DEV
Inventor: YAMADA SENICHI , TOWATA SHINICHI , YAMAMURA TAKETAMI , ISHIKAWA TOSHIHIRO , SHIBUYA MASAKI
IPC: C22C47/08 , C22C21/00 , C22C47/00 , C22C47/12 , C22C49/00 , C22C49/04 , C22C49/06 , D01F9/10 , D06M11/00 , D06M11/77 , D06M23/08 , D06M23/10 , D06M101/00
Abstract: PURPOSE:To provide the titled reinforced metallic composite having improved mechanical characteristics such as anisotropy, residual stress and wear resistance by reinforcing the metal with continuous inorg. fibers consisting of Si, Ti, or Zr, C and O and short fibers, etc., of a heat resistant material interposed among said fibers. CONSTITUTION:The continuous inorg. fibers which consist of an amorphous material composed of Si, M (M is Ti or Zr), C and O or solid soln. such as beta-SiC or MC and/or respective ultrafine crystalline particles and aggregate, etc., of amorphous SiO2 and MO2 and contain Si, M, C and O are prepd. Said continuous inorg. fibers and a fibrous body consisting of the short fibers, whiskers or powder of the heat resistant material such as SiC, SiN or alumina interposed among the spaces of said inorg. fibers or the woven fabric thereof are then disposed in the cavity of a casting mold. The melt of a base material metal such as Al alloy or MC alloy is poured in this state into the cavity and is then cooled to solidify. The inorg. fiber-reinforced metal (FRM) composite is thus obtd.
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公开(公告)号:JPS62297425A
公开(公告)日:1987-12-24
申请号:JP13929686
申请日:1986-06-17
Applicant: UBE INDUSTRIES , TOYOTA CENTRAL RES & DEV
Inventor: YAMADA SENICHI , TOWATA SHINICHI , YAMAMURA TAKETAMI , ISHIKAWA TOSHIHIRO , SHIBUYA MASAKI
IPC: C22C47/08 , C22C21/00 , C22C47/00 , C22C49/00 , C22C49/06 , D01F9/10 , D06M11/00 , D06M11/83 , D06M101/00
Abstract: PURPOSE:To provide a fiber-reinforced metal which has overall excellent mechanical characteristics by consisting the same of continuous inorg. fibers consisting of Si, Ti or Zr, C and O and an Al alloy base material contg. a prescribed ratio of Ni and incorporating the needle-like phase of said alloy into said Al base material. CONSTITUTION:The continuous inorg. fibers which consist of an amorphous material substantially composed of Si, M, C and O, or solid soln. such as beta-SiC, MC (M is Ti or Zr) and/or respective ultrafine crystalline particles and aggregate, etc., consisting of amorphous SiO2 and MO2 and consist of Si, Ti, or Zr, C and O are prepd. Such continuous inorg. fibers and the Al alloy member contg. 0.5-6wt% Ni are combined by a casting method, more particularly high-pressure casting method and are solidified in a short period. The combined material is cooled from the direction orthogonal with the continuous fibers in the stage of such solidification, by which the fine needle-like crystalline material is crystallized in entanglement with said fibers in the direction perpendicular to the fibers among the continuous fibers, by which the excellent inter- layer shearing strength is imparted. As a result, the fiber-reinforced metal (FRM) having high strength is obtd.
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公开(公告)号:JPS62267329A
公开(公告)日:1987-11-20
申请号:JP11047186
申请日:1986-05-15
Applicant: UBE INDUSTRIES
Inventor: YAMAMURA TAKETAMI , ISHIKAWA TOSHIHIRO , SHIBUYA MASAKI
Abstract: PURPOSE:To obtain the titled composite material having excellent mechanical properties and transparency, by reinforcing a plastic material with an inorganic fiber having a core layer and a skin layer and composed of a specific inorganic substance containing Si, Ti, Zr, O and C. CONSTITUTION:The objective composite material is reinforced with an inorganic fiber composed of (A) a core layer consisting of an inorganic substance containing Si, Ti, Zr, C and O and composed of (i) an amorphous substance composed of Si, M (M is Ti or Zr), C and O or (ii) an agglomerate of crystalline ultra-fine particles of beta-SiC, MC, a solid solution of beta-SiC and MC and/or MC having particle diameter of
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85.
公开(公告)号:JP2003226582A
公开(公告)日:2003-08-12
申请号:JP2002029616
申请日:2002-02-06
Applicant: UBE INDUSTRIES
Inventor: YAMAOKA HIROYUKI , HARADA YOSHIKATSU , FUJII TERUAKI , ISHIKAWA TOSHIHIRO
IPC: C04B41/85 , C04B35/622
Abstract: PROBLEM TO BE SOLVED: To provide a ceramic having a surface layer with a gradient composition, which has excellent functions such as photocatalytic functions, electrical functions, thermo-catalytic functions or a function as a catalyst carrier, or environmental resistance such as oxidation resistance, alkali resistance or wear resistance, and excellent mechanical properties, and to provide a method of producing the same. SOLUTION: The ceramic comprises a composite phase which is constituted of a first phase mainly comprising silicon-based ceramic components and a second phase mainly comprising ceramic components other than the ceramic components in the first phase, and the present ratio of fine crystalline particles of at least one kind of the ceramic components constituting the second phase is increased in a gradient manner toward the surface layer. COPYRIGHT: (C)2003,JPO
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公开(公告)号:JP2001072475A
公开(公告)日:2001-03-21
申请号:JP24522699
申请日:1999-08-31
Applicant: UBE INDUSTRIES
Inventor: KAJII SHINJI , MATSUNAGA KENJI , NUNOGAMI TOSHIHIKO , ISHIKAWA TOSHIHIRO
Abstract: PROBLEM TO BE SOLVED: To provide a fastening structure element for high-temperature structure body by setting the content of inorganic fiber to a specific value and allowing a layer an amorphous and/or crystalline carbon of a specific thickness to distribute as boundary layers between the inorganic fibers and the inorganic substance and between the fibers. SOLUTION: Inorganic fibers are included in the inorganic fiber-bonding type ceramic composite in an amount of >=80 vol.%. On the surfaces of individual inorganic fibers, amorphous and/or crystalline carbon is formed in an incommensurate phase as a boundary layer in an thickness of 1-200 nm and the inorganic substance distributes so that the gaps of the inorganic fibers may be filled with the inorganic substance. Thus, the developed crack can be deflected even in the inside part of the boundary layer, and the fracture resistance of this ceramic is markedly increased. This characteristics can become a merit for a screw structure part as a binding structure element for the assembly part, in other words, the production of bolts and nuts.
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公开(公告)号:JP2000007453A
公开(公告)日:2000-01-11
申请号:JP19510098
申请日:1998-06-25
Applicant: UBE INDUSTRIES , FUKUNAGA HIDEHARU , TOKYO GAS CO LTD , OSAKA GAS CO LTD , TOHO GAS KK , SEIBU GAS CO LTD
Inventor: ISHIKAWA TOSHIHIRO , NAKAGAWA SHIGETO , FUKUNAGA HIDEHARU , YOSHIDA MAKOTO
IPC: C04B35/653 , C04B35/80
Abstract: PROBLEM TO BE SOLVED: To obtain a fiber reinforced ceramic composite material having excellent high temp. characteristics and cracking resistance. SOLUTION: A ceramic composite material which is a solidified body comprising α-Al2O3 and Y3Al5O12, as a matrix is reinforced with crystalline silicon carbide fibers having >=2.7 g/cm3 density, >=2 GPa tensile strength, >=250 GPa elastic modulus, a sintered structure of SiC and good alkali resistance.
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公开(公告)号:JP2000007451A
公开(公告)日:2000-01-11
申请号:JP17844498
申请日:1998-06-25
Applicant: UBE INDUSTRIES
Inventor: MATSUNAGA KENJI , KAJII SHINJI , NUNOGAMI TOSHIHIKO , ISHIKAWA TOSHIHIRO
IPC: C04B35/80
Abstract: PROBLEM TO BE SOLVED: To produce the composite material having a remarkably high proportional limit and high fracture toughness and also having excellent mechanical property even in the air at >=1000 deg.C. SOLUTION: This inorganic fiber combining composite material is composed of an inorganic fiber, which contains an amorphous material (a) consisting of Si, M, C and O, an aggregate (b) (M expresses Ti or Zr) of a crystalline fine particle of β-SiC, MC and C and an amorphous material of SiO2 and MO2 or a mixture (c) of the amorphous material (a) with the aggregate (b), and an inorganic material, which exists so as to fill the gap of the inorganic fiber, contains an amorphous material (d) consisting of Si and O and if necessary M and a crystalline material (e) consisting of crystalline SiO2 and/or MO2 or a mixture (f) of the amorphous material (d) with the crystalline material (e) and in which a crystalline material consisting of MC having 100 nm to 1000 nm particle diameter are dispersed. The content of the inorganic fiber is >=80 vol.% and a layer, in which a crystalline material consisting of MC having
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公开(公告)号:JPH11107051A
公开(公告)日:1999-04-20
申请号:JP26854297
申请日:1997-10-01
Applicant: UBE INDUSTRIES
Inventor: ISHIKAWA TOSHIHIRO , KUMAKAWA KIYOSHI , HISAYUKI TERUMI , SHIBUYA MASAKI
Abstract: PROBLEM TO BE SOLVED: To obtain a nonwoven fabric or woven fabric having high mechanical properties and excellent heat-resistance and weaving performance and useful for reinforcing fiber, etc., by using a crystalline silicon carbide fiber having respectively specific density and elastic modulus. SOLUTION: This fabric is composed of a crystalline silicon carbide fiber consisting of a sintered SiC structure, having a density of >=2.7 g/cm , a strength of >=2 Gpa and an elastic modulus of >=250 Gpa and composed of 55-70 wt.% of Si, 28-45 wt.% of C, 0.06-3.8 wt.% of Al and 0.06-0.5 wt.% of B. The nonwoven fabric or woven fabric is preferably produced by forming a nonwoven fabric or woven fabric with an amorphous or finely crystalline silicon carbide fiber containing 0.05-3 wt.% of Al, 0.05-0.4 wt.% of B and >=1 wt.% of excess carbon and heat-treating the formed fabric in an inert gas at 1600-2100 deg.C.
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公开(公告)号:JPH1136142A
公开(公告)日:1999-02-09
申请号:JP22615697
申请日:1997-08-22
Applicant: UBE INDUSTRIES
Inventor: ISHIKAWA TOSHIHIRO , HARADA YOSHIKATSU , INOUE YOSHIYUKI , YAMAOKA HIROYUKI
IPC: D01F9/10
Abstract: PROBLEM TO BE SOLVED: To obtain a crystalline silicon carbide fiber excellent in mechanical properties, alkali resistance, and acid resistance by including Si, C, Al, B, etc., and forming an SiC sintered structure. SOLUTION: This crystalline silicon carbide fiber excellent in alkali resistance is obtained by subjecting a silicon carbide fiber comprising 55 to 70 wt.% of Si, 30 to 45 wt.% of C, 0.06 to 3.8 wt.% of Al, 0.06 to 0.5 wt.% of B, and 0.06 to 3.8 wt.% of Y and/or 0.06 to 3.8 wt.% of Mg to heat treatment at 1,600 to 2,100 deg.C in an inert gas to resultantly cause an SiC sintered structure wherein the density is >=2.7 g/cm , the mechanical strength and elastic modulus are respectively >=2 GPa and >=250 GPa, and the strength retention rate is >=50% when immersed in a saturated aqueous solution at room temperatures, then dried and finally subjected to heat treatment in air at 1,000 deg.C for 2 hrs.
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