公开(公告)号：JPS54128589A

公开(公告)日：1979-10-05

申请号：JP3619878

申请日：1978-03-29

Applicant: MITSUBISHI CHEM IND

Inventor： SHIYOUNO KANJI ,  SHIRAGAMI MITSUAKI ,  HIRONAKA TAKASHI

IPC: C07D201/02 ,  C01C1/24 ,  C07D201/16

Abstract: PURPOSE:To recover epsilon-caprolactam and ammonium sulfate of high purity in high yield, by separating a neutralization mixture after the Beckmann rearrangement of cyclohexanone oxime into an aqueous and an oil phases, and by extracting the phases with specific solvents. CONSTITUTION:Cyclohexanone oxime is subjected to the Beckmann rearrangement in the presence of sulfuric acid, and neutralized with aqueous ammonia to give a mixture, which is separated into an aqueous and oil phases in the first stage. In the second stage, the aqueous phase is extracted with an organic solvent e.g. benzene or toluene, to transfer organic substances, e.g. epsilon-caprolactam, from the aqueous to the solvent phase. An aqueous ammonium sulfate is thus recovered. The oil phase spearated in the first stage is extracted with the same organic solvent to give a solvent phase containing epsilon-caprolactam, which is distilled to recover the epsilon-caprolactam. Extraction is carried out by countercurrent method, using a perforated plate tower.

公开(公告)号：JPS5139232B1

公开(公告)日：1976-10-26

申请号：JP3927271

申请日：1971-06-07

IPC: C07D201/02 ,  C07D273/00

公开(公告)号：JPS5148628A

公开(公告)日：1976-04-26

申请号：JP8845575

申请日：1975-07-21

Applicant: MONSANTO CO

Inventor： ROSU MERUBIN HEDORITSUKU ,  JEIMUZU DERUBIN GABAATO

IPC: C08G69/00 ,  B01J27/00 ,  B01J31/00 ,  C07D201/02 ,  C08G63/82 ,  C08G69/44 ,  C08L23/00 ,  C08L23/16 ,  C08L67/00 ,  C08L77/00

公开(公告)号：JPS5132520A

公开(公告)日：1976-03-19

申请号：JP10196374

申请日：1974-09-06

Applicant: TORAY INDUSTRIES

Inventor： KOBAYASHI YOSHIO ,  SAKAI ATSUSHI ,  YASUHARA YUTAKA

IPC: C07D201/16 ,  C07C67/00 ,  C07C253/00 ,  C07C255/19 ,  C07D201/02

公开(公告)号：JPS4936708B1

公开(公告)日：1974-10-02

申请号：JP7466870

申请日：1970-08-26

IPC: C07C67/00 ,  C07C239/00 ,  C07C251/46 ,  C07D201/02 ,  C07D201/04

公开(公告)号：JPS4892325A

公开(公告)日：1973-11-30

申请号：JP2772072

申请日：1972-03-17

IPC: C07D201/02 ,  C07C67/00 ,  C07C231/00 ,  C07C231/10 ,  C07C231/12 ,  C07C233/47

公开(公告)号：JPS4881885A

公开(公告)日：1973-11-01

申请号：JP1575072

申请日：1972-02-15

IPC: C07D201/02 ,  B01J21/00 ,  B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J21/14 ,  B01J23/00 ,  B01J25/00 ,  B01J27/00 ,  B01J29/85 ,  B01J37/26 ,  C07B61/00

公开(公告)号：JPS4881835A

公开(公告)日：1973-11-01

申请号：JP1497572

申请日：1972-02-12

IPC: C07D201/02 ,  C07B61/00 ,  C07C67/00 ,  C07C239/00 ,  C07C251/46

公开(公告)号：WO2014031226A1

公开(公告)日：2014-02-27

申请号：PCT/US2013/047741

申请日：2013-06-26

Applicant: UOP LLC

Inventor： BRICKER, Jeffery C. ,  CHEN, John Q. ,  COUGHLIN, Peter K. ,  MAJUMDER, Debarshi

IPC: C07C255/03 ,  C07C253/18 ,  C07D213/12 ,  C07D207/24 ,  C07D201/02 ,  C07D207/263 ,  C07D295/023 ,  C07D223/10

CPC classification number: C07D213/12 ,  C01B3/025 ,  C01B3/26 ,  C01B3/36 ,  C01B2203/025 ,  C01B2203/04 ,  C01B2203/048 ,  C01B2203/068 ,  C07C253/18 ,  C07D201/08 ,  C07D207/06 ,  C07C255/03

Abstract: Methods and systems are provided for converting methane in a feed stream to acetylene. The hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream may be treated to convert acetylene to nitrogen based hydrocarbon compounds such as pyridines. The method includes the reaction of acetylene with ammonia and controlling the ratio of acetylene to ammonia to generate the desired nitrogen based hydrocarbon compound.

Abstract translation: 提供了将进料流中的甲烷转化为乙炔的方法和系统。 将烃流引入超音速反应器中并热解以将至少一部分甲烷转化为乙炔。 可以处理反应器流出物流以将乙炔转化为氮基烃化合物，例如吡啶。 该方法包括乙炔与氨反应并控制乙炔与氨的比例，产生所需的氮基烃化合物。

公开(公告)号：WO2008103366A4

公开(公告)日：2008-08-28

申请号：PCT/US2008/002202

申请日：2008-02-20

Applicant: BOARD OF TRUSTEES OF MICHIGAN STATE UNIVERSITY ,  FROST, John W.

Inventor： FROST, John W.

IPC: C07D201/00 ,  C07D201/02 ,  C07D201/08

Abstract: Catalytic processes for preparing caprolactam, pipecolinic acid, and their derivatives, from lysine or alpha-amino-epsilon-caprolactam starting materials, and products produced thereby. A process for preparing caprolactam or a derivative thereof, the process comprising contacting a reactant comprising lysine or alpha aminocaprolactam with a catalyst and a gas comprising hydrogen gas, in the presence of a solvent. The catalyst may be provided on a support material, such as a transition metal.