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公开(公告)号：TWI664138B
公开(公告)日：2019-07-01
申请号：TW104111752
申请日：2015-04-10
Applicant: 德商馬克斯普朗克科學促進公司 , MAX-PLANCK-GESELLSCHAFT ZUR FOERDERUNG DER WISSENSCHAFTEN E. V. , EMPA瑞士材料測試暨研究機構 , EMPA-EIDGENOESSISCHE MATERIALPRUEFUNGS-UND FORSCHUNGSANSTALT
Inventor： 法塞 羅曼 , FASEL, ROMAN , 魯菲克斯 帕斯卡 , RUFFIEUX, PASCAL , 山雀思 法倫西亞 喬安 拉蒙 , SANCHEZ VALENCIA, JUAN RAMON , 傑恩森 馬丁 , JANSEN, MARTIN , 穆勒 安德亞斯 , MUELLER, ANDREAS , 阿姆夏羅夫 空史坦汀 , AMSHAROV, KONSTANTIN
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公开(公告)号：TW201600453A
公开(公告)日：2016-01-01
申请号：TW104111752
申请日：2015-04-10
Applicant: 馬克斯普朗克科學促進公司 , MAX-PLANCK-GESELLSCHAFT ZUR FOERDERUNG DER WISSENSCHAFTEN E. V. , EMPA瑞士材料測試暨研究機構 , EMPA-EIDGENOESSISCHE MATERIALPRUEFUNGS-UND FORSCHUNGSANSTALT
Inventor： 法塞 羅曼 , FASEL, ROMAN , 魯菲克斯 帕斯卡 , RUFFIEUX, PASCAL , 山雀思 法倫西亞 喬安 拉蒙 , SANCHEZ VALENCIA, JUAN RAMON , 傑恩森 馬丁 , JANSEN, MARTIN , 穆勒 安德亞斯 , MUELLER, ANDREAS , 阿姆夏羅夫 空史坦汀 , AMSHAROV, KONSTANTIN
CPC classification number: C01B31/0233 , B01J23/42 , B82Y30/00 , B82Y40/00 , C01B32/16 , C01B32/162 , C01B2202/02 , C07C13/62 , C07C15/20 , C07C2603/54 , C23C16/26 , C23C16/44 , Y10S977/75 , Y10S977/843
Abstract: 本發明係關於一種製備具有直徑dSWCNT之單層奈米碳管(SWCNT)的方法，其包含(i)提供前驅體元件，其包含該單層奈米碳管之片段SSWCNT，該片段SSWCNT由至少一個由鄰位稠合苯環形成之環構成，且具有開口的第一端E1及與該第一端E1相對之第二端E2，(ii)藉由與碳源化合物在含金屬催化劑之表面上之氣相反應使該前驅體元件生長，其中該前驅體元件與該含金屬催化劑表面經由該片段SSWCNT之該開口端E1接觸，且該含金屬催化劑呈具有滿足以下關係的平均直徑dcat之粒子形式：dcat>2×dSWCNT，或呈連續膜形式。
Abstract in simplified Chinese: 本发明系关于一种制备具有直径dSWCNT之单层奈米碳管(SWCNT)的方法，其包含(i)提供前驱体组件，其包含该单层奈米碳管之片段SSWCNT，该片段SSWCNT由至少一个由邻位稠合苯环形成之环构成，且具有开口的第一端E1及与该第一端E1相对之第二端E2，(ii)借由与碳源化合物在含金属催化剂之表面上之气相反应使该前驱体组件生长，其中该前驱体组件与该含金属催化剂表面经由该片段SSWCNT之该开口端E1接触，且该含金属催化剂呈具有满足以下关系的平均直径dcat之粒子形式：dcat>2×dSWCNT，或呈连续膜形式。
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公开(公告)号：US12071514B2
公开(公告)日：2024-08-27
申请号：US17055586
申请日：2019-05-20
Inventor： Sabyasachi Gaan , Rudolf Hufenus , Rashid Nazir , Pietro Simonetti , Khalifah Salmeia , Dambarudhar Parida , Ali Gooneie
IPC: C08G73/06 , C07F9/6558 , C07F9/6561
CPC classification number: C08G73/0633 , C07F9/65583 , C07F9/6561 , C08G73/0644 , C08G73/065 , C08G2210/00
Abstract: The present invention exploits reactive organophosphorus compounds containing unsaturated vinyl groups, which can be used in a flexible and highly controlled manner to prepare various macromolecular derivatives either via radical reactions or via Michael addition with suitable nucleophiles. Based on the fact that secondary amine groups on the one hand and vinyl groups on the other hand can work as mutual linking sites, an arsenal of novel and useful addition products can be built up. By selecting the number of secondary amine sites and vinyl sites of the participating reaction partners, very different addition products can be formed. In particular, one can form either linear chain type macromolecules (i.e. linear oligomers or polymers) or highly crosslinked network polymers.
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公开(公告)号：TWI680100B
公开(公告)日：2019-12-21
申请号：TW104104481
申请日：2015-02-11
Applicant: 德商巴斯夫歐洲公司 , BASF SE , EMPA瑞士材料測試暨研究機構 , EMPA-EIDGENOESSISCHE MATERIALPRUEFUNGS-UND FORSCHUNGSANSTALT , 德商馬克斯普朗克科學促進公司 , MAX-PLANCK-GESELLSCHAFT ZUR FOERDERUNG DER WISSENSCHAFTEN E. V.
Inventor： 史瓦伯 瑪提亞斯 喬格 , SCHWAB, MATTHIAS GEORG , 穆倫 克勞斯 , MUELLEN, KLAUS , 方信良 , FENG, XINLIANG , 楊博 , YANG, BO , 敦斯拉夫 提姆 , DUMSLAFF, TIM , 法塞 羅曼 , FASEL, ROMAN , 魯菲克斯 帕斯卡 , RUFFIEUX, PASCAL , 劉佳 , LIU, JIA , 開金明 , CAI, JINMING , 山雀思 山雀思 卡洛斯 , SANCHEZ-SANCHEZ, CARLOS , 劉郡治 , LIU, JUNZHI
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公开(公告)号：TW201538423A
公开(公告)日：2015-10-16
申请号：TW104104481
申请日：2015-02-11
Applicant: 巴斯夫歐洲公司 , BASF SE , EMPA瑞士材料測試暨研究機構 , EMPA-EIDGENOESSISCHE MATERIALPRUEFUNGS-UND FORSCHUNGSANSTALT , 馬克斯普朗克科學促進公司 , MAX-PLANCK-GESELLSCHAFT ZUR FOERDERUNG DER WISSENSCHAFTEN E. V.
Inventor： 史瓦伯 瑪提亞斯 喬格 , SCHWAB, MATTHIAS GEORG , 穆倫 克勞斯 , MUELLEN, KLAUS , 方信良 , FENG, XINLIANG , 楊博 , YANG, BO , 敦斯拉夫 提姆 , DUMSLAFF, TIM , 法塞 羅曼 , FASEL, ROMAN , 魯菲克斯 帕斯卡 , RUFFIEUX, PASCAL , 劉佳 , LIU, JIA , 開金明 , CAI, JINMING , 山雀思 山雀思 卡洛斯 , SANCHEZ-SANCHEZ, CARLOS , 劉郡治 , LIU, JUNZHI
CPC classification number: C08G61/10 , C01B32/184 , C01B2204/06 , C07C15/20 , C07C25/22 , C08G2261/312 , C08G2261/314 , C08G2261/72 , C08G2261/724
Abstract: 本發明係關於具有經控制鋸齒形邊緣及彎曲邊緣組態的石墨烯奈米帶及製備該等石墨烯奈米帶之方法。該等奈米帶選自下式：
Abstract in simplified Chinese: 本发明系关于具有经控制锯齿形边缘及弯曲边缘组态的石墨烯奈米带及制备该等石墨烯奈米带之方法。该等奈米带选自下式：
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Patent Agency Ranking
6.发明授权公开(公告)号：US11965063B2
公开(公告)日：2024-04-23
申请号：US15734657
申请日：2019-06-04
Inventor： Matthias Koebel , Ana Stojanovic , Wim Malfait , Adilien Nour
CPC classification number: C08G77/20 , C08J9/228 , B82Y40/00 , C08J2205/026 , C08J2383/06
Abstract: A polymeric liquid material formed of molecular building blocks of core-shell type architecture, wherein each building block consists of a hyperbranched polysiloxane core and a functional siloxane shell peripherally attached thereto, the material comprising bridging oxygen moieties (Si—O—Si), hydrolysable alkoxy moieties (Si—O—R) and organofunctional moieties (R′—Si—) and (R1—S1-R2) and less than 0.5 mass percent hydroxy moieties (Si—OH). The core has a degree of polymerization DPcore in the range of 1.3 to 2.7, the shell is formed of R′-substituted siloxane moieties and has a degree of polymerization DPshell in the range of 0.3 to 2.5. At least 75 atomic percent of all Si atoms in the core are bonded exclusively to alkoxy or bridging oxygens, the remainder each being bonded to 3 oxygens and 1 carbon. The total Si to free hydrolysable alkoxy molar ratio in the material is 1:1.25 to 1:2.75, and the material has a viscosity in the range of 10-100,000 cP. A method for preparing the polymeric liquid material relies on first forming the hyper-branched polysiloxane core followed by a build-up of the functional siloxane shell. To do so, a reaction scheme based on adding stoichiometric amounts of acetic anhydride in a water-free environment is exploited.
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公开(公告)号：US20230212017A1
公开(公告)日：2023-07-06
申请号：US17775415
申请日：2020-11-06
Inventor： Shanyu ZHAO , Gilberto DE FREITAS SIQUEIRA , Wim MALFAIT , Matthias KOEBEL , Christopher UBERT , David NORRIS
IPC: C01B33/158 , B33Y40/20 , B33Y10/00 , B33Y70/00 , C09D11/322 , C09D11/36 , C09D11/033 , C09D11/037
CPC classification number: C01B33/1585 , B33Y40/20 , B33Y10/00 , B33Y70/00 , C09D11/322 , C09D11/36 , C09D11/033 , C09D11/037
Abstract: An ink composition for additive manufacture of silica aerogel objects essentially consists of a gellable silica sol containing an admixture of 30 to 70 vol.% of a mesoporous silica powder in a base solvent. The mesoporous silica powder has a particle size range of 0.001 to 1 mm and a tap density of 30 to 200 kg/m3 and comprises at least 10% by weight of silica aerogel powder. The composition has a yield stress in the range of 30 to 3000 Pa and a viscosity of 5 to 150 Pa·s at a shear rate of 50 s−1. Furthermore, the composition has shear thinning properties defined as a reduction in viscosity by a factor between 10 and 103 for an increase in shear rate by a factor of 104 to 105. A method of additive manufacturing of a three-dimensional silica aerogel object by direct ink writing comprises providing such ink composition, forcing the same through a convergent nozzle, thereby forming a jet of the ink composition which is directed in such manner as to form a three-dimensional object by additive manufacturing. After initiating and carrying out gelation of the gellable silica sol constituting said object, a drying step yields the desired three-dimensional silica aerogel object.
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8.发明申请公开(公告)号：US20220089819A1
公开(公告)日：2022-03-24
申请号：US15734657
申请日：2019-06-04
Inventor： Matthias KOEBEL , Ana STOJANOVIC , Wim MALFAIT , Adilien NOUR
Abstract: A polymeric liquid material formed of molecular building blocks of core-shell type architecture, wherein each building block consists of a hyperbranched polysiloxane core and a functional siloxane shell peripherally attached thereto, the material comprising bridging oxygen moieties (Si—O—Si), hydrolysable alkoxy moieties (Si—O—R) and organofunctional moieties (R′—Si—) and (R1-S1-R2) and less than 0.5 mass percent hydroxy moieties (Si—OH). The core has a degree of polymerization DPcore in the range of 1.3 to 2.7, the shell is formed of R′-substituted siloxane moieties and has a degree of polymerization DPshell in the range of 0.3 to 2.5. At least 75 atomic percent of all Si atoms in the core are bonded exclusively to alkoxy or bridging oxygens, the remainder each being bonded to 3 oxygens and 1 carbon. The total Si to free hydrolysable alkoxy molar ratio in the material is 1:1.25 to 1:2.75, and the material has a viscosity in the range of 10-100,000 cP. A method for preparing the polymeric liquid material relies on first forming the hyper-branched polysiloxane core followed by a build-up of the functional siloxane shell. To do so, a reaction scheme based on adding stoichiometric amounts of acetic anhydride in a water-free environment is exploited.
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公开(公告)号：US10388260B2
公开(公告)日：2019-08-20
申请号：US16065819
申请日：2016-12-28
Inventor： Francis Schwarze , Markus Heeb , Marjan Gilani , Sebastien Josset
IPC: G10D1/00
Abstract: In a method for improving the acoustic properties of spruce resonance wood for musical instruments at least one resonance wood blank is subjected to a treatment with Physisporinus vitreus under controlled, sterile conditions. The previously sterilized resonance wood blank is immersed into a liquid medium enriched with fungus myecelium and kept therein in the dark for an exposure time and finally sterilized, wherein during the exposure time a temperature of 18 to 26° C. and a relative humidity of approximately 60 to approximately 80% are maintained. Due to the fact that the liquid medium contains nanofibrillated cellulose (NFC) in an amount of 200 to 300 g per liter, a reproducible, uniform improvement of the acoustic properties of the resonance wood free from local defects is ensured.
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公开(公告)号：US20190088235A1
公开(公告)日：2019-03-21
申请号：US16065819
申请日：2016-12-28
Inventor： Francis SCHWARZE , Markus HEEB , Marjan GILANI , Sebastien JOSSET
IPC: G10D1/00
CPC classification number: G10D1/005
Abstract: In a method for improving the acoustic properties of spruce resonance wood for musical instruments at least one resonance wood blank is subjected to a treatment with Physisporinus vitreus under controlled, sterile conditions. The previously sterilized resonance wood blank is immersed into a liquid medium enriched with fungus myecelium and kept therein in the dark for an exposure time and finally sterilized, wherein during the exposure time a temperature of 18 to 26° C. and a relative humidity of approximately 60 to approximately 80% are maintained. Due to the fact that the liquid medium contains nanofibrillated cellulose (NFC) in an amount of 200 to 300 g per liter, a reproducible, uniform improvement of the acoustic properties of the resonance wood free from local defects is ensured.
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