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公开(公告)号：US20130225737A1
公开(公告)日：2013-08-29
申请号：US13599625
申请日：2012-08-30
Applicant: Claudius P. Gosse , Thomas M. Larson , Pierre J.P. Legrand , Raphael F. Caers , Paul H. Daniels , Allen D. Godwin , Didier Naert
Inventor： Claudius P. Gosse , Thomas M. Larson , Pierre J.P. Legrand , Raphael F. Caers , Paul H. Daniels , Allen D. Godwin , Didier Naert
CPC classification number: C08K5/12 , C08K3/22 , C08K3/26 , C08K3/36 , C08K5/0016 , C08K5/57 , C08L27/06
Abstract: Esters of cyclohexane polycarboxylic acids are used as plasticisers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticisers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticisers may also be included. The formulations and processes of making these formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials, toys, and food contact articles.
Abstract translation: 环己烷多元羧酸的酯用作聚氯乙烯的增塑剂，以使得能够使用较少聚氯乙烯获得具有相当机械性能的产品。 这些酯的使用还产生具有增加的紫外光稳定性，改进的低温性能，较低粘度和改进的加工性以及燃烧时减少的烟雾的配方。 当环己烷多元羧酸的酯可以作为粘度降低剂时，环己烷多羧酸的酯可以单独使用或与其它增塑剂混合使用。 还可以包括快速熔化增塑剂。 制备这些制剂的制剂和方法特别可用于生产从半刚性到高度柔性材料的一系列商品，并且在生产医疗材料，玩具和食品接触制品方面特别有用。
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2.发明申请公开(公告)号：US20120289636A1
公开(公告)日：2012-11-15
申请号：US13513156
申请日：2010-11-16
Applicant: Karla S. Colle , Allen D. Godwin
Inventor： Karla S. Colle , Allen D. Godwin
CPC classification number: C07C67/04 , A61K8/37 , A61K8/8123 , A61K2800/30 , A61Q19/00 , C07C29/095 , C07C67/08 , C08K5/10 , C08K5/12 , C08K2201/014 , C09K8/58 , C11D3/2017 , C11D3/2048 , C07C31/125 , C07C69/14 , C07C69/003 , C07C69/80 , C08L27/06 , C07C31/02
Abstract: A method for preparation of secondary alcohols with a high proportion of hydroxyl group at the C2 position is disclosed. Alkyl carboxylates, high in alpha-methylcarboxylate content, are produced via reaction of an alpha-olefin and a carboxylic acid in the presence of a cerium catalyst. The resultant alkyl carboxylate is hydrolyzed to yield a secondary alcohol with a high 2-hydroxyl content. The secondary alcohol may be used to prepare esters, especially phthalate esters or cyclohexanoate diesters, which are useful as plasticizers. These esters are more effective as plasticizers than esters derived from other secondary alcohols due to their high C2 point of attachment.
Abstract translation: 公开了一种在C2位置制备具有高比例羟基的仲醇的方法。 在铈催化剂存在下，通过α-烯烃和羧酸的反应生产α-甲基羧酸酯含量高的烷基羧酸盐。 将所得的羧酸烷基酯水解，得到具有高2-羟基含量的仲醇。 仲醇可用于制备可用作增塑剂的酯，特别是邻苯二甲酸酯或环己酸二酯。 由于其高C2连接点，这些酯作为增塑剂比来自其它仲醇的酯更有效。
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公开(公告)号：US20110312864A1
公开(公告)日：2011-12-22
申请号：US13139949
申请日：2009-12-03
Applicant: Allen D. Godwin , Philippe L. Buess , Raphael F. Caers , Arie Van Vliet , Eddy T.A. Van Driessche , Alfons Cuyckens
Inventor： Allen D. Godwin , Philippe L. Buess , Raphael F. Caers , Arie Van Vliet , Eddy T.A. Van Driessche , Alfons Cuyckens
IPC: C10M169/04 , C07C31/12 , C07C29/14 , C07C69/78 , C07C69/67 , C07C69/80 , C07C69/82 , C07C69/757 , C07C69/75 , C07C11/00 , C08K5/12 , C08L27/06 , C08K5/11 , C08K5/101 , C07C31/125
CPC classification number: C07C29/175 , C07C29/141 , C07C2601/14 , C08K5/10 , C07C31/125 , C08L27/06
Abstract: The present invention relates to alcohols and in particular to C4 to C15 alcohols that are used in the production of esters.
Abstract translation: 本发明涉及醇，特别涉及用于生产酯的C4至C15醇。
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4.发明申请Production of synthetic hydrocarbon fluids, plasticizers and synthetic lubricant base stocks from renewable feedstocks 有权从可再生原料生产合成烃流体，增塑剂和合成润滑剂基础油公开(公告)号：US20100160506A1
公开(公告)日：2010-06-24
申请号：US12653742
申请日：2009-12-17
Applicant: Margaret May-Som Wu , Karla Schall Colle , Ramzi Yanni Saleh , Allen D. Godwin , John Edmond Randolph Stanat
Inventor： Margaret May-Som Wu , Karla Schall Colle , Ramzi Yanni Saleh , Allen D. Godwin , John Edmond Randolph Stanat
IPC: C08K5/1515 , C08K5/109 , C07D301/03 , C07D317/24 , C07C1/207
CPC classification number: C07D317/36 , C08L21/00 , C10G3/44 , C10G3/48 , C10G29/205 , C10G2300/1014 , C10G2300/1018 , C10G2300/1092 , C10G2300/30 , C10G2300/302 , C10G2300/304 , C10G2400/06 , C10G2400/10 , C10M107/10 , C10M2205/0285 , C10N2220/022 , C10N2220/023 , C10N2220/024 , C10N2270/00 , Y02P30/20
Abstract: This disclosure is directed to an integrated method for making synthetic hydrocarbon fluids, plasticizers and polar synthetic lubricant base stocks from a renewable feedstock. More particularly, the disclosure is directed to a metathesis reaction of natural oil or its derivative ester and ethylene in the presence of an effective amount of a metathesis catalyst to form linear alpha-olefins, internal olefins and reduced chain length triglycerides. The linear alpha-olefins and/or internal olefins are polymerized to produce synthetic hydrocarbon fluids in the presence of a suitable catalyst. The reduced chain length triglycerides are converted into polar synthetic lubricant base stocks or plasticizers by hydrogenation, isomerization, followed by hydrogenations, or by hydroisomerization processes. Alternatively, the reduced chain length triglycerides can also be epoxidized to form epoxidized triglyceride plasticizers, optionally followed by carbonation, to form carbonated triglyceride plasticizers.
Abstract translation: 本发明涉及从可再生原料制备合成烃流体，增塑剂和极性合成润滑剂基础油的综合方法。 更具体地，本公开涉及天然油或其衍生物酯和乙烯在有效量的复分解催化剂存在下的复分解反应，以形成线性α-烯烃，内烯烃和还原链长度甘油三酯。 在合适的催化剂存在下，将线性α-烯烃和/或内烯烃聚合以产生合成烃流体。 还原的链长度甘油三酯通过氢化，异构化，随后氢化或通过加氢异构化方法转化为极性合成润滑剂基础油料或增塑剂。 或者，还原链长度甘油三酯也可以被环氧化以形成环氧化甘油三酯增塑剂，任选地随后碳酸化形成碳酸化甘油三酯增塑剂。
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公开(公告)号：US06969736B1
公开(公告)日：2005-11-29
申请号：US10855553
申请日：2004-05-27
Applicant: Allen D. Godwin , Jon E. Stanat , Richard J. Saplis
Inventor： Allen D. Godwin , Jon E. Stanat , Richard J. Saplis
CPC classification number: C08K5/12 , C08K2201/014 , Y10T428/294
Abstract: Less branched C9 alcohols are used to provide plasticizer esters particularly suitable for high temperature applications such as wire and cable insulation.
Abstract translation: 较少支链的C 9醇用于提供特别适用于高温应用如电线电缆绝缘的增塑剂酯。
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Patent Agency Ranking
公开(公告)号：US06887305B2
公开(公告)日：2005-05-03
申请号：US10157464
申请日：2002-05-29
Applicant: Thomas Marshall Larson , Allen D. Godwin , Bruce R. Lundmark , Anthony James Giaquinto
IPC: G03G15/20
CPC classification number: G03G15/2025
Abstract: A release agent for use in imaging systems having hot a fuser roller wherein the release agent is a hydrocarbon.
Abstract translation: 一种用于具有热定影辊的成像系统的脱模剂，其中脱模剂是烃。
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公开(公告)号：US06777514B2
公开(公告)日：2004-08-17
申请号：US10228755
申请日：2002-08-27
Applicant: Abhimanyu O. Patil , Nicholas V. Smith , Jose G. Santiesteban , Allen D. Godwin , Steven P. Rucker , Stephen Zushma
Inventor： Abhimanyu O. Patil , Nicholas V. Smith , Jose G. Santiesteban , Allen D. Godwin , Steven P. Rucker , Stephen Zushma
IPC: C08F428
CPC classification number: C08G67/02 , C08L27/06 , C08L73/00 , C08L2666/14
Abstract: The invention is related to a geminally disubstituted olefin-carbon monoxide-ethylene polymer. The invention is also related to a method for preparing geminally disubstituted olefin-carbon monoxide-ethylene polymers by reacting a geminally disubstituted olefin feed, a carbon monoxide feed and an ethylene feed under free radical polymerization conditions. The invention is further related to a geminally disubstituted olefin-carbon monoxide-ethylene-X polymer, where monomer X is a free radical polymerizable monomer. The invention is also directed to a method for preparing geminally disubstituted olefin-carbon monoxide-ethylene-X polymers by reacting a geminally disubstituted olefin feed, a carbon monoxide feed, an ethylene feed and a feed containing monomer X under free radical polymerization conditions. The polymers of the invention are useful as polyvinyl chloride plasticizers.
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公开(公告)号：US08829093B2
公开(公告)日：2014-09-09
申请号：US13751835
申请日：2013-01-28
Applicant: Jihad Dakka , Lorenzo C. DeCaul , Christine A. Costello , Edmund J. Mozeleski , Pierre J. Osterrieth , Diana S. Smirnova , Stephen Zushma , Allen D. Godwin
Inventor： Jihad Dakka , Lorenzo C. DeCaul , Christine A. Costello , Edmund J. Mozeleski , Pierre J. Osterrieth , Diana S. Smirnova , Stephen Zushma , Allen D. Godwin
CPC classification number: C08K5/12 , C07C69/76 , C07C2601/14 , C08K5/0016 , C08K5/101 , C08L27/06
Abstract: Provided are compounds of the following: wherein R1 is a saturated or unsaturated cyclic hydrocarbon optionally substituted with an alkyl and/or an OXO-ester, and R2 is the residue of a C4 to C14 OXO-alcohol. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.
Abstract translation: 提供以下化合物：其中R1是任选被烷基和/或OXO-酯取代的饱和或不饱和环状烃，R 2是C 4至C 14 O XO-醇的残基。 还提供了制备含有所述化合物的化合物和增塑聚合物组合物的方法。
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公开(公告)号：US08669311B2
公开(公告)日：2014-03-11
申请号：US12742505
申请日：2008-10-23
Applicant: Karla S. Colle , Jon E. R. Stanat , Juan J. Reinoso , Allen D. Godwin
Inventor： Karla S. Colle , Jon E. R. Stanat , Juan J. Reinoso , Allen D. Godwin
CPC classification number: C08K5/0016 , C08K5/12 , C08L15/02
Abstract: C7-C12 secondary alcohol esters of cyclohexanecarboxylic acids are especially useful as plasticizers for PVC and other plasticizable polymers. In embodiments, these plasticizers are useful in plastisol formulations to help improved processability of flexible PVC material. In other embodiments these same plasticizers can be used in blends with other plasticizers to improve processability. In preferred embodiments these same plasticizers can be used to prepare flexible PVC compounds with enhanced low temperature flexibility, low toxicity, and improved resistance to outdoor aging.
Abstract translation: 环己烷羧酸的C7-C12仲醇酯特别适用于PVC和其他可塑化聚合物的增塑剂。 在实施方案中，这些增塑剂可用于增塑溶胶配方以有助于改善柔性PVC材料的可加工性。 在其它实施方案中，这些相同的增塑剂可以与其它增塑剂混合使用以改善加工性能。 在优选实施方案中，这些相同的增塑剂可用于制备具有增强的低温柔韧性，低毒性和改善的耐室外老化性能的柔性PVC化合物。
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公开(公告)号：US20130210984A1
公开(公告)日：2013-08-15
申请号：US13704408
申请日：2011-06-03
Applicant: Karla S. Colle , Allen D. Godwin
Inventor： Karla S. Colle , Allen D. Godwin
IPC: C07C67/00
CPC classification number: C07C67/00 , C07C29/095 , C07C67/04 , C08K5/11 , C08K5/12 , C07C31/125 , C07C69/003 , C07C69/14 , C07C67/08 , C07C69/82 , C07C69/44 , C07C69/80 , C07C69/76
Abstract: The invention relates to secondary alcohols produced by contacting an olefin and a carboxylic acid with a zeolite, esters made therefrom, and to plasticizer compositions comprising the esters.
Abstract translation: 本发明涉及通过使烯烃和羧酸与沸石，由其制得的酯和包含酯的增塑剂组合物接触而制备的仲醇。
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