SUBSTITUTED AZOLIN-2-YL-AMINO COMPOUNDS
    1.
    发明申请
    SUBSTITUTED AZOLIN-2-YL-AMINO COMPOUNDS 审中-公开
    取代的AZOLIN-2-YL-AMINO化合物

    公开(公告)号:WO2008017649A1

    公开(公告)日:2008-02-14

    申请号:PCT/EP2007/058109

    申请日:2007-08-06

    CPC classification number: C07D417/12 A01N43/50 A01N43/76 A01N43/78 C07D277/18

    Abstract: The present invention relates to azolin-2-yl-amino compounds of formulae (I. a) and (l.b) and their salts which are useful for combating animal pest, in particular arthropod and nematodes. The present invention also relates to a method for combating such pests and for protecting crops against infestation or infection by such pests. Furthermore, the present invention relates to veterinary compositions for combating animal pests. Formula (I.a), formula (I.b) wherein n is 0 to 4; X is S, O or NR 5 ; A is -C(R 6a )(R 6b )-, O, NR 7 , S, S(O) or S(O) 2 ; B is a bond Or CH 2 ; R 1 is H, CN, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 1 -C 6 -alkylcarbonyl, C 3 -C 6 -cycloalkyl, phenyl, benzyl, etc.; R 2a , R 2b are H, CN, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 1 -C 6 -alkylcarbonyl, C 1 -C 6 -alkoxycarbonyl, (C 1 -C 6 -alkyl)thiocarbonyl, C(O)NR a R b , C(S)NR a R b , (SO 2 )NR a R b , phenyl, benzyl, 5 or 6 membered heterocyclic ring etc.; or R 1 together with R 2a is C 3 -C 5 -alkandiyl; or R 1 together with R 2b are C(O); R 3a , R 3b , R 3c , R 3d are H, halogen, CN, C 1 -C 6 -alkyl, C 1 -C 6 -alkylamino, C 3 -C 6 -cycloalkyl, phenyl, benzyl, etc.; R 4a , R 4b are H, halogen, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, phenyl, benzyl, 5 or 6 membered hetaryl; or R 4a together with R 4b may also be =0, =NR C or =CR d R e ; or R 2a together with R 4a may form a bridging bivalent radical.

    Abstract translation: 本发明涉及用于对抗动物害虫,特别是节肢动物和线虫的式(Ⅰa)和(Ⅰ.B)的吡咯烷-2-基氨基化合物及其盐。 本发明还涉及一种防治这种害虫并防止作物抵抗这种害虫侵染或感染的方法。 此外,本发明涉及用于对抗动物害虫的兽用组合物。 式(Ⅰa),式(Ⅰb)其中n为0-4; X是S,O或NR 5; A是-C(R 6a)(R 6b) - ,O,NR 7,S,S(O)或S(O ) 2 ; B是键或CH 2 2; R 1是H,CN,C 1 -C 6 - 烷基,C 2 -C 3 - C 1 -C 6 - 亚烷基,C 1 -C 6 - 烷基羰基,C 3 -C 6 - 环烷基,苯基,苄基等; R 2a,R 2b是H,CN,C 1 -C 6 - 烷基,C 1 -C 6烷基, C 1 -C 6亚烷基,C 1 -C 6 - 烷基羰基,C 1 -C 6 - 烷基羰基,C 1 -C 6 - C 6 -C 6 - 烷氧基羰基,(C 1 -C 6 - 烷基)硫代羰基,C(O)NR a C C(S)NR a R b,(SO 2)NR a, 苯基,苄基,5或6元杂环等; 或R 1与R 2a一起为C 3 -C 5 - 亚烷基; 或R 1和R 2b一起是C(O); R 3a,R 3b,R 3c,R 3d是H,卤素,CN,C C 1 -C 6 - 烷基,C 1 -C 6 - 烷基氨基,C 3 - C 6 -C 6 - 环烷基,苯基,苄基等; R 4a,R 4b是H,卤素,C 1 -C 6 - 烷基,C 1 -C 4烷基, C 2 -C 6 - 烯基,苯基,苄基,5或6元杂芳基; 或R 4a与R 4b一起也可以是= 0,= NR C或= CR D, SUP>电子; 或R 2a与R 4a一起可以形成桥连二价基团。

    AMINO SUBSTITUTED BENZO(HETERO)CYCLIC DERIVATIVES
    4.
    发明申请
    AMINO SUBSTITUTED BENZO(HETERO)CYCLIC DERIVATIVES 审中-公开
    氨基取代的苯甲(环)环化合物

    公开(公告)号:WO2004080170A2

    公开(公告)日:2004-09-23

    申请号:PCT/EP2004/001677

    申请日:2004-02-20

    IPC: A01N

    CPC classification number: A01N43/72 A01N43/60

    Abstract: Use of compounds Formula (I), A = a 5- to 7-membered ring which may contain 1-3 heteroatoms and which may be saturated or partially or completely unsaturated; R 1 = OH, SH, NH 2 , CN, NO 2 , halogen, C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl; C 1 -C 6 - alkoxy, C 1 -C 6 -haloalkoxy, C 1 -C 6 -alkylthio, C 1 -C 6 -haloalkylthio, C 2 -C 6 -alkenyl, C 2 -C 6 -alkenyloxy, C 2 -C 6 -alkenylthio, C 2 -C 6 -alkynyl, C 2 -C 6 ­alkynyloxy, C 2 -C 6 -alkynylthio, C 1 -C 6 -alkylsulfonyl, C 1 -C6-alkylsulfoxyl, C 2 -C 6 -alkenylsulfonyl, C 2 -C 6 -alkynylsulfoxyl, C 1 -C 6 -alkylcarbonyl, C 1 -C 6 - alkoxycarbonyl, C 1 -C 6 -alkylcarbonyloxy; R 2 = C 1 -C 6 -alkyl or a mono- or bicyclic 5- to 10-membered aromatic ringsystem which may contain 1 to 4 heteroatoms and which is either bonded directly or through an O, S, C 1 -C 6 -alkylene or C 1 -C 6 -alkyleneoxy linkage to A or fused to A and which may be substituted; R 3 , R 4 = H, C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl, C 1 -C 6 -alkylamino, C 1 -C 6 -alkoxy, C 3 -C 6 - cycloalkyl, or R 3 and R 4 together with the nitrogen atom to which they are attached form a saturated or partially saturated mono- or bicyclic 5- to 10-membered ring system con-taining 1 to 3 heteroatoms or a 5-membered hetaryl containing 1 to 4 nitro-gen atoms, wherein the carbon and/or nitrogen atoms in the ring systems may be substituted or phenyl or benzyl which may be substituted; or R 3 and R 4 together form the chains -(CH 2 ) 2 N + (O-)(CH 2 ) 2 - or -(CH 2 ) 3 N + (O - )(CH 2 ) 2 - ; m = 0 to 4; n is 0 to 4; and the enantiomers, diastereomers, cis/trans isomers or salts thereof for combatting insects, arachnids or nematodes, methods for the control of these pests and of protecting growing plants attack or infestation by these pests by applying a pesticidally effective amount of a compound of formula (I), processes for preparing them, and compositions comprising them.

    Abstract translation: 化合物式(I)的用途,A =可含有1-3个杂原子并且可以是饱和或部分或完全不饱和的5-至7-元环; R 1 = OH,SH,NH 2,CN,NO 2,卤素,C 1 -C 6烷基,C 1 -C 6 - 卤代烷基; C 1 -C 6烷氧基,C 1 -C 6 - 卤代烷氧基,C 1 -C 6 - 烷硫基,C 1 -C 6卤代烷硫基,C 2 -C 6 - 烯基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 烯硫基,C 2 -C 6炔基, C 1 -C 6烷氧羰基,C 1 -C 6烷氧基羰基,C 1 -C 6烷氧基羰基,C 1 -C 6烷氧羰基,C 1 -C 6烷氧羰基, R 2 = C 1 -C 6 - 烷基或可以含有1至4个杂原子并且直接键合或通过O,S,C 1 -C 6亚烷基或通过C 1 -C 6 - 烷基取代的单 - 或双环5-至10-元芳环体系 与A或与A稠合的C1-C6-亚烷基氧键,并且其可以被取代; R 3,R 4 = H,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷基氨基,C 1 -C 6 - 烷氧基,C 3 -C 6环烷基或R 3和 R 4与它们所连接的氮原子一起形成饱和或部分饱和的单环或双环的5-至10-元环系统,其含有1至3个杂原子或含有1至4个硝基的5元杂芳基 - 原子,其中环系中的碳原子和/或氮原子可以被取代,或可被取代的苯基或苄基; 或者R 3和R 4一起形成链 - (CH 2)2 N +(O - )(CH 2)2 - 或 - (CH 2)3 N +(O - )(CH 2)2 < - >; m = 0〜4; n为0〜4; 以及用于防治昆虫,蜘蛛或线虫的对映异构体,非对映异构体,顺式/反式异构体或其盐,用于控制这些害虫的方法以及通过施用杀虫有效量的这种化合物来保护这些害虫的生长植物侵袭或侵染 (I),其制备方法和包含它们的组合物。

    PESTICIDAL FLUOROALKENE DERIVATIVES
    5.
    发明申请
    PESTICIDAL FLUOROALKENE DERIVATIVES 审中-公开
    杀虫荧光酮衍生物

    公开(公告)号:WO2004013112A1

    公开(公告)日:2004-02-12

    申请号:PCT/EP2003/008397

    申请日:2003-07-30

    CPC classification number: A01N43/90 A01N43/74 C07D277/36 C07D277/74

    Abstract: Pesticidal fluoroalkene derivatives (I) wherein A is oxygen, NR a ; R a is hydrogen; optionally halogenated alkyl, alkenyl, alkynyl; X is hydrogen, halogen; optionally halogenated alkyl or phenyl; R 1 ,R 2 are hydrogen, halogen, hydroxyl, cyano, nitro, mercapto, amino; alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkylthio, alkylamino, dialkylamino, alkoxycarbonyl, alkylcarbonyloxy, optionally halogenated or substituted by 1 to 3 R b groups: R b is cyano, nitro, halogen, hydroxy, mercapto, amino, carboxyl, aminocarbonyl, aminothiocarbonyl; optionally halogenated alkyl, haloalkyl, alkenyl, alkenyloxy, alkynyl, alkoxy, haloalkoxy, alkylthio, alkylamino, dialkylamino, formyl, alkylcarbonyl, alkylsulfonyl, alkoxysulfonyl, alkylsulfonyloxy, alkoxycarbonyl, alkylcarbonyloxy, alkylaminocarbonyl, dialkylaminocarbonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl, alkylenedioxy or cycloalkyl; Het is a monocyclic or bicyclic 3- to 10-membered heteroaromatic ring system containing 1 to 5 heteroatoms selected from oxygen, sulfur and nitrogen, optionally halogenated or substituted by 1 to 4 R c groups: R c is R b , alkoxyalkyl, alkylsulfinyl, alkylaminosulfonyl, di-alkylaminosulfonyl, alkylcarbonylamino, optionally substituted by halogen or 1 to 3 cyano, hydroxy, mercapto, amino, C1-C6-alkylthio, C1-C6-alkylamino, di-C1-C6-alkylamino, C1-C6-alkoxycarbonyl, C1-C6-alkylcarbonyloxy or nitro groups; cycloalkyl, cycloalkoxy, saturated or partially unsaturated heterocyclyl, heterocyclyloxy, aryl, aryloxy, arylthio, arylalkoxy, arylalkyl, hetaryl, hetaryloxy, hetarylthio, optionally substituted; m is 0-2; n is 0-3; p is 0-6, methods for the preparation of compounds I, compositions and methods comprising the compounds and compositions for the control of nematodes, insects, arachnids, harmful fungi and unwanted plants, and for treating, controlling, preventing and protecting warm-blodded animals, fish and humans against infestation and infection by helminths, arachnids and arthropod endo- and ectoparasites.

    Abstract translation: 杀虫氟代烯烃衍生物(I)其中A是氧,NR a; R a是氢; 任选卤代烷基,烯基,炔基; X是氢,卤素; 任选卤代烷基或苯基; R 1,R 2是氢,卤素,羟基,氰基,硝基,巯基,氨基; 烷基,烯基,炔基,烷氧基,烯氧基,烷硫基,烷基氨基,二烷基氨基,烷氧基羰基,烷基羰基氧基,任选被卤化或被1至3个R基团取代:R b是氰基,硝基,卤素,羟基,巯基,氨基 ,羧基,氨基羰基,氨基硫代羰基; 任选卤代烷基,卤代烷基,烯基,烯氧基,炔基,烷氧基,卤代烷氧基,烷硫基,烷基氨基,二烷基氨基,甲酰基,烷基羰基,烷基磺酰基,烷氧基磺酰基,烷基磺酰氧基,烷氧基羰基,烷基羰基氧基,烷基氨基羰基,二烷基氨基羰基,烷基氨基硫代羰基,二烷基氨基硫代羰基,亚烷基二氧基或环烷基。 Het是含有1至5个选自氧,硫和氮的杂原子的单环或双环3至10元杂芳族环系,任选被卤化或被1-4个R c取代:R c是R b 烷氧基烷基,烷基亚磺酰基,烷基氨基磺酰基,二烷基氨基磺酰基,烷基羰基氨基,任选被卤素取代或氰基,羟基,巯基,氨基,C 1 -C 6烷硫基,C 1 -C 6烷基氨基,二-C 1 -C 6烷基氨基, C 1 -C 6 - 烷氧基羰基,C 1 -C 6烷基羰基氧基或硝基; 环烷基,环烷氧基,饱和或部分不饱和的杂环基,杂环氧基,芳基,芳氧基,芳硫基,芳基烷氧基,芳烷基,杂芳基,杂芳氧基,杂芳硫基,任选取代的; m为0-2; n为0-3; p为0-6,制备化合物I的方法,包含用于控制线虫,昆虫,蜘蛛,有害真菌和不想要的植物的化合物和组合物的组合物和方法,以及用于治疗,控制,预防和保护温暖的 动物,鱼类和人类,通过蠕虫,蜘蛛和节肢动物内部和外寄生虫感染和感染。

    AZOLINE COMPOUNDS FOR COMBATING ARTHROPOD PESTS
    6.
    发明申请
    AZOLINE COMPOUNDS FOR COMBATING ARTHROPOD PESTS 审中-公开
    用于组合青蒿琥酯的AZOLINE化合物

    公开(公告)号:WO2007147701A1

    公开(公告)日:2007-12-27

    申请号:PCT/EP2007/055133

    申请日:2007-05-25

    CPC classification number: C07D277/18

    Abstract: The present invention relates to azoline compounds and their salts which are useful for combating arthropod pests. The present invention also relates to a method for combating arthropod pests and to agricultural compositions for combating said pests. It has been found that these objectives can be achieved by azoline compounds of the general formulae Ia or Ib, wherein X is S, O or NR 4 ; Ar is phenyl or a 5 or 6 membered heteroaromatic ring; R 1 is H, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, phenyl, a heteroaromatic ring etc.; R 2a , R 2b are H, CN, C 1 -C 6 -alkyl etc.; R 1 together with R 2a may also form a linear C 2 -C 4 -alkandiyl; R 3a-d are H, halogen, C 1 -C 6 -alkyl etc.

    Abstract translation: 本发明涉及可用于防治节肢动物害虫的唑啉化合物及其盐。 本发明还涉及一种防治节肢动物害虫的方法和用于对抗所述害虫的农业组合物。 已经发现,这些目的可以通过通式Ia或Ib的唑啉化合物来实现,其中X是S,O或NR 4; Ar是苯基或5或6元杂芳环; R 1是H,C 1 -C 6 - 烷基,C 2 -C 6 - 亚烷基,苯基,杂芳环等; R 2a,R 2b是H,CN,C 1 -C 6 - 烷基等; R 1和R 2a一起也可以形成直链C 2 -C 4 - 亚烷基; R 3a-d为H,卤素,C 1 -C 6 - 烷基等。

    PESTCIDAL COMPOSITIONS
    7.
    发明申请
    PESTCIDAL COMPOSITIONS 审中-公开
    PESTCIDAL组合物

    公开(公告)号:WO2007071585A1

    公开(公告)日:2007-06-28

    申请号:PCT/EP2006/069525

    申请日:2006-12-11

    CPC classification number: C07D417/12

    Abstract: The present invention relates to 1-(Azolin-2-yl)-amino-alkane compounds, which are useful for combating insects, arachnids and nematodes. The present invention also relates to a method for combating animal pests selected from insects, arachnids and nematodes, and to agricultural compositions for combating animal pests. It has been found that animal pests can be combated by 1-(Azolin-2-yl)-amino-alkane compounds of the general formula (I) wherein A is a radical of the formulae (A 1 ) or (A 2 ): and wherein X is sulfur or oxygen and W, B and R 1 to R 6 are defined as in the description.

    Abstract translation: 本发明涉及1-(唑啉-2-基) - 氨基 - 烷烃化合物,其可用于防治昆虫,蜘蛛和线虫。 本发明还涉及一种防治选自昆虫,蜘蛛和线虫的动物害虫的方法以及用于对抗动物害虫的农业组合物。 已经发现,通过通式(I)的1-(氮杂环丁烷-2-基) - 氨基 - 烷烃化合物可以使动物害虫相互作用,其中A是式(A < )或(A 2 S 2):并且其中X是硫或氧,W,B和R 1至R 6定义如下: 描述。

    INDANYL-AND TETRAHYDRONAPHTHYL-AMINO-AZOLINE COMPOUNDS FOR COMBATING ANIMAL PESTS
    8.
    发明申请
    INDANYL-AND TETRAHYDRONAPHTHYL-AMINO-AZOLINE COMPOUNDS FOR COMBATING ANIMAL PESTS 审中-公开
    用于组合动物饲料的吲哚和四氢萘基 - 氨基 - 氨基酚化合物

    公开(公告)号:WO2007060121A1

    公开(公告)日:2007-05-31

    申请号:PCT/EP2006/068482

    申请日:2006-11-15

    CPC classification number: C07D277/18 C07D233/50 C07D263/28

    Abstract: The present invention relates to Indanyl- and Tetrahydronaphthyl-amino-azoline compounds of formula (I) wherein the variables R 1 and R 2 are as defined in description. The invention relates also to methods of combating or controlling insects, arachnids or nematodes, to methods for protecting growing plants from attack or infestation by insects, arachnids or nematodes, to methods for the protection of seeds from soil insects and of the seedlings' roots and shoots from soil and foliar insects and to methods for treating, controlling, preventing or protecting animals against infestation or infection by parasites.

    Abstract translation: 本发明涉及式(I)的茚满基和四氢萘基 - 氨基 - 唑啉化合物,其中变量R 1和R 2如描述中所定义。 本发明还涉及防治昆虫,蜘蛛或线虫的方法,用于保护生长植物免受昆虫,蜘蛛或线虫侵袭或侵染的方法,用于保护种子免受土壤昆虫和幼苗根部和 来自土壤和叶面昆虫的芽,以及用于治疗,控制,预防或保护动物免受寄生虫感染或感染的方法。

    PYRAZOLYLSUBSTITUIERTE THIENYLOXY-PYRIDINE
    10.
    发明申请
    PYRAZOLYLSUBSTITUIERTE THIENYLOXY-PYRIDINE 审中-公开
    PYRAZOLYLSUBSTITUIERTE thienyloxypyridines吡啶

    公开(公告)号:WO2003022843A1

    公开(公告)日:2003-03-20

    申请号:PCT/EP2002/009750

    申请日:2002-08-31

    CPC classification number: C07D409/14 A01N43/56

    Abstract: Die vorliegende Erfindung betrifft pyrazolylsubstituierte Thienyloxy-Pyridine der Formel I, in der die Variablen die folgenden Bedeutungen haben: R 1 , R 3 : Wasserstoff, Halogen, Cyano, Nitro, Alkyl, Halogenalkyl, Alkoxy oder Halogenalkoxy; R 2 : Wasserstoff, Halogen, Cyano, Alkenyl, Alkinyl, Halogenalkyl, Halogenalkenyl, Halogenalkinyl, Alkoxy, Alkenyloxy, Alkinyloxy, Halogenalkoxy, Alkoxyalkyl, Alkylamino, Di-(alkyl)amino, Alkylthio, Halogenalkylthio, Alkylsulfinyl, Halogenalkylsulfinyl, Alkylsulfonyl, Halogenalkylsulfonyl oder COR 7 ; R 4 , R 5 , R 6 : Wasserstoff, Halogen, Cyano, Alkyl, Halogenalkyl, Alkoxy, Halogenalkoxy, Alkylthio, Halogenalkylthio, Alkylsulfonyl oder Halogenalkylsulfonyl; R 7 :? ¿Wasserstoff, Hydroxy, Alkyl, Alkoxy, Amino, Alkylamino oder Di(alkyl)amino; sowie deren landwirtschaftlich brauchbaren Salze; Verfahren und Zwischenprodukte zu ihrer Herstellung; sowie die Verwendung dieser Verbindungen oder diese enthaltende Mittel zur Bekämpfung unerwünschter Pflanzen.

    Abstract translation: 本发明涉及噻吩氧基pyrazolylsubstituierte - 吡啶式I:其中各变量具有以下含义:R t <1>,R <3>是氢,卤素,氰基,硝基,烷基,卤代烷基,烷氧基或卤代烷氧基; [R <2>:氢,卤素,氰基,烯基,炔基,卤代烷基,卤代烯基,卤代炔基,烷氧基,链烯氧基,炔氧基,卤代烷氧基,烷氧基烷基,烷基氨基,二(烷基)氨基,烷硫基,卤代烷硫基,烷基亚磺酰基,卤代烷,烷基磺酰基, 卤代烷基磺酰基或COR <7>; [R <4>,R <5> - [R <6>:氢,卤素,氰基,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基,烷基磺酰基或卤代烷基磺酰基; [R <7>:<>是氢,羟基,烷基,烷氧基,氨基,烷基氨基或二(烷基)氨基; 及其可农用盐; 方法和中间体及其制备; 和使用这些化合物或组合物的包含它们的防治不希望的植物。

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