α-CYANOACRYLATES
    3.
    发明申请
    α-CYANOACRYLATES 审中-公开
    阿尔法 - 氰基丙烯酸酯

    公开(公告)号:WO2003051824A1

    公开(公告)日:2003-06-26

    申请号:PCT/EP2002/014353

    申请日:2002-12-17

    Abstract: α-Cyanoacrylates of the formula (I), where: R 1 is OR a wherein R a is hydrogen, substituted alkyl, branched alkyl, branched alkenyl, cycloloalkyl, heterocyclyl, aryl, phenylalkyl or alkyl­imino; is NR b R c wherein R b is hydrogen, alkyl which may be substituted, alkenyl, alkynyl; R c is hydrogen, alkyl which may be substituted alkenyl, alkynyl, cycloalkyl, heterocyclyl, aryl, phenylalkyl or alkylimino; or R b and R c form an alkandiyl-chain which may be substituted; or is SR d wherein R d is hydrogen, alkyl which may be substituted, alkenyl, alkynyl, cycloalkyl, heterocyclyl, aryl, phenylalkyl or alkylimino; R 2 is alkyl which may be substituted; is alkenyl or alkynyl; R 3 is alkyl may be substituted; is alkenyl or alkynyl; R 4 is hydrogen, halogen, cyano or alkyl; and their agriculturally useful salts, processes and intermediates for their preparation; and the use of these compounds or of compositions comprising these compounds for controlling undesirable plants are described.

    Abstract translation: 式(I)的烷基丙烯酸酯,其中:R 1是其中R a a是氢的取代的烷基,支链烷基 ,支链烯基,环烷基,杂环基,芳基,苯基烷基或烷基亚氨基; 其中R b是氢,可以被取代的烷基,烯基,炔基; 烯基,炔基,环烷基,杂环基,芳基,苯基烷基或烷基亚氨基; 或者R c和R c形成可以被取代的烷撑二链; 或者是其中R d为氢的烷基,可被取代的烷基,烯基,炔基,环烷基,杂环基,芳基,苯基烷基或烷基亚氨基; R 2是可被取代的烷基; 是烯基或炔基; R 3是烷基可以被取代; 是烯基或炔基; R 4是氢,卤素,氰基或烷基; 及其农业上有用的盐,其制备方法和中间体; 并且描述了这些化合物或包含这些化合物的组合物用于防治不期望的植物的用途。

    SUBSTITUIERTE PHTHALIMIDO-ZIMTSÄUREDERIVATE MIT HERBIZIDER WIRKUNG
    5.
    发明授权
    SUBSTITUIERTE PHTHALIMIDO-ZIMTSÄUREDERIVATE MIT HERBIZIDER WIRKUNG 失效
    用除草活性的取代的邻苯二甲酰亚胺酸衍生物

    公开(公告)号:EP0788479B1

    公开(公告)日:2000-04-19

    申请号:EP95936508.1

    申请日:1995-10-17

    Abstract: Disclosed are substituted phthalimido-cinnamic acid derivatives of formula (I), wherein R1 is H, C¿1?-C4-alkyl; R?2¿ is H, halogen; R3 is CN, NO¿2?, halogen, C1-C6-alkyl, C1-C6-alkyl halide, C1-C6-alkoxy, C1-C6-alkoxy halide; R?4¿ is H, CN, NO¿2?, halogen, C1-C6-alkyl; R?5¿ is H, C¿1?-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, substituted C1-C6-alkyl; R?6¿ is one of the radicals indicated under R5 or CN, NO¿2?, C1-C6-alkoxy, C1-C6-alkoxy halide, C1-C6-alkyl thio, C1-C6 alkyl thio halide, C3-C6-cycloalkyl, sustituted alkyl, C3-C6-alkenyl halide, (C1-C6-alkoxy)-carbonyl, COOH, (C1-C6-alkyl amino)carbonyl, di-(C1-C6-alkyl)amino carbonyl, (C1-C6-alkyl) carbonyl, (C1-C6-alkyl halide) carbonyl, optionally substituted aryl, hetaryl, aryl C1-C6 alkyl or hetaryl C1-C6 alkyl; or R?5 and R6¿ together are an alkylene chain, in which a methylene unit can be substituted a C¿1?-C4-alkyl imino group; R?7¿ is H, C¿1?-C6-alkyl, C3-C6-alkenyl, C3-C6 alkinyl, C2-C6 alkyl halide, C1-C6 cyanoalkyl, C1-C6 alkoxy C2-C6 alkyl, C1-C6-alkyl thio C2-C6 alkyl, (C1-C6-alkoxy)carbonyl-C1-C6-alkyl, optionally substituted phenyl or benzyl; X is O, S or N(R?8¿), as well as the salts of formula (I). Disclose also is their use as herbicides and for desication/defoliation of plants.

    HERBIZIDE BENZOYLDERIVATE
    6.
    发明公开
    HERBIZIDE BENZOYLDERIVATE 失效
    除草剂苯甲酰

    公开(公告)号:EP0811005A1

    公开(公告)日:1997-12-10

    申请号:EP96904761.0

    申请日:1996-02-13

    Abstract: The invention concerns benzoyl derivatives of formula (I) in which the substituents have the following meanings: L and M represent hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy (these groups being optionally substituted by one to five halogen atoms or C1-C4 alkoxy), halogen, cyano, nitro, a -(Y)n-S(O)mR7 or -(Y)¿n-CO-R?8 group; Z represents a five to six-membered heterocyclic saturated or unsaturated group containing one to three heteroatoms selected from the group comprising oxygen, sulphur and nitrogen and which can optionally be substituted by halogen, cyano, nitro, a -CO-R8 group, C¿1?-C4 alkyl, C1-C4 alkyl halide, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 alkoxy halide, C1-C4 alkyl thio, C1-C4 alkyl thio halide, di-C1-C4 alkyl amino, phenyl optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, or an oxo group which can be present in the tautomeric form as a hydroxy group, is substituted or, together with a condensation-bound phenyl ring which is optionally substituted by halogen or, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, with a condensation-bound carbocycle or with a condensation-bound second heterocycle which can optionally be substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4 alkyl amino, C1-C4 alkoxy, C1-C4 alkoxy halide or a C1-C4 alkyl halide, forms a bicyclic system; Y represents O or NR?9¿; n is 0 or 1; m is 0, 1 or 2; R7 represents C¿1?-C4 alkyl, C1-C4 alkyl halide or NR?9R10; R8¿ represents C¿1?-C4 alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or NR?9R10; R9¿ represents hydrogen or C¿1?-C4 alkyl; R?10¿ represents C¿1?-C4 alkyl; Q represents a cyclohexane-1,2-dione ring connected at position 2 and of formula (II) in which R?1, R2, R4 and R6¿ represent hydrogen or C¿1?-C4 alkyl, R?5¿ represents hydrogen, C¿1?-C4 alkyl or a -COOR?10¿ group, R3 represents hydrogen, C¿1?-C4 alkyl, C3-C6 cycloalkyl, these groups optionally including one to three of the following substituents: halogen, C1-C4 alkyl thio, C1-C4 alkoxy, or R?3¿ represents tetrahydropropanyl-3, tetrahydropropanyl-4 or tetrahydrothiopyranyl-3, or R?3 and R5¿ together form a bond or a three to six-membered carbocyclic ring. The invention also concerns standard agricultural salts of compounds of formula (I) usually utilized in agriculture.

    HETAROYLCYCLOHEXANDIONDERIVATE MIT HERBIZIDER WIRKUNG
    10.
    发明授权
    HETAROYLCYCLOHEXANDIONDERIVATE MIT HERBIZIDER WIRKUNG 失效
    HETAROYLCYCLOHEXANDIONIONDERIVATE MIT HERBIZIDER WIRKUNG

    公开(公告)号:EP0931070B1

    公开(公告)日:2003-03-19

    申请号:EP97941998.3

    申请日:1997-09-09

    Abstract: Hetaroyl derivatives having the formula (I) are disclosed, as well as their salts useful in agriculture. In the formula, the variables have the following meanings: R1, R2 are hydrogen, nitro, halogen, cyano, rhodano, hydroxy, mercapto, optionally substituted and/or functionalised C¿1?-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 alkoxysulfonyl, or optionally substituted phenyl, phenoxy, phenylthio, phenylsulfinyl or phenylsulfonyl; Z is an optionally substituted, 4-membered, unsaturated, partially or completely saturated chain with three carbon atoms and one nitrogen atom; and Q is optionally substituted cyclohexan-1,3-dione linked at position 2. Also disclosed is a process for preparing the hetaroyl derivatives, agents containing the same, as well as the use of these derivatives or the agents containing the same for controlling undesirable plants.

    Abstract translation: 公开了具有式(I)的Hetaroyl衍生物及其在农业中有用的盐。 在该式中,变量具有以下含义:R 1,R 2是氢,硝基,卤素,氰基,rhodano,羟基,巯基,任选取代和/或官能化的C 1 -C 6烷基,C 1 -C 6烷氧基, C6烷基硫基,C1-C6烷基亚磺酰基,C1-C6烷基磺酰基,C1-C6烷氧基磺酰基或任选取代的苯基,苯氧基,苯硫基,苯基亚磺酰基或苯基磺酰基; Z是具有三个碳原子和一个氮原子的任选取代的4元不饱和部分或完全饱和链; 并且Q是在位置2处连接的任选取代的环己-1,3-二酮。还公开了制备杂芳酰基衍生物的方法,含有它们的试剂,以及这些衍生物或含有它们的试剂用于防治不希望的 植物。

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