公开(公告)号：JP2013075829A

公开(公告)日：2013-04-25

申请号：JP2013008446

申请日：2013-01-21

Applicant: Evonik Degussa Gmbh ,  エボニック デグサ ゲーエムベーハーEvonik Degussa GmbH

Inventor： SCHULZE-ISFORT CHRISTIAN ,  KLOTZ OSWIN ,  GOLCHERT RAINER ,  DIENER UWE ,  SCHUMACHER KAI

IPC: C01G23/07 ,  C04B35/626 ,  C23C16/40 ,  C23C16/453

CPC classification number: C01G23/07 ,  C01P2004/80 ,  C01P2006/11 ,  C01P2006/12 ,  C04B35/46 ,  C04B35/62665 ,  C04B35/6268 ,  C04B2235/3232 ,  C04B2235/444 ,  C04B2235/5409 ,  C04B2235/724 ,  C04B2235/76 ,  Y02P20/129

Abstract: PROBLEM TO BE SOLVED: To provide titanium dioxide powder having high sintering activity.SOLUTION: This invention relates to crystalline titanium dioxide powder in the form of aggregated primary particles having a BET surface area of 30-65 m/g and a rutile content of 50-70%. It is produced by introducing titanium tetrachloride vapor and, separately therefrom, hydrogen, air or oxygen-enriched air into a mixing chamber, subsequently igniting the mixture of titanium tetrachloride vapor, hydrogen and primary air in a burner and burning the flame into a reaction chamber and subsequently separating off the solid from gaseous substances, where the amounts used therefor are selected so as to satisfy following equation: A=A=10{[(TiCl×H)/(amount of air×total gas)]/BET}, [in the equation, A=6-12 is obeyed]. The titanium dioxide powder can be used in the ceramics industry.

Abstract translation: 要解决的问题：提供具有高烧结活性的二氧化钛粉末。 本发明涉及具有BET表面积为30-65μm的聚集的一次颗粒形式的结晶二氧化钛粉末和金红石含量 50-70％。 它是通过将四氯化钛蒸气和与其分开的氢气，空气或富氧空气引入混合室而产生的，随后在燃烧器中点燃四氯化钛蒸汽，氢气和一次空气的混合物，并将火焰燃烧成反应室 然后将固体与气态物质分离，其中选择用于其的量以满足以下等式：A = A = 10 <（SPC = SBST = “POST”> 4 ×H 2 ）/（空气量×总气体）] / BET}，[式中，A = 6-12 服从]。 二氧化钛粉末可用于陶瓷工业。 版权所有（C）2013，JPO＆INPIT

公开(公告)号：JP2013053067A

公开(公告)日：2013-03-21

申请号：JP2012277136

申请日：2012-12-19

Applicant: Evonik Degussa Gmbh ,  エボニック デグサ ゲーエムベーハーEvonik Degussa GmbH

Inventor： SCHULZE-ISFORT CHRISTIAN ,  SCHUMACHER KAI ,  SCHUHARDT NINA ,  KLOTZ OSWIN ,  GOLCHERT RAINER

IPC: C01G23/07

CPC classification number: C04B35/62665 ,  B01J21/063 ,  B01J35/002 ,  B01J35/1014 ,  B01J37/0238 ,  B01J37/349 ,  C01G23/07 ,  C01P2004/50 ,  C01P2004/80 ,  C01P2006/11 ,  C01P2006/12 ,  C04B2235/3232 ,  C04B2235/5409 ,  Y10T428/2982

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a titanium dioxide powder.SOLUTION: The crystalline titanium dioxide powder in the form of aggregated primary particles has a BET surface area of 70-100 m/g and a rutile content of higher than 10% but less than or equal to 40%. The method for producing the titanium dioxide powder includes: introducing titanium tetrachloride vapor, and separately therefrom, hydrogen, air or oxygen-enriched air into a mixing chamber; igniting a mixture of the titanium tetrachloride vapor, hydrogen and primary air in a burner to obtain a flame; burning the flame in a reaction chamber; and subsequently separating the solid from gaseous substances, wherein the amounts used are selected to satisfy expression A: A=10{[(TiClX H)/(amount of air x total gas)]/BET} (wherein A is 0.1-0.4).

Abstract translation: 待解决的问题：提供二氧化钛粉末的制造方法。 解决方案：聚集的一次颗粒形式的结晶二氧化钛粉末的BET表面积为70-100μm，金红石含量高于10 ％但小于或等于40％。 制备二氧化钛粉末的方法包括：将四氯化钛蒸汽和与其分开的氢气，空气或富氧空气引入混合室; 在燃烧器中点燃四氯化钛蒸气，氢气和一次空气的混合物以获得火焰; 在反应室内燃烧火焰; 并且随后将固体与气态物质分离，其中选择所用量以满足表达式A：A = 10 ä[（TiCl 4 < / SB> XH 2 ）/（空气量x总气体）] / BET}（其中A为0.1-0.4）。 版权所有（C）2013，JPO＆INPIT

公开(公告)号：JP2006213915A

公开(公告)日：2006-08-17

申请号：JP2005372186

申请日：2005-12-26

Applicant: Degussa Ag ,  デグサ アクチエンゲゼルシャフトDegussa AG

Inventor： MAIER JUERGEN ,  SCHUMACHER KAI ,  HASENZAHL STEFFEN DR ,  RIEDEMANN HEIKE ,  GRAY ANN

IPC: C09C1/36 ,  A61K8/29 ,  A61Q17/04 ,  C01G23/00 ,  C09C3/06 ,  C09C3/12

CPC classification number: C08K9/06 ,  C01P2006/11 ,  C01P2006/12 ,  C09C1/3684

Abstract: PROBLEM TO BE SOLVED: To provide a titanium dioxide produced by thermal decomposition which exhibits satisfactory transparency and does not cause an unpleasant and dull feeling on a skin when used as a tanning preventive agent, and to provide a formulation for a tanning preventive agent using the same. SOLUTION: The titanium dioxide is surface-modified and covered with the silicon dioxide, is produced by the thermal decomposition, and especially, is produced by flame hydrolysis. The titanium dioxide and the formulation for a tanning preventive agent using the same is obtained by spraying a surface-treating agent onto the titanium dioxide covered with silicon dioxide, followed by treating the resultant product at a certain temperature. COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供通过热分解制备的二氧化钛，其表现出令人满意的透明度，并且当用作防晒剂时不会在皮肤上引起令人不愉快和无光泽的感觉，并提供用于鞣制预防剂的制剂 代理使用相同。 解决方案：二氧化钛被表面改性并被二氧化硅覆盖，通过热分解产生，特别是通过火焰水解产生。 通过将表面处理剂喷雾到覆盖有二氧化硅的二氧化钛上，然后在一定温度下处理所得产物，得到二氧化钛和使用该二氧化钛的鞣制防止剂的制剂。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2006193405A

公开(公告)日：2006-07-27

申请号：JP2005106834

申请日：2005-04-01

Applicant: Degussa Ag ,  デグサ アクチエンゲゼルシャフトDegussa AG

Inventor： SCHUMACHER KAI ,  KERNER DIETER DR ,  SCHILLING ROLAND ,  FLESCH JUERGEN ,  SCHIENER THOMAS

IPC: C01B33/18 ,  C08K3/36 ,  C08L67/00 ,  C08L83/04

CPC classification number: C01B33/18 ,  C01B33/183 ,  C01P2004/64 ,  C01P2006/12 ,  C09C1/30

Abstract: PROBLEM TO BE SOLVED: To provide a silicon dioxide powder displaying a good thickening action combined with a short incorporation time into polymers, particularly polyester resins. SOLUTION: The silicon dioxide powder is pyrogenically produced in the form of aggregates of primary particles having a BET surface area of 200±25 m 2 /g, wherein the aggregates display an average surface area of 7,000 to 12,000 nm 2 , an average equivalent circle diameter (ECD) of 80 to 100 nm and an average circumference of 850 to 1,050 nm. COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供一种二氧化硅粉末，其显示出良好的增稠作用，并将结合时间短于聚合物，特别是聚酯树脂。 解决方案：二氧化硅粉末以BET表面积为200±25m 2 / SP / g / g的一次粒子的聚集体的形式热解生产，其中聚集体显示平均表面积 7,000至12,000nm 2 ，平均当量圆直径（ECD）为80至100nm，平均周长为850至1050nm。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2006193404A

公开(公告)日：2006-07-27

申请号：JP2005106833

申请日：2005-04-01

Applicant: Degussa Ag ,  デグサ アクチエンゲゼルシャフトDegussa AG

Inventor： SCHUMACHER KAI ,  KERNER DIETER DR ,  DIENER UWE ,  SCHOLZ MARIO DR

IPC: C01B33/18 ,  C09D7/12 ,  C09D183/04 ,  C09D201/00 ,  C09K3/10

CPC classification number: C08K3/36 ,  C01B33/183 ,  C09K3/1018 ,  C08L83/04 ,  C08L21/00

Abstract: PROBLEM TO BE SOLVED: To provide a silicon dioxide powder displaying a good thickening action combined with a short incorporation time into polymers and good dispersibility in the polymers, particularly silicone polymers.
SOLUTION: The silicon dioxide powder is pyrogenically produced in the form of aggregates of primary particles having a BET surface area of 150±15 m
2 /g, wherein the aggregates display an average surface area of 12,000 to 20,000 nm
2 , an average equivalent circle diameter (ECD) of 90 to 120 nm and an average circumference of 1,150 to 1,700 nm, and the powder is produced by a pyrogenic process.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供显示出良好的增稠作用的二氧化硅粉末，并将聚合物的掺入时间短，并且在聚合物，特别是硅氧烷聚合物中具有良好的分散性。 解决方案：二氧化硅粉末以BET表面积为150±15m 2 / SP / g / g的一次粒子的聚集体的形式热解生产，其中聚集体显示平均表面积 12000〜20,000nm（SPCD）2，平均当量圆直径（ECD）为90〜120nm，平均周长为1150〜1700nm，通过热解法制造粉末。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2006193403A

公开(公告)日：2006-07-27

申请号：JP2005106635

申请日：2005-04-01

Applicant: Degussa Ag ,  デグサ アクチエンゲゼルシャフトDegussa AG

Inventor： SCHUMACHER KAI ,  ISHIBASHI NARIYASU ,  KOBAYASHI HITOSHI ,  PAUL BRANDL

IPC: C01B33/18

CPC classification number: C01B33/183 ,  Y10T428/2982

Abstract: PROBLEM TO BE SOLVED: To provide a silicon dioxide powder that can be incorporated quickly into liquid media. SOLUTION: The silicon dioxide powder is pyrogenically produced in the form of aggregates of primary particles having a BET surface area of 300±25 m 2 /g, wherein the aggregates display an average surface area of 4,800 to 6,000 nm 2 , an average equivalent circle diameter (ECD) of 60 to 80 nm and an average circumference of 580 to 750 nm, is produced. COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供可以迅速并入液体介质中的二氧化硅粉末。 解决方案：二氧化硅粉末以BET表面积为300±25m 2 / SP / g / g的一次粒子的聚集体的形式热解生产，其中聚集体显示平均表面积 4,800〜6000nm 2，平均当量圆直径（ECD）为60〜80nm，平均周长为580〜750nm。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2006193401A

公开(公告)日：2006-07-27

申请号：JP2005035119

申请日：2005-02-10

Applicant: Degussa Ag ,  デグサ アクチエンゲゼルシャフトDegussa AG

Inventor： SCHUMACHER KAI ,  JACOBSEN HAUKE ,  BRANDES RALPH DR ,  ROCHNIA MATTHIAS DR ,  SHIBAZAKI TAKEYOSHI ,  ISHIBASHI NARIYASU

IPC: C01B33/18 ,  B01J21/08 ,  B01J32/00 ,  C08K3/36 ,  C08L101/00 ,  C09D7/12 ,  C09K3/14

CPC classification number: C09K3/1463 ,  C01B33/1417 ,  C01B33/183 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2998

Abstract: PROBLEM TO BE SOLVED: To provide a silicon dioxide powder that can be mixed quickly into liquid media. SOLUTION: The silicon dioxide powder is a pyrogenically produced silicon dioxide powder in the form of aggregates of primary particles having a BET surface area of 90±15 m 2 /g, wherein the aggregates display an average surface area of 10,000 to 20,000 nm 2 , an average equivalent circle diameter of 90 to 130 nm and an average circumference of 1,000 to 1,400 nm. The powder is produced by a pyrogenic process in which SiCl 4 and a second silicon component selected from the group comprising H 3 SiCl, H 2 SiCl 2 , HSiCl 3 , CH 3 SiCl 3 , (CH 3 ) 2 SiCl 2 , (CH 3 ) 3 SiCl and (n-C 3 H 7 )SiCl 3 are mixed with primary air and a combustion gas and burnt into a reaction chamber. At this time, secondary air is also introduced into the reaction chamber, and the feed materials are chosen so that the adiabatic flame temperature T ad becomes 1,810 to 1,890°C. A dispersion containing the pyrogenically produced silicon dioxide powder is also provided. COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供可以快速混合到液体介质中的二氧化硅粉末。 解决方案：二氧化硅粉末是热原生产的二氧化硅粉末，其形式为BET表面积为90±15m 2 / SP / g / g的一次粒子的聚集体，其中聚集体显示出 平均表面积为10,000〜20,000nm 2 ，平均当量圆直径为90〜130nm，平均周长为1000〜1400nm。 该粉末是通过热解法制备的，其中SiCl 4 和第二硅成分选自包含H 3 SB 3 SiCl，H SB 2 SiCl 2 ，HSiCl 3 ，CH 3 SiCl 3 SB 3，（CH 3 SB 3） SB> 2 SiCl 2 ，（CH 3 SB 3）3 SiCl和（nC 3 SB 3） SB> 7 ）将SiCl 3 SB与一次空气和燃烧气体混合并燃烧到反应室中。 此时，二次空气也被引入到反应室中，并且进料材料被选择为使得绝热火焰温度T ad 变为1,810至1,890℃。 还提供含有热解法生产的二氧化硅粉末的分散体。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2006176401A

公开(公告)日：2006-07-06

申请号：JP2005372187

申请日：2005-12-26

Applicant: Degussa Ag ,  デグサ アクチエンゲゼルシャフトDegussa AG

Inventor： MAIER JUERGEN ,  SCHUMACHER KAI ,  HASENZAHL STEFFEN DR ,  RIEDEMANN HEIKE ,  GRAY ANN

IPC: C01G23/04 ,  A61K8/25 ,  A61K8/27 ,  A61K8/29 ,  A61Q17/04

CPC classification number: C09C1/3661 ,  A61K8/25 ,  A61K8/29 ,  A61Q17/04 ,  C01P2006/11 ,  C01P2006/12 ,  C09C1/0084 ,  C09C1/3684 ,  Y10T428/2991 ,  Y10T428/2995

Abstract: PROBLEM TO BE SOLVED: To provide a silicon-titanium mixed dioxide which is produced by pyrolysis and does not exhibit drawbacks of prior art. SOLUTION: There is provided a surface-modified silicon-titanium mixed dioxide produced by pyrolysis. The method of producing the mixed dioxide comprises: spraying water on the silicon-titanium mixed dioxide produced by pyrolysis in a mixer as needed; spraying a surface-modifying agent; mixing as needed; and then temperature-treating the obtained mixture. COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供通过热解产生并且不具有现有技术的缺点的硅 - 钛混合二氧化物。 解决方案：提供通过热解产生的表面改性的硅 - 钛混合二氧化物。 制备混合二氧化物的方法包括：根据需要在混合器中通过热解产生的硅 - 钛混合二氧化物上喷洒水; 喷涂表面改性剂; 根据需要混合; 然后对得到的混合物进行温度处理。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2003297781A

公开(公告)日：2003-10-17

申请号：JP2003028820

申请日：2003-02-05

Applicant: Degussa Ag ,  デグサ アクチエンゲゼルシャフト

Inventor： SCHUMACHER KAI ,  MANGOLD HELMUT ,  MAIER JUERGEN ,  LORTZ WOLFGANG DR ,  BATZ-SOHN CHRISTOPH DR

IPC: B24B37/00 ,  B01J13/00 ,  C09C1/30 ,  C09G1/02 ,  C09K3/14 ,  H01L21/304 ,  H01L21/3105

CPC classification number: C09K3/1463 ,  C01P2004/84 ,  C01P2006/12 ,  C09C1/3054 ,  C09G1/02 ,  C09K3/1409 ,  H01L21/31053 ,  Y10T428/2993

Abstract: PROBLEM TO BE SOLVED: To produce aqueous dispersion liquid containing a cerium oxide easily and to regulate grain size reproducibly such that the dispersion liquid contains impurities at a small ratio. SOLUTION: From a core of doped silicon dioxide having a low-level structure produced by thermal decomposition, the aqueous dispersion liquid containing a cerium salt solution or the mixture of the salt solution and a suspension, more preferably powder produced when a cerium oxide shell is formed by spraying them, is produced such that the powder in the dispersion liquid has an average secondary grain size not exceeding 0.2 μm. COPYRIGHT: (C)2004,JPO

Abstract translation: 解决问题：为了容易地制造含有氧化铈的水性分散液，可再现性地调节粒径，使得分散液含有少量的杂质。 解决方案：从具有通过热分解产生的低级结构的掺杂二氧化硅的核心，含有铈盐溶液的水分散液或盐溶液和悬浮液的混合物，更优选当铈 通过喷雾形成氧化物壳，使得分散液中的粉末的平均二次粒径不超过0.2μm。 版权所有（C）2004，JPO

公开(公告)号：WO2009050013A2

公开(公告)日：2009-04-23

申请号：PCT/EP2008062833

申请日：2008-09-25

Applicant: EVONIK DEGUSSA GMBH ,  LORTZ WOLFGANG ,  SCHUMACHER KAI ,  PIETSCH JOERG

Inventor： LORTZ WOLFGANG ,  SCHUMACHER KAI ,  PIETSCH JOERG

IPC: C01B33/141

CPC classification number: C01B33/141 ,  B82Y30/00 ,  C01B33/1415 ,  C01B33/1417 ,  C01B37/005 ,  C01G23/04 ,  C01G23/047 ,  C01P2002/52 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/19 ,  C01P2006/22 ,  C01P2006/80

Abstract: Process for preparing an aqueous dispersion which has a pH of 9 to 14 and comprises particles of a pyrogenic titanium- silicon mixed oxide powder having a proportion of silicon dioxide of 75 to 99.99% by weight and of titanium dioxide of 0.01 to 25% by weight, whose mean aggregate diameter in the dispersion is not more than 200 nm, and at least one basic, quaternary ammonium compound.

Abstract translation: 制备pH为9〜14的水性分散体的方法，其包含二氧化硅比例为75〜99.99重量％，二氧化钛为0.01〜25重量％的热解钛硅混合氧化物粉末的粒子 ，其分散体中的平均聚集体直径不大于200nm，和至少一种碱性季铵化合物。