公开(公告)号：WO2009009413A3

公开(公告)日：2009-03-12

申请号：PCT/US2008069139

申请日：2008-07-03

Applicant: HONEYWELL INT INC ,  SINGH RAJIV R ,  SHANKLAND IAN ,  HULSE RYAN

Inventor： SINGH RAJIV R ,  SHANKLAND IAN ,  HULSE RYAN

IPC: C09K5/04 ,  C07C19/08

CPC classification number: C09K5/045 ,  C09K2205/122 ,  C09K2205/126

Abstract: Disclosed are heat transfer compositions, and methods of using and selecting heat transfer compositions, in which the composition comprises a first component comprising difluoromethane (R-32), and at least one second component selected from group consisting of CF3I, 1,2,3,3,3-pentafluoropropene (HFO 1225ye), and combinations of these, and optionally, but preferably, at least one third component selected from the group consisting of fluorinated C2 - C3 compounds, including any combination of two or more fluorinated C2 - C3 compounds.

Abstract translation: 公开了传热组合物以及使用和选择传热组合物的方法，其中组合物包含含有二氟甲烷（R-32）的第一组分和选自CF 3 I，1,2,3 ，3,5-五氟丙烯（HFO 1225ye）以及它们的组合，并且任选但优选至少一种选自氟化C2-C3化合物，包括两种或更多种氟化C2-C3的任何组合的第三组分 化合物。

公开(公告)号：WO2012154227A3

公开(公告)日：2013-03-28

申请号：PCT/US2012021061

申请日：2012-01-12

Applicant: HONEYWELL INT INC ,  MERKEL DANIEL C ,  WANG HAIYOU ,  POKROVSKI KONSTANTIN A ,  TUNG HSUEH SUNG ,  SHANKLAND IAN

Inventor： MERKEL DANIEL C ,  WANG HAIYOU ,  POKROVSKI KONSTANTIN A ,  TUNG HSUEH SUNG ,  SHANKLAND IAN

IPC: C07C17/20 ,  B01J19/24 ,  C07C17/42 ,  C07C21/18

CPC classification number: C07C17/25 ,  C07C17/087 ,  C07C17/206 ,  Y02P20/125 ,  Y02P20/582 ,  C07C21/18 ,  C07C19/10 ,  C07C19/08

Abstract: Disclosed is an integrated process to co-produce trans-1-chloro-3,3,3-trifluoro- propene (1233zd(E)), trans-1,3,3,3-tetrafluoropropene (1234ze(E)), and 1,1,1,3,3- pentafluoropropane (245fa). Overall the co-production is a three-step process. The chemistry involves the steps of: (1) the reaction of 240fa with anhydrous HF in excess in a liquid-phase catalyzed reactor in such a way as to co-produce primarily 1233zd(E) and 244fa (plus byproduct HC1); (2) the 244fa stream can then be used to directly produce any of the three desired products; (3 a) the 244fa stream can be dehydrochlorinated to produce the desired second product 1234ze(E); and/or (3b) the 244fa stream can be dehydrofluorinated to produce 1233zd(E) if more of that product is desired; and/or (3 c) the 244fa stream can be further fluorinated to form 245 fa.

Abstract translation: 公开了共反应产生反式-1-氯-3,3,3-三氟丙烯（1233zd（E）），反式-1,3,3,3-四氟丙烯（1234ze（E））和 1,1,1,3,3-五氟丙烷（245fa）。 总的来说，联合制作是一个三步骤的过程。 该化学方法包括以下步骤：（1）在液相催化反应器中240fa与无水HF过量反应，主要共同生产1233zd（E）和244fa（加副产物HC1）; （2）然后可以使用244fa流直接生产三种所需产物中的任何一种; （3a）244fa流可以脱氯化氢以产生所需的第二产物1234ze（E）; 和/或（3b）如果需要更多的该产物，则244fa流可以被脱氟化氢以产生1233zd（E） 和/或（3c）244fa流可以进一步氟化以形成245fa。

公开(公告)号：WO2010088196A3

公开(公告)日：2010-11-25

申请号：PCT/US2010022053

申请日：2010-01-26

Applicant: HONEYWELL INT INC ,  HULSE RYAN ,  SINGH RAJIV RATNA ,  TUNG HSUEH SUNG ,  SHANKLAND IAN

Inventor： HULSE RYAN ,  SINGH RAJIV RATNA ,  TUNG HSUEH SUNG ,  SHANKLAND IAN

IPC: C11D7/50 ,  C01B7/19 ,  C07C17/25 ,  C07C19/08 ,  C07C21/18 ,  C11D7/30

CPC classification number: C07C19/08 ,  C07C17/206 ,  C07C17/25 ,  C07C17/383 ,  C07C21/18

Abstract: The invention is directed to a ternary azeotrope-like mixture consisting essentially of effective amounts of 1,1,1,3,3-pentafluoropropane, 1-chloro-3,3,3-trifluoropropene, and hydrogen fluoride.

Abstract translation: 本发明涉及基本上由有效量的1,1,1,3,3-五氟丙烷，1-氯-3,3,3-三氟丙烯和氟化氢组成的三元类共沸混合物。

公开(公告)号：WO2012148695A3

公开(公告)日：2013-02-28

申请号：PCT/US2012033419

申请日：2012-04-13

Applicant: HONEYWELL INT INC ,  WANG HAIYOU ,  MERKEL DANIEL C ,  POKROVSKI KONSTANTIN A ,  TUNG HSUEH SUNG ,  SHANKLAND IAN

Inventor： WANG HAIYOU ,  MERKEL DANIEL C ,  POKROVSKI KONSTANTIN A ,  TUNG HSUEH SUNG ,  SHANKLAND IAN

IPC: C07C17/087 ,  B01J21/06 ,  B01J23/18 ,  C07C21/18

CPC classification number: C07C17/206 ,  C07B2200/09 ,  C07C17/087 ,  C07C17/25 ,  C07C17/383 ,  Y02P20/125 ,  C07C19/10 ,  C07C19/08 ,  C07C21/18

Abstract: Disclosed is a fully integrated process for making 1,1,1,3,3-pentafluoropropane (HFC-245fa), trans-1-chloro-3,3,3-trifluoropropene (HCFO-1233zd(E)), and trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)). The chemistry involves (a) the reaction of 1,1,1,3,3-pentachloropropane (HCC-240fa), or a derivative thereof selected from 1,1,3,3-tetrachloropropene and 1,3,3,3-tetrachloropropene, with anhydrous HF in excess in the presence of a catalyst in a liquid-phase reactor in such a way as to co-produce HCFO-1233zd, HFO-1234ze, HCFC-244fa (3-chloro-1,1,1,3-tetrafluoropropane), and HFC-245fa in a first reactor; (b) the reaction of HCFO-1233zd and HFO-1234ze with HCl in excess in the presence of a catalyst in a second reactor to convert these two olefins into HCFC-243fa and HCFC-244fa, respectively; (c) the reaction of HCFC-243fa and HCFC-244fa over a dehydrochlorination catalyst or in a caustic solution in a third reactor to form HCFO-1233zd and HFO-1234ze; and (d) the reaction of HCFO-1233zd(Z) and HFO-1234ze(Z) in the presence of a catalyst in a fourth reactor to form trans-1233zd and trans-1234ze, respectively.

Abstract translation: 公开了制备1,1,1,3,3-五氟丙烷（HFC-245fa），反式-1-氯-3,3,3-三氟丙烯（HCFO-1233zd（E））的完全一体化方法， 1,3,3,3-四氟丙烯（HFO-1234ze（E））。 该化学方法包括（a）1,1,1,3,3-五氯丙烷（HCC-240fa）或其衍生物选自1,1,3,3-四氯丙烯和1,3,3,3-四氯丙烯的反应， 四氯丙烯，在催化剂存在下，在液相反应器中以无水HF过剩，以共同生产HCFO-1233zd，HFO-1234ze，HCFC-244fa（3-氯-1,1,1， 3-四氟丙烷）和HFC-245fa在第一反应器中; （b）HCFO-1233zd和HFO-1234ze与HCl在过渡催化剂存在下在第二反应器中的反应，分别将这两种烯烃转化为HCFC-243fa和HCFC-244fa; （c）HCFC-243fa和HCFC-244fa在脱氯化氢催化剂或第三反应器中的苛性碱溶液中的反应，形成HCFO-1233zd和HFO-1234ze; 和（d）HCFO-1233zd（Z）和HFO-1234ze（Z）在催化剂存在下在第四反应器中的反应分别形成反式-1233zd和反式1234ze。

公开(公告)号：WO2009011987A9

公开(公告)日：2009-03-19

申请号：PCT/US2008065918

申请日：2008-06-05

Applicant: HONEYWELL INT INC ,  SINGH RAJIV R ,  SHANKLAND IAN

Inventor： SINGH RAJIV R ,  SHANKLAND IAN

IPC: B01J20/26 ,  C09K3/32

CPC classification number: B01J19/06 ,  B01J19/00 ,  B01J20/26 ,  B01J20/261 ,  B01J20/264 ,  B01J20/267 ,  B01J2220/445 ,  C09K3/32

Abstract: Disclosed are methods for treating hazardous materials, such as those which result from an unwanted spill or leak, which comprise one or more of the steps or effects of: neutralizing the dispersed material; solidifying the dispersed material; immobilizing the material; and/or reducing the evolution of harmful or unwanted gaseous forms from the spillage, preferably using a binding agent which comprises a polyacrylate-polyacrylamide cross-linked copolymer.

Abstract translation: 公开了用于处理危险材料的方法，例如由不想要的溢出或泄漏引起的危险物质的方法，其包括以下步骤或效果中的一种或多种：中和分散的材料; 固化分散材料; 固定材料; 和/或减少来自溢出物的有害或不需要的气态形式的演化，优选使用包含聚丙烯酸酯 - 聚丙烯酰胺交联共聚物的粘合剂。

公开(公告)号：WO2012094288A3

公开(公告)日：2012-08-30

申请号：PCT/US2012020035

申请日：2012-01-03

Applicant: HONEYWELL INT INC ,  POKROVSKI KONSTANTIN A ,  SINGH RAJIV RATNA ,  SHANKLAND IAN ,  TUNG HSUEH SUNG

Inventor： POKROVSKI KONSTANTIN A ,  SINGH RAJIV RATNA ,  SHANKLAND IAN ,  TUNG HSUEH SUNG

IPC: C07C17/20 ,  C07B39/00 ,  C07C19/10 ,  C07C21/18

CPC classification number: C07C17/361 ,  C07B2200/09 ,  C07C17/206 ,  C07C17/25 ,  C07C19/10 ,  C07C21/18

Abstract: The present invention discloses high purity E-1-chloro-3,3,3-trifluoropropene (1233zd(E)) and methods to produce the same. More specifically, the present invention discloses the methods of making 1233zd(E) essentially free of toxic impurities (e.g. 2-chloro-3,3,3-trifluoropropene (1233xf), chlorotetrafluoro-propene (1224), and 3,3,3-trifluoropropyne). The present invention further provides methods for making high purity 1233zd(E) with concentration of 1233xf and 1224 at or below 200 parts per million (ppm) and 3,3,3-trifluoropropyne impurities at or below 20 ppm. Formation of 1233xf impurity can be avoided if pure 1,1,1,3,3-pentachloropropane is used as a starting material. It was also found that formation of 1233xf is avoided if a liquid phase manufacturing process is used.

Abstract translation: 本发明公开了高纯度E-1-氯-3,3,3-三氟丙烯（1233zd（E））及其制备方法。 更具体地说，本发明公开了制备基本上不含有毒杂质的1233zd（E）的方法（例如2-氯-3,3,3-三氟丙烯（1233xf），氯四氟丙烯（1224）和3,3,3 -trifluoropropyne）。 本发明还提供了制备浓度为1233xf和1224等于或低于200ppm（ppm）的高纯度1233zd（E）和等于或低于20ppm的3,3,3-三氟丙炔杂质的方法。 如果使用纯1,1,1,3,3-五氯丙烷作为原料，则可以避免形成1233xf杂质。 还发现如果使用液相制造方法，则避免形成1233xf。

公开(公告)号：WO2009132242A3

公开(公告)日：2009-12-17

申请号：PCT/US2009041615

申请日：2009-04-24

Applicant: HONEYWELL INT INC ,  SINGH RAJIV R ,  SHANKLAND IAN ,  BOWMAN JAMES M ,  WILLIAMS DAVID J

Inventor： SINGH RAJIV R ,  SHANKLAND IAN ,  BOWMAN JAMES M ,  WILLIAMS DAVID J

IPC: C08J9/06 ,  C08J9/00 ,  C08J9/04 ,  C08K5/02 ,  C08L23/04 ,  C08L23/10 ,  C08L25/04 ,  C08L61/04 ,  C08L75/04

CPC classification number: C07C21/18 ,  C08G2101/00 ,  C08J9/144 ,  C08J9/147 ,  C08J2205/052

Abstract: Provided are foam blowing agents comprising one or more chlorofluoroolefins selected from 1,2-dichloro-1,2-difluoroethene, 3,3-dichloro-3-fluoropropene, 2-chloro-1,1,1,3,4,4,4-heptafluoro-2-butene, and 2-chloro-1,1,1,4,4,4-hexafluoro-2-butene, as well as foams produced therefrom.

Abstract translation: 提供的是含有一种或多种选自1,2-二氯-1,2-二氟乙烯，3,3-二氯-3-氟丙烯，2-氯-1,1,1,3,4,4， 4-七氟-2-丁烯和2-氯-1,1,1,4,4,4-六氟-2-丁烯，以及由其制备的泡沫。

公开(公告)号：WO2008061083A3

公开(公告)日：2008-09-18

申请号：PCT/US2007084515

申请日：2007-11-13

Applicant: HONEYWELL INT INC ,  THOMAS RAYMOND H ,  SINGH RAJIV R ,  SAMUELS GEORGE J ,  SHANKLAND IAN ,  WILSON DAVID P ,  ROBINSON ROY P ,  VANDERPUY MICHAEL ,  WELCH JOHN L ,  SHAFER GREGORY J ,  SPATZ MARK W ,  HULSE RYAN

Inventor： THOMAS RAYMOND H ,  SINGH RAJIV R ,  SAMUELS GEORGE J ,  SHANKLAND IAN ,  WILSON DAVID P ,  ROBINSON ROY P ,  VANDERPUY MICHAEL ,  WELCH JOHN L ,  SHAFER GREGORY J ,  SPATZ MARK W ,  HULSE RYAN

IPC: C10M105/32 ,  C10M111/02 ,  C10M171/00

CPC classification number: C09K5/045 ,  C09K2205/122 ,  C10N2240/30

Abstract: The invention pertains to heat transfer compositions, particularly to automobile refrigerants comprising a hydrofluoroalkene, an iodocarbon, and at least one lubricant having hydrogen atoms and carbon atoms, wherein no more than 17% of the total number of hydrogen atoms which are attached to a carbon atom are tertiary hydrogen atoms.

Abstract translation: 本发明涉及传热组合物，特别涉及包含氢氟烯烃，碘代烃和至少一种具有氢原子和碳原子的润滑剂的汽车制冷剂，其中不超过连接到碳上的氢原子总数的17％ 原子是叔氢原子。

公开(公告)号：WO2009025921A2

公开(公告)日：2009-02-26

申请号：PCT/US2008065926

申请日：2008-06-05

Applicant: HONEYWELL INT INC ,  SINGH RAJIV R ,  SHANKLAND IAN ,  SZUCH COLLEEN D

Inventor： SINGH RAJIV R ,  SHANKLAND IAN ,  SZUCH COLLEEN D

IPC: B09B3/00 ,  C09K3/32

CPC classification number: B09B3/0025 ,  B01J19/002 ,  B01J2219/00261 ,  B01J2219/00263 ,  C09K3/32

Abstract: A method for restraining a chemical discharge comprising (a) deploying a binding agent into a receptacle containing a hazardous material in a liquid state upon the occurrence of at least one predetermined event that increases the risk of accidentally discharging or leaking the hazardous material from the receptacle; and (b) contacting the hazardous material with the binding agent to form a composition comprising at least a portion of the hazardous material and the binding agent and having at least one property selected from a solid or semisolid state, a viscosity greater than the hazardous material's viscosity at ambient conditions, a vapor pressure lower than the hazardous material's vapor pressure at ambient conditions, and a surface tension greater that the hazardous material's surface tension.

Abstract translation: 一种用于抑制化学放电的方法，包括（a）在发生至少一个预定事件的情况下将粘合剂部署到容纳液态的有害物质的容器中，这增加了从容器意外地排出或泄漏危险材料的风险 ; 和（b）将危险材料与粘合剂接触以形成包含至少一部分危险材料和粘合剂的组合物，并且具有选自固体或半固体状态的至少一种性质，大于危险物质的粘度 在环境条件下的粘度，低于危险物质在环境条件下的蒸气压的蒸气压，以及表面张力大于危险材料的表面张力。

公开(公告)号：WO2009011987A2

公开(公告)日：2009-01-22

申请号：PCT/US2008065918

申请日：2008-06-05

Applicant: HONEYWELL INT INC ,  SINGH RAJIV R ,  SHANKLAND IAN

Inventor： SINGH RAJIV R ,  SHANKLAND IAN

IPC: C09K3/32 ,  B09B3/00

CPC classification number: B01J19/06 ,  B01J19/00 ,  B01J20/26 ,  B01J20/261 ,  B01J20/264 ,  B01J20/267 ,  B01J2220/445 ,  C09K3/32

Abstract: Disclosed are methods for treating hazardous materials, such as those which result from an unwanted spill or leak, which comprise one or more of the steps or effects of: neutralizing the dispersed material; solidifying the dispersed material; immobilizing the material; and/or reducing the evolution of harmful or unwanted gaseous forms from the spillage, preferably using a binding agent which comprises a polyacrylate-polyacrylamide cross-linked copolymer.

Abstract translation: 公开了用于处理危险材料的方法，例如由不希望的溢出或泄漏引起的那些危险材料，其包括以下一个或多个步骤或效果：中和分散的材料; 固化分散的材料; 固定材料; 和/或减少有害或不需要的气体形式从溢出物中的逸出，优选使用包含聚丙烯酸酯 - 聚丙烯酰胺交联共聚物的粘合剂。