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公开(公告)号:US12139647B2
公开(公告)日:2024-11-12
申请号:US17999005
申请日:2021-04-23
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Tuoqi Li , Joseph J. Zupancic , Yinzhong Guo , Jie Wu
IPC: C09J167/00 , C08G18/58 , C08K3/32
Abstract: Provided is a composition comprising one or more epoxy phosphate esters wherein the structure comprises two or more polyester linkages. Also provided is a method of making the epoxy phosphate esters that comprises reacting one or more epoxy-terminated polyesters with one or more phosphoric acids. Further provided is an adhesive composition that comprises one or more epoxy phosphate esters, one or more multifunctional isocyanate prepolymers, and one or more multifunctional isocyanate-reactive compounds.
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公开(公告)号:US20240001656A1
公开(公告)日:2024-01-04
申请号:US18254156
申请日:2021-11-09
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: James A. Walker , Lawrence J. Effler, JR. , Sudhanwa D. Dewasthale , Amira A. Marine , Manesh Nadupparambil Sekharan , Jill M. Martin , Mai Chen , Yinzhong Guo , Christopher I. Gandy
CPC classification number: B32B27/08 , B32B7/12 , B32B27/14 , B32B27/26 , B32B2323/04 , B32B2250/03 , B32B2307/00
Abstract: An article having recyclability properties including a combination of: (a) at least one polyolefin polymer; and (b) a waterborne adhesive composition having a recyclability property, wherein the recyclability property of the waterborne adhesive composition is such that when the article with the waterborne adhesive composition is reprocessed, the article with the waterborne adhesive composition exhibits less than a 40% decreased change in performance compared to a control article without the waterborne adhesive composition that is reprocessed the same way as the article with the waterborne adhesive composition; a recyclable laminate structure including (a) at least one first polymer film layer; and (β) at least one layer of the above waterborne laminating adhesive composition; and a process for manufacturing the above recyclable laminate structure.
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公开(公告)号:US11746266B2
公开(公告)日:2023-09-05
申请号:US17068348
申请日:2020-10-12
Inventor: Yinzhong Guo , Juan Carlos Casarrubias , Kevin K. Miyake , Mateus Batista Torres Cipro , Elkin David Cardona Jimenez
IPC: C09J175/08 , B32B7/12 , B32B15/085 , B32B15/20 , B32B37/12 , C09J175/06 , C08G18/38 , C08G18/42 , C08G18/36 , C09J175/04 , C08G18/48 , C08G18/76 , C08G18/50 , C08G18/79 , C08G18/80 , C08L75/04 , C08G18/40 , B65D81/34
CPC classification number: C09J175/08 , B32B7/12 , B32B15/085 , B32B15/20 , B32B37/12 , B65D81/34 , C08G18/36 , C08G18/3885 , C08G18/4018 , C08G18/4202 , C08G18/4211 , C08G18/4216 , C08G18/4219 , C08G18/4238 , C08G18/4829 , C08G18/5045 , C08G18/5075 , C08G18/7671 , C08G18/797 , C08G18/8025 , C08L75/04 , C09J175/04 , C09J175/06 , B32B2037/1269 , C08G18/4208 , C08G2170/00 , C08G2190/00
Abstract: A two-component solventless polyurethane adhesive composition including (A) at least one isocyanate component and (B) at least one polyol component. The isocyanate component (A) comprises an isocyanate prepolymer that is the reaction product of (Ai) a polyisocyanate and (Aii) an isocyanate-reactive component; wherein the isocyanate-reactive component comprises (Aiia) at least one polyol having a functionality greater than two, (Aiib) at least one aromatic polyester polyol having a functionality of greater than two, and (Aiic) at least one hydrophobic polyol. The polyol component (B) comprises (Bi) at least one polyether polyol having a functionality greater than two, (Bii) at least one aromatic polyester polyol transesterified with a natural oil, and (Biii) at least one phosphate ester polyol. A method for forming a laminate is also disclosed, the method comprising the steps of: (I) mixing the above reactants (components (A) and (B)) to form a solventless adhesive composition, (II) applying a layer of the solventless adhesive composition to a surface of a first substrate, (III) bringing the layer of the solventless adhesive composition on the first substrate into contact with a surface of a second substrate to form a laminate, and (IV) curing the solventless adhesive composition. A laminate comprising the above solventless adhesive composition is also disclosed.
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公开(公告)号:US11584829B2
公开(公告)日:2023-02-21
申请号:US16754435
申请日:2018-08-23
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Carlos A. Escobar Marin , Amit K. Chaudhary , Yinzhong Guo , James M. Lipovsky , Ludwik S. Cygan , Liang Chen
IPC: C08J3/00 , C08K3/22 , C08K5/09 , C09D123/08 , C09D191/06 , C09D193/04 , B01F27/27
Abstract: Methods for preparing waterborne heat seal coating compositions are disclosed, including (A) melt blending an ethylene vinyl acetate copolymer, a tackifier, and a wax in a first mixing apparatus to form a melt blend, (B) contacting the melt blend with an initial aqueous stream comprising a neutralizing agent, water, and a surfactant in an emulsification zone of the second mixing apparatus to form a dispersion, and (C) diluting the dispersion with water in a dilution zone of the second mixing apparatus to form the waterborne heat seal coating composition. Methods for preparing waterborne heat seal coating compositions are also disclosed, including (A) melt blending an ethylene vinyl acetate copolymer, a tackifier, and a wax in a mixing and conveying zone of a mixing apparatus to form a melt blend, (B) contacting the melt blend with an initial aqueous stream comprising a neutralizing agent, water, and a surfactant in an emulsification zone of the mixing apparatus to form a dispersion, and (C) diluting the dispersion with water in a dilution zone of the mixing apparatus to form the waterborne heat seal coating composition, wherein the length-to-diameter ratio of the extruder mixing apparatus is greater than or equal to 12 to 1. Waterborne heat seal coating compositions prepared according to the disclosed methods are also disclosed.
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公开(公告)号:US20220017677A1
公开(公告)日:2022-01-20
申请号:US17294127
申请日:2019-11-13
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Yinzhong Guo , Mai Chen
Abstract: The present disclosure provides a process comprising providing an isocyanate component A comprising a blend of (i) an aromatic isocyanate prepolymer and (ii) an aliphatic isocyanate prepolymer; providing a polyol component B comprising a blend of; (i) a phosphate-functional polyol, (ii) a polyether polyol, and (iii) an element selected from the group consisting of a polyurethane polyol, a polyester polyol and a combination thereof; mixing component A and component B to form a solventless adhesive (SLA) composition, wherein a weight ratio of component A to component B is from 2:1 to 1:1, the SLA composition having a pot life from 30 min to 60 min at 40 C; applying the SLA composition between a first film and a second film to form a raw laminate; and curing the raw laminate to form a laminate product.
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公开(公告)号:US20150329739A1
公开(公告)日:2015-11-19
申请号:US14651061
申请日:2013-12-05
Applicant: BLUE CUBE IP LLC , ROHM AND HAAS COMPANY
Inventor: Christian Piechocki , Ray E. Drumright , Sandrine Sinsoulieu , Erin B. Vogel , Yinzhong Guo
IPC: C09D163/00
CPC classification number: C09D163/00 , C08G59/226 , C08G59/24
Abstract: A coating composition including a blend of at least two or more epoxy resins, wherein at least one of the epoxy resins comprises (i) a CHDM epoxy resin having less than about 2 wt % total chlorine content; and wherein at least one of the epoxy resins comprises (ii) at least one other epoxy resin other than the epoxy resin in component (i); a curable coating composition including (a) the above blend of epoxy resins and (b) at least one amine curing agent; a thermoset coating product prepared from the above cur able composition; and a process for preparing the above compositions and a coating therefrom.
Abstract translation: 一种包含至少两种或多种环氧树脂的共混物的涂料组合物,其中至少一种环氧树脂包括(i)总氯含量小于约2重量%的CHDM环氧树脂; 并且其中所述环氧树脂中的至少一种包含(ii)除了组分(i)中的环氧树脂之外的至少一种其它环氧树脂; 一种可固化涂料组合物,其包含(a)上述环氧树脂的混合物和(b)至少一种胺固化剂; 由上述弯曲组合物制备的热固性涂料产品; 以及制备上述组合物及其涂层的方法。
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公开(公告)号:US20240199928A1
公开(公告)日:2024-06-20
申请号:US18286917
申请日:2022-04-21
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Yinzhong Guo , Daniele Vinci , Thorsten Schmidt , Franca Arrighi
IPC: C09J175/06 , C08G18/10 , C08G18/50
CPC classification number: C09J175/06 , C08G18/10 , C08G18/5021 , C08G18/5084 , C09J2475/00
Abstract: Provided is a 2-pack adhesive composition comprising I) pack I, which comprises a prepolymer composition (PCB), wherein the prepolymer composition (PCB) comprises one or more isocyanate functional prepolymers (FPA), wherein the isocyanate functional prepolymer (FPA) comprises polymerized units of 4,4′ MDI, and wherein the prepolymer composition (PCB) comprises a total amount of all isocyanate monomers of 0 to 0.2% by weight based on the weight of prepolymer composition (PCB). and II) CA pack II, which comprises one or more amine functional polyols. Also provided is a method of making a laminate using such a 2-pack adhesive composition.
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公开(公告)号:US12006451B2
公开(公告)日:2024-06-11
申请号:US17414584
申请日:2018-12-21
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Rui Shi , Zhaohui Qu , Yinzhong Guo
IPC: B32B41/00 , C08G18/12 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/76 , C09J175/06 , C09J175/08
CPC classification number: C09J175/06 , C08G18/12 , C08G18/4018 , C08G18/4238 , C08G18/4825 , C08G18/4829 , C08G18/7671 , C09J175/08 , C09J2301/12 , C09J2301/30 , C09J2400/163 , C09J2423/046 , C09J2475/00
Abstract: The present disclosure provides a two-component solvent-less adhesive composition. The two-component solvent-less adhesive composition contains the reaction product of (A) an isocyanate component containing the reaction product of (i) an isocyanate monomer and (ii) a first dimer acid polyester polyol; and (B) a polyol component containing (i) a second dimer acid polyester polyol and (ii) optionally, a polyol selected from a polyether polyol, a polyester polyol, and combinations thereof. The two-component solvent-less adhesive composition contains from 15 wt % to 45 wt % units derived from dimer acid, based on the total weight of the two-component solvent-less adhesive composition.
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公开(公告)号:US20240317953A1
公开(公告)日:2024-09-26
申请号:US18275157
申请日:2021-12-09
Applicant: DOW GLOBAL TECHNOLOGIES LLC , ROHM AND HAAS COMPANY
Inventor: Yinzhong Guo , Zhenwan Fu , Jie Wu
CPC classification number: C08J7/0427 , B65D65/42 , C08J7/046 , C08J7/052 , C08J11/06 , C09D5/022 , C09D7/43 , C09D175/00 , B65D2565/385 , C08J2323/06 , C08J2475/00
Abstract: A glossy coated film having recyclability properties comprising a combination of: (a) at least one film layer of a recyclable polyolefin; and (b) at least one coating layer: wherein the at least one coating layer comprises a waterborne coating composition and a water-dispersible polyisocyanate; and wherein the coating layer has a recyclability property; and wherein the at least one coating layer is disposed on at least a portion of the surface of one side of the at least one film layer of the recyclable polyolefin.
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公开(公告)号:US20240001657A1
公开(公告)日:2024-01-04
申请号:US18254161
申请日:2021-11-09
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: James A. Walker , Lawrence J. Effler, JR. , Sudhanwa D. Dewasthale , Amira A. Marine , Manesh Nadupparambil Sekharan , Jill M. Martin , Mai Chen , Yinzhong Guo , Christopher I. Gandy
CPC classification number: B32B27/08 , B32B7/12 , B32B37/12 , B65D65/40 , B32B27/18 , B32B27/32 , B32B2323/00 , B32B2439/00 , B32B2272/00 , B32B2270/00 , B32B2250/242 , B32B2307/414 , B32B2307/558 , B32B2307/5825 , B32B2307/54 , B32B2250/05
Abstract: An article having recyclability properties including a combination of: (a) a polyolefin polymer; and (b) a solvent-borne adhesive composition having a recyclability property, wherein the recyclability property of the solvent-borne adhesive composition is such that when the article with the solvent-borne adhesive composition is reprocessed, the article with the solvent-borne adhesive composition exhibits less than a 40% decreased change in performance compared to a control article without the solvent-borne adhesive composition that is reprocessed the same way as the article with the solvent-borne adhesive composition; a recyclable laminate structure including at least: (a) at least a first polymer film layer; and (b) a layer of the above solvent-borne laminating adhesive composition; and a process for manufacturing the above recyclable laminate structure.
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