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1.发明申请ALDEHYDE ADSORBENT, METHOD FOR REMOVING ALDEHYDE, METHOD FOR PRODUCING ACETIC ACID, AND METHOD FOR REGENERATING ALDEHYDE ADSORBENT 有权醛类吸附剂，去除醛类的方法，用于生产乙酸的方法和用于再生阿尔德德吸附剂的方法公开(公告)号：US20160121320A1
公开(公告)日：2016-05-05
申请号：US14897125
申请日：2014-06-03
Applicant: CHIYODA CORPORATION
Inventor： Zhixiong You , Yoichi Umehara , Tetsuro Matsumura , Takeshi Minami
CPC classification number: B01J39/20 , B01J39/05 , B01J39/19 , B01J49/06 , B01J49/53 , C07C45/79 , C07C51/12 , C07C51/44 , C07C51/47 , C07C53/08
Abstract: An aldehyde adsorbent that can adsorb and remove aldehyde from a carboxylic acid-containing liquid is provided. The aldehyde adsorbent is an aldehyde adsorbent for adsorbing aldehyde in a carboxylic acid-containing liquid containing aldehyde, including a cation exchange resin ion-exchanged with a polyvalent amine in 1 to 99% by mol of the total exchange capacity.
Abstract translation: 提供了可以从含羧酸的液体中吸附和除去醛的醛吸附剂。 醛吸附剂是用于在含醛的含羧酸的液体中吸附醛的醛吸附剂，其包含与多价胺离子交换的阳离子交换树脂，其总交换容量为1至99摩尔％。
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公开(公告)号：US20140316071A1
公开(公告)日：2014-10-23
申请号：US14323437
申请日：2014-07-03
Applicant: CHIYODA CORPORATION
Inventor： Zhixiong You , Takeshi Minami , Chunji Yin , Yoichi Umehara , Tetsuro Matsumura , Chikako Hashimoto , Yasuo Hosono
IPC: C08F226/06 , C08F212/36
CPC classification number: C08F226/06 , C07C51/12 , C08F212/36 , C07C53/08
Abstract: According to a method for producing acetic acid by carbonylation of methanol characterized in that an acid having an acid dissociation constant (pKa) smaller than the constant of acetic acid is allowed to be present in the reaction system, acetic acid can be produced by the reaction of methanol and carbon monoxide in a reaction liquid in the presence of a solid catalyst containing rhodium and alkyl iodide, to achieve an enhanced reaction rate of carbonylation of methanol in producing acetic acid in the region at a high carbonylation degree (Ca>0.8 mol/mol) for more efficient production of acetic acid.
Abstract translation: 根据通过羰基化甲醇生产乙酸的方法，其特征在于在反应体系中存在酸解离常数（pKa）小于乙酸常数的酸，可以通过反应生成乙酸 的甲醇和一氧化碳在含有铑和烷基碘的固体催化剂存在下的反应液中，以在羰基化程度高（Ca> 0.8mol / L）的区域中提高甲醇生产乙酸的羰基化反应速率， mol）以更有效地生产乙酸。
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公开(公告)号：US09638684B2
公开(公告)日：2017-05-02
申请号：US14547989
申请日：2014-11-19
Applicant: CHIYODA CORPORATION
Inventor： Zhixiong You , Ryuichi Kanai , Yoichi Umehara , Takeshi Minami
CPC classification number: G01N33/442 , B01J23/464 , G01N5/04 , G01N17/00 , G01N25/12
Abstract: Provided is a method of evaluating a resin capable of quantitatively evaluating a deterioration degree of the resin with high accuracy and ease. The method includes evaluating the resin based on a shift of a characteristic peak representing a deterioration degree of the resin, the peak being observed in thermal analysis of the resin by a temperature increase, to lower temperatures.
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公开(公告)号：US09440902B2
公开(公告)日：2016-09-13
申请号：US14896286
申请日：2014-06-03
Applicant: CHIYODA CORPORATION
Inventor： Zhixiong You , Yoichi Umehara , Tetsuro Matsumura , Takeshi Minami
CPC classification number: C07C51/12 , B01J31/06 , B01J31/181 , B01J2231/321 , B01J2531/821 , B01J2531/822 , C07C53/08
Abstract: To provide a production method for suppressing the reduction in production rate of a carbonyl compound due to transferring a noble metal component into liquid phase. A method for producing a carbonyl compound, including: a reaction step of reacting a carbonylation raw material with CO in liquid phase including a solid catalyst having noble metal complex on a resin carrier containing quaternized nitrogen to produce a carbonyl compound; a distillation step of distilling a reaction product liquid to recover gas phase distillate including the carbonyl compound; and a circulation step of circulating a bottom product from the distillation to reaction step. After part of the bottom product contacts with an acidic cation-exchange resin to remove nitrogen compound, liquid having higher moisture concentration than the bottom product contacts with the resin to extract noble metal complex captured by oligomer adsorbing the resin, and the complex is returned to the reaction step.
Abstract translation: 提供一种制备方法，用于抑制由于将贵金属组分转移到液相中羰基化合物的生产速率的降低。 一种制备羰基化合物的方法，包括：使羰基化原料与液相中的CO反应的反应步骤，所述液相包含含有贵金属配合物的固体催化剂，在含有季铵化氮的树脂载体上，以产生羰基化合物; 蒸馏步骤，蒸馏反应产物液体以回收包括羰基化合物的气相馏出物; 以及将塔底产物从蒸馏循环到反应步骤的循环步骤。 在部分底部产物与酸性阳离子交换树脂接触以除去氮化合物后，具有比底部产物更高水分浓度的液体与树脂接触以提取由低聚物吸附树脂捕获的贵金属络合物，并将复合物返回至 反应步骤。
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公开(公告)号：US11065607B2
公开(公告)日：2021-07-20
申请号：US16084023
申请日：2017-03-07
Applicant: CHIYODA CORPORATION
Inventor： Chikako Hashimoto , Ryuichi Kanai , Zhixiong You , Tetsuro Matsumura , Yoichi Umehara
Abstract: A vinylpyridine resin for a catalyst support; a method for producing thereof; and a catalyst for carbonylation of methanol are disclosed. The vinylpyridine resin has: content of nitrogen derived from a pyridine group of 3.00% by mass or more and 8.00% by mass or less; degree of crosslinking of 35% by mole or more and 70% by mole or less; molar ratio C/N of carbon atoms to nitrogen atoms of 12.00 or more and 36.00 or less; total pore volume of 0.20 cc/g or more and 0.45 cc/g or less; specific surface area of 70.0 m2/g or more and 280 m2/g or less; average pore diameter of 5.0 nm or more and 25.0 nm or less; and proportion of a volume of pores having a pore diameter of 10 nm or more to a volume of the whole pores of 4.0% or more and 90.0% or less.
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Patent Agency Ranking
6.发明申请公开(公告)号：US20200290028A1
公开(公告)日：2020-09-17
申请号：US16084023
申请日：2017-03-07
Applicant: CHIYODA CORPORATION
Inventor： Chikako Hashimoto , Ryuichi Kanai , Zhixiong You , Tetsuro Matsumura , Yoichi Umehara
Abstract: A vinylpyridine resin for a catalyst support; a method for producing thereof; and a catalyst for carbonylation of methanol are disclosed. The vinylpyridine resin has: content of nitrogen derived from a pyridine group of 3.00% by mass or more and 8.00% by mass or less; degree of crosslinking of 35% by mole or more and 70% by mole or less; molar ratio C/N of carbon atoms to nitrogen atoms of 12.00 or more and 36.00 or less; total pore volume of 0.20 cc/g or more and 0.45 cc/g or less; specific surface area of 70.0 m2/g or more and 280 m2/g or less; average pore diameter of 5.0 nm or more and 25.0 nm or less; and proportion of a volume of pores having a pore diameter of 10 nm or more to a volume of the whole pores of 4.0% or more and 90.0% or less.
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公开(公告)号：US20160130207A1
公开(公告)日：2016-05-12
申请号：US14896286
申请日：2014-06-03
Applicant: CHIYODA CORPORATION
Inventor： Zhixiong You , Yoichi Umehara , Tetsuro Matsumura , Takeshi Minami
CPC classification number: C07C51/12 , B01J31/06 , B01J31/181 , B01J2231/321 , B01J2531/821 , B01J2531/822 , C07C53/08
Abstract: To provide a production method for suppressing the reduction in production rate of a carbonyl compound due to transferring a noble metal component into liquid phase. A method for producing a carbonyl compound, including: a reaction step of reacting a carbonylation raw material with CO in liquid phase including a solid catalyst having noble metal complex on a resin carrier containing quaternized nitrogen to produce a carbonyl compound; a distillation step of distilling a reaction product liquid to recover gas phase distillate including the carbonyl compound; and a circulation step of circulating a bottom product from the distillation to reaction step. After part of the bottom product contacts with an acidic cation-exchange resin to remove nitrogen compound, liquid having higher moisture concentration than the bottom product contacts with the resin to extract noble metal complex captured by oligomer adsorbing the resin, and the complex is returned to the reaction step.
Abstract translation: 提供一种制备方法，用于抑制由于将贵金属组分转移到液相中羰基化合物的生产速率的降低。 一种制备羰基化合物的方法，包括：使羰基化原料与液相中的CO反应的反应步骤，所述液相包含含有贵金属配合物的固体催化剂，在含有季铵化氮的树脂载体上，以产生羰基化合物; 蒸馏步骤，蒸馏反应产物液体以回收包括羰基化合物的气相馏出物; 以及将塔底产物从蒸馏循环到反应步骤的循环步骤。 在部分底部产物与酸性阳离子交换树脂接触以除去氮化合物后，具有比底部产物更高的水分浓度的液体与树脂接触以提取由低聚物吸附树脂捕获的贵金属络合物，并将复合物返回至 反应步骤。
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公开(公告)号：US20150147816A1
公开(公告)日：2015-05-28
申请号：US14547989
申请日：2014-11-19
Applicant: CHIYODA CORPORATION
Inventor： Zhixiong You , Ryuichi Kanai , Yoichi Umehara , Takeshi Minami
CPC classification number: G01N33/442 , B01J23/464 , G01N5/04 , G01N17/00 , G01N25/12
Abstract: Provided is a method of evaluating a resin capable of quantitatively evaluating a deterioration degree of the resin with high accuracy and ease. The method includes evaluating the resin based on a shift of a characteristic peak representing a deterioration degree of the resin, the peak being observed in thermal analysis of the resin by a temperature increase, to lower temperatures.
Abstract translation: 提供一种能够以高精度和容易的方式定量评价树脂的劣化程度的树脂的评价方法。 该方法包括基于表示树脂的劣化程度的特征峰的偏移，将树脂的热分析中观察到的峰值升高到更低的温度来评估树脂。
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公开(公告)号：US09662646B2
公开(公告)日：2017-05-30
申请号：US14897125
申请日：2014-06-03
Applicant: CHIYODA CORPORATION
Inventor： Zhixiong You , Yoichi Umehara , Tetsuro Matsumura , Takeshi Minami
IPC: B01J39/20 , C07C51/44 , C07C51/47 , C07C45/79 , C07C51/12 , B01J39/05 , B01J39/19 , B01J49/06 , B01J49/53
CPC classification number: B01J39/20 , B01J39/05 , B01J39/19 , B01J49/06 , B01J49/53 , C07C45/79 , C07C51/12 , C07C51/44 , C07C51/47 , C07C53/08
Abstract: An aldehyde adsorbent that can adsorb and remove aldehyde from a carboxylic acid-containing liquid is provided. The aldehyde adsorbent is an aldehyde adsorbent for adsorbing aldehyde in a carboxylic acid-containing liquid containing aldehyde, including a cation exchange resin ion-exchanged with a polyvalent amine in 1 to 99% by mol of the total exchange capacity.
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10.发明申请公开(公告)号：US20160257578A1
公开(公告)日：2016-09-08
申请号：US15024585
申请日：2014-07-15
Applicant: CHIYODA CORPORATION
Inventor： Zhixiong You , Yoichi Umehara , Masayo Shinohara , Kazushige Kawamura , Takeshi Minami
CPC classification number: C02F1/285 , B01D17/0202 , B01J20/261 , B01J20/264 , B01J20/267 , B01J20/3285 , B01J20/3425 , C02F2101/32 , C02F2101/322 , C02F2101/345 , C02F2103/10 , C02F2103/36 , C02F2103/365 , C02F2303/16
Abstract: Disclosed herein is a water treatment process for efficiently removing oils from oil-containing water.The water treatment process is a method for treating oil-containing water, comprising the steps of: preparing an oil-adsorbing material that is made of a lipophilic resin such as a pyridine resin and that has many pores in its surface and bears hydrophilic groups on an inner surface of the pores; and bringing oil-containing water into contact with the surface of the oil-adsorbing material. The step of preparing an oil-adsorbing material includes the step of converting some of hydrophobic groups, such as nitrogen-containing aromatic rings, on the inner surface of the pores to hydrophilic groups such as quaternized amine or sulfonic acid.
Abstract translation: 本文公开了一种用于从含油水中有效地除去油的水处理方法。 水处理方法是一种处理含油水的方法，其特征在于，包括以下步骤：制备由亲水性树脂如吡啶树脂制成的油吸附材料，并且在其表面具有许多孔并且具有亲水基团 孔的内表面; 并使含油水与吸油材料的表面接触。 制备油吸附材料的步骤包括将孔内表面上的一些疏水基团如含氮芳环转化为亲水基团如季胺或磺酸的步骤。
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