公开(公告)号：US20170114169A1

公开(公告)日：2017-04-27

申请号：US15397805

申请日：2017-01-04

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Jeff F. Greco ,  Max P. McDaniel ,  Youlu Yu ,  Gary L. Glass ,  Tony R. Crain

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/02 ,  C08F110/02 ,  C08F210/08 ,  C08F210/14 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04

Abstract: Disclosed herein are ethylene-based polymers having a melt index less than 50 g/10 min, a ratio of Mw/Mn from 4 to 20, a density from 0.90 to 0.945 g/cm3, and a substantially constant short chain branch distribution. These polymers can be produced using a dual catalyst system containing a boron bridged metallocene compound with a cyclopentadienyl group and an indenyl group, and a single atom bridged metallocene compound with a fluorenyl group.

公开(公告)号：US20170088639A1

公开(公告)日：2017-03-30

申请号：US14863575

申请日：2015-09-24

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Qing Yang ,  Lloyd W. Guatney ,  Jeffrey F. Greco

IPC: C08F4/6592 ,  C08F4/645

CPC classification number: C08F4/65925 ,  C08F4/6457 ,  C08F210/16 ,  C08F2410/04 ,  C08F4/6543 ,  C08F4/025 ,  C08F4/685 ,  C08F4/6343 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/01 ,  C08F2500/12 ,  C08F2500/17 ,  C08F110/02 ,  C08F4/65904

Abstract: Catalyst systems containing a Ziegler-Natta catalyst component are disclosed. Such catalyst systems can contain a co-catalyst and a supported catalyst containing a fluorided silica-coated alumina, a magnesium compound, and vanadium and/or tetravalent titanium.

公开(公告)号：US09605100B2

公开(公告)日：2017-03-28

申请号：US15193195

申请日：2016-06-27

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Errun Ding ,  Paul DesLauriers ,  Yongwoo Inn ,  Lili Cui ,  Qing Yang ,  Ashish M. Sukhadia ,  Guylaine St. Jean ,  Richard M. Buck

IPC: C08F4/653 ,  C08F4/6592 ,  C08F210/16 ,  C08L23/08 ,  C08F4/659 ,  C08F4/69 ,  C08F210/02 ,  C08J5/00

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65922 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/69 ,  C08F210/02 ,  C08J5/00 ,  C08J2323/08 ,  C08L23/0815 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/12

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can employ a catalyst system containing two or three metallocene components, resulting in ethylene-based copolymers that can have a medium density and improved stress crack resistance.

公开(公告)号：US20170029541A1

公开(公告)日：2017-02-02

申请号：US15290010

申请日：2016-10-11

Applicant: Chevron Phillips Chemical Company LP

Inventor： Ted H. Cymbaluk ,  Max P. McDaniel ,  Qing Yang ,  Dennis L. Holtermann

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C08F4/52 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F2500/12 ,  C08F4/6592 ,  C08F210/14

Abstract: Methods for preparing single and dual metallocene catalyst systems containing an activator-support are disclosed. These methods can include precontacting of the activator-support and an organoaluminum compound, as well as sequential contacting of two different metallocene compounds to form a dual metallocene catalyst system.

Abstract translation: 公开了制备含有活化剂 - 载体的单茂金属催化剂体系和双茂金属催化剂体系的方法。 这些方法可以包括活化剂 - 载体和有机铝化合物的预接触，以及两种不同茂金属化合物的顺序接触以形成双茂金属催化剂体系。

公开(公告)号：US09550849B2

公开(公告)日：2017-01-24

申请号：US14995268

申请日：2016-01-14

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Qing Yang ,  Yongwoo Inn ,  William M. Whitte ,  John R. Rathman ,  Steven J. Secora ,  Daniel G. Hert

IPC: C08L23/08 ,  C08F4/653 ,  C08F4/6592 ,  C08F210/16 ,  C08F4/659

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65916 ,  C08L23/0815 ,  C08F210/14 ,  C08F2500/07 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/05 ,  C08F4/65927 ,  C08F4/65925

Abstract: Disclosed herein are ethylene-based polymers having a density greater than 0.945 g/cm3, a high load melt index less than 25 g/10 min, a peak molecular weight ranging from 52,000 to 132,000 g/mol, and an environmental stress crack resistance of at least 250 hours. These polymers have the processability of chromium-based resins, but with improved impact strength and stress crack resistance, and can be used in large-part blow molding applications.

Abstract translation: 本文公开了具有密度大于0.945g / cm 3，高负荷熔融指数小于25g / 10min，峰值分子量为52,000至132,000g / mol的乙烯基聚合物和环境应力开裂抗性 至少250小时。 这些聚合物具有铬基树脂的加工性，但具有改善的冲击强度和抗应力开裂性，并且可用于大部分吹塑应用。

公开(公告)号：US20170002122A1

公开(公告)日：2017-01-05

申请号：US15268668

申请日：2016-09-19

Applicant: Chevron Phillips Chemical Company LP

Inventor： Kensha Marie Clark ,  Qing Yang ,  Gary L. Glass

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C08F4/649 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F110/02 ,  C08F4/65925 ,  C08F4/65927

Abstract: Methods for preparing metallocene-based catalyst systems containing an activator-support are disclosed. These methods are directed to contacting an activator-support, an organoaluminum compound, and a mixture containing a metallocene compound and cyclohexene or a mixture of cyclohexane and 1-hexene, resulting in catalyst systems with increased catalytic activity for the polymerization of olefins.

Abstract translation: 公开了制备含有活化剂 - 载体的茂金属系催化剂体系的方法。 这些方法涉及使活化剂 - 载体，有机铝化合物和含有茂金属化合物和环己烯或环己烷和1-己烯的混合物的混合物接触，导致催化剂体系具有增加的烯烃聚合催化活性。

公开(公告)号：US20160325252A1

公开(公告)日：2016-11-10

申请号：US15216742

申请日：2016-07-22

Applicant: Chevron Phillips Chemical Company LP

Inventor： Elizabeth A. Benham ,  Albert P. Masino ,  Qing Yang ,  Randy S. Muninger ,  Rebecca A. Gonzales

IPC: B01J4/02 ,  C08F110/02 ,  B01J19/12 ,  B01J14/00 ,  B01J19/06

CPC classification number: B01J4/02 ,  B01J4/008 ,  B01J14/00 ,  B01J19/06 ,  B01J19/123 ,  B01J19/127 ,  B01J19/1837 ,  B01J2204/002 ,  B01J2219/00094 ,  B01J2219/00164 ,  B01J2219/00182 ,  B01J2219/00186 ,  B01J2219/0801 ,  C08F4/00 ,  C08F110/02 ,  C08F2420/00 ,  C08F2500/05 ,  C08F2500/07 ,  C08F2500/08 ,  C08F210/16 ,  C08F210/14 ,  C08F10/00 ,  C08F2/01

Abstract: Techniques are provided for catalyst preparation. A system for catalyst preparation may include an agitator disposed inside a polymerization catalyst tank and configured to mix a polymerization catalyst and a solvent to generate a polymerization catalyst solution. The system may also include a heating system coupled to the polymerization catalyst tank and configured to maintain a temperature of the polymerization catalyst solution above a threshold. The system may also include a precontactor configured to receive feed streams comprising an activator and the polymerization catalyst solution from the polymerization catalyst tank to generate a catalyst complex. The system may also include a transfer line configured to transfer the catalyst complex from an outlet of the precontactor to a reactor.

Abstract translation: 为催化剂制备提供了技术。 用于催化剂制备的系统可以包括设置在聚合催化剂罐内部并构造成混合聚合催化剂和溶剂以产生聚合催化剂溶液的搅拌器。 该系统还可以包括耦合到聚合催化剂罐并被配置为将聚合催化剂溶液的温度保持在阈值以上的加热系统。 该系统还可以包括预接触器，其构造成接收包含活化剂的进料流和来自聚合催化剂罐的聚合催化剂溶液以产生催化剂络合物。 该系统还可以包括配置成将催化剂配合物从预接触器的出口转移到反应器的输送管线。

公开(公告)号：US09334350B2

公开(公告)日：2016-05-10

申请号：US14639582

申请日：2015-03-05

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Ashish M. Sukhadia ,  Errun Ding ,  Chung Ching Tso ,  Albert P. Masino ,  Qing Yang ,  Lloyd W. Guatney ,  Guylaine St. Jean ,  Daniel G. Hert

IPC: C08F210/02 ,  C08F210/16 ,  C08F210/14 ,  C08J5/18 ,  C08L23/08

CPC classification number: C08F210/16 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/14 ,  C08F2410/02 ,  C08F2500/05 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/12 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2314/06 ,  C08F4/65904 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/26

Abstract: Disclosed herein are broad molecular weight distribution olefin polymers having densities in the 0.895 to 0.930 g/cm3 range, and with improved impact and tear resistance. These polymers can have a ratio of Mw/Mn in the 8 to 35 range, a high load melt index in the 4 to 50 range, less than about 0.008 LCB per 1000 total carbon atoms, and a reverse comonomer distribution.

公开(公告)号：US09303099B2

公开(公告)日：2016-04-05

申请号：US14602319

申请日：2015-01-22

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Max P. McDaniel ,  Tony R. Crain ,  Albert P. Masino ,  Ted H. Cymbaluk ,  John D. Stewart

IPC: C08F4/649 ,  C08F4/653 ,  C08F4/6592 ,  C08F210/16 ,  C08L23/08 ,  C08F4/76 ,  C08F4/659 ,  C08F210/14 ,  C08F2/01 ,  C08F4/52

CPC classification number: C08F4/76 ,  C08F2/01 ,  C08F4/52 ,  C08F4/649 ,  C08F4/65904 ,  C08F4/65916 ,  C08F210/14 ,  C08F210/16 ,  C08F2410/01 ,  C08L23/0815 ,  Y10S526/943 ,  C08F4/65925 ,  C08F4/65927 ,  C08F2/38 ,  C08F2500/04 ,  C08F2500/05 ,  C08F2500/12

Abstract: Methods for controlling properties of an olefin polymer using an alcohol compound are disclosed. The MI and the HLMI of the polymer can be decreased, and the Mw and the Mz of the polymer can be increased, via the addition of the alcohol compound.

Abstract translation: 公开了使用醇化合物控制烯烃聚合物性能的方法。 可以降低聚合物的MI和HLMI，并且可以通过加入醇化合物来增加聚合物的Mw和Mz。

公开(公告)号：US20160017069A1

公开(公告)日：2016-01-21

申请号：US14870361

申请日：2015-09-30

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Max P. McDaniel ,  Tony R. Crain ,  Youlu Yu ,  Yongwoo Inn

IPC: C08F110/02

CPC classification number: C08F110/02 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/00 ,  C08F210/16 ,  C08L23/00 ,  C08L23/0815 ,  C08L2314/06 ,  Y10S526/943 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/05 ,  C08F210/14 ,  C08L23/06

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes use a catalyst system containing three metallocene components, often resulting in polymers having a reverse comonomer distribution and a broad and non-bimodal molecular weight distribution.

Abstract translation: 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法使用含有三种茂金属组分的催化剂体系，其常常导致聚合物具有反向共聚单体分布和广泛的和非双峰分子量分布。