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    Alkanol amine salts of phosphates
    92.
    发明授权
    Alkanol amine salts of phosphates 失效
    磷酸盐碱性盐

    公开(公告)号：US3428713A

    公开(公告)日：1969-02-18

    申请号：US42532965

    申请日：1965-01-13

    Applicant: DU PONT

    Inventor： BARTLETT PHILIP LEE ,  BISWELL CHARLES BEDFORD

    IPC: C07F9/08 ,  C07F9/11 ,  C07F9/12 ,  C10L1/26

    CPC classification number: C10L1/2658 ,  C07F9/08 ,  C07F9/11 ,  C07F9/12 ,  C10L1/2641

    Abstract: 1,053,193. Alkanol amine salts of alkyl acid orthophosphate esters. E. I. DU PONT DE NEMOURS & CO. June 15, 1965 [June 15, 1964; Jan. 13, 1965], No. 25243/65. Heading C2C. [Also in Division C5] The invention comprises a salt of a primary mono- or di-alkyl orthophosphate ester in which each alkyl group contains from 8 to 16 carbon atoms and an alkanol amine having the formula wherein R and R 1 are hydrogen or alkyl, cycloalkyl, phenyl or alkyl phenyl groups, R and R 1 together containing a total of from 8 to 24 carbon atoms, R 11 is an alkyl, cycloalkyl, phenyl or aralkyl group containing 6 to 25 carbon atoms and R 111 is hydroxyethyl or a hydroxypropyl radical. The salt may be prepared by neutralizing the alkyl orthophosphate ester with the appropriate alkanol amine, the reactants normally being in equimolar proportions. The orphosphate esters may be obtained by reacting an alcohol (3 moles) with phosphorus pentoxide (1 mole) to give an approximately equimolar mixture of the corresponding mono- and di-alkyl esters of phosphoric acid. This mixture may be used as such to prepare a mixture of amine salts or the separate esters may be isolated from it and used to prepare individual amine salts. The alcohols used may be branched- or straight-chain primary alkanols having 8 to 16 carbon atoms or mixtures thereof. The branched-chain alkanols may be those prepared by the Oxo-process using a branchedchain olefin such as C 7 -C 15 mono-olefinic polymers and interpolymers of propylene and butylene, or they may be prepared by the aldolisation of appropriate aldehydes followed by hydrogenation or by the alkaline condensation of primary alcohols of the type RCH 2 CH 2 OH where R is an alkyl group of from 2 to 6 carbon atoms. The alkanol-amines of type A above may be obtained by the reaction of the appropriate amine RR 1 NH with 3-chloropropanediol-1,2 and those of type B may be prepared by reading the appropriate amine R 11 NH 2 with ethylene oxide or propylene oxide or, when R 111 is hydroxyethyl, by reacting the alkyl or aralkyl chloride R 11 Cl with diethanolamine. The amine phosphate salts are useful as anti-stalling additives for hydrocarbon distillate fuels (see Division C5).

    Hydrocarbon fuel composition
    93.
    发明授权
    Hydrocarbon fuel composition 失效
    烃燃料组成

    公开(公告)号：US3388978A

    公开(公告)日：1968-06-18

    申请号：US67048867

    申请日：1967-08-17

    Applicant: CITIES SERVICE OIL CO

    Inventor： KERSCHNER PAUL M ,  HESS FREDERICK G

    IPC: C07F9/09 ,  C10L1/14 ,  C10L1/26 ,  C10L1/30 ,  C10M137/04 ,  C10M137/08

    CPC classification number: C10M137/04 ,  C07F9/09 ,  C10L1/14 ,  C10L1/2641 ,  C10L1/2658 ,  C10L1/301 ,  C10M137/08 ,  C10M2203/108 ,  C10M2223/04 ,  C10M2223/041 ,  C10M2223/042 ,  C10M2223/043 ,  C10M2227/083 ,  C10N2210/02 ,  C10N2210/04 ,  C10N2210/06 ,  C10N2210/08 ,  C10N2250/121

    Abstract: 1,135,261. Metal organoorthophosphates; organometallic compounds. CITIES SERVICE OIL CO. 5 Jan., 1966, No. 542/66. Headings C2C and C2J. [Also in Division C5] Metal organo orthophosphates including compounds having metal-carbon bonds are prepared by contacting, in an inert organic solvent, (a) phosphorus pentoxide, and (b) a polyvalent metal halide, which may contain organic groups, with (c) an organic hydroxyl compound having from 1 to 30 carbon atoms at a temperature of between 10‹ and 120‹ C. The products suitably have one of the following general formulµ where M is a polyvalent metal suitably of Groups II, IV, VI and VIII, and R is a hydrocarbon group of 1 to 30 atoms. Products having a free hydroxy group may be neutralized with an amine. In the examples the following reactants and products are described: (1) P 2 O 5 , TiCl 4 and C 8 H 17 OH to give [(C 8 H 17 O) 2 OPO] 2 Ti[OPO(OH)(OC 8 H 17 )] 2 (2) P 2 O 5 , ZrC1 4 , C 8 H 17 OH and CH 3 OH to give [(C8H 17 O)(CH 3 O)OPO] 2 Zr[OPO(OH)(OC 8 H 17 )] 2 (3) P 2 O 5 , NiC1 2 and C 8 H 17 OH to give [(C 8 H 17 O) 2 OPO]Ni[OPO(OH)(OC 8 H 17 )] (4) P 2 O 5 , SnCl 4 , ocyl phenol and iso-butyl alcohol, to give [(RO) 2 OPO] 2 Sn[OPO(OR)(OH)] 2 where 2 of the Rs are isobutyl and 4 of the Rs are octyl-phenyl groups, (5) P 2 O 5 , [C 6 H 5 CH 2 ] 2 SnCl 2 and isopropyl alcohol to give (6) as in (1), but replacing 2-ethylhexanol (C 8 H 17 OH) with phenol, benzylalcohol or cyolohexanol. The orthophosphates are useful as additives in fuels and lubricants.

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