公开(公告)号：US20150070875A1

公开(公告)日：2015-03-12

申请号：US14368927

申请日：2013-05-30

Applicant: National Institute for Materials Science

Inventor： Naoto Hirosaki ,  Takashi Takeda ,  Shiro Funahashi

IPC: C09K11/77 ,  C30B29/34 ,  H01J19/57 ,  G02F1/1335 ,  H01J17/49 ,  C30B1/04 ,  F21K99/00

CPC classification number: C09K11/7792 ,  C09K11/7706 ,  C09K11/7721 ,  C09K11/7734 ,  C09K11/7749 ,  C09K11/7764 ,  C30B1/04 ,  C30B29/34 ,  F21K9/64 ,  G02F1/133603 ,  G02F2001/133614 ,  H01J11/42 ,  H01J17/49 ,  H01J19/57 ,  H01J29/20 ,  H01L33/502 ,  H01L33/504 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/8592 ,  H01L2924/12044 ,  H01L2924/181 ,  H01L2924/00014 ,  H01L2924/00 ,  H01L2924/00012

Abstract: A chemically and thermally stable phosphor having unconventional light emitting properties and high light emitting intensity with an LED of 470 nm or less, includes an inorganic compound comprising: a crystal designated by A3(D,E)8X14, a crystal designated by Sr3Si8O4N10 or an inorganic crystal having the identical crystal structure of the Sr3Si8O4N10 crystal, which comprises A element, D element, X element, and optionally E element if necessary (A is one or more kinds selected from Li, Mg, Ca, Sr, and Ba; D is one or more kinds selected from Si, Ge, Sn, Ti, Zr, and Hf; X is one or more kinds selected from O, N, and F; and E is one or more kinds selected from B, Al, Ga, In, Sc, Y, and La.), into which M element is solid-solved (M is one or more kinds selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb.).

Abstract translation: 具有470nm或更小的LED的非常规发光特性和高发光强度的化学和热稳定的荧光体包括无机化合物，其包含：由A3（D，E）8X14表示的晶体，由Sr 3 Si 8 O 4 N 10表示的晶体或 如果需要，包含A元素，D元素，X元素和任选的E元素的Sr 3 Si 8 O 4 N 10晶体的晶体结构相同的无机结晶（A是选自Li，Mg，Ca，Sr和Ba中的一种或多种; D 是选自Si，Ge，Sn，Ti，Zr和Hf中的一种或多种; X是选自O，N和F中的一种或多种; E是选自B，Al，Ga， （M，Mn，Ce，Pr，Nd，Sm，Eu，Tb，Dy和Yb中的一种或多种）固溶于其中的M元素（In，Sc，Y和La））。

公开(公告)号：US20140306159A1

公开(公告)日：2014-10-16

申请号：US14313385

申请日：2014-06-24

Applicant: Panasonic Corporation

Inventor： Shozo OSHIO

IPC: C09K11/77

CPC classification number: C09K11/7795 ,  H01J11/42 ,  Y10T428/2982

Abstract: Provided is a rare earth phosphovanadate phosphor that is excellent in emission characteristics and preferred also from the viewpoint of industrial production, and a production method thereof. The rare earth phosphovanadate phosphor includes at least a primary particle in which a linear uneven pattern including a plurality of ridge lines parallel to each other is formed on the surface of the particle. Further, the method for producing a rare earth phosphovanadate phosphor involves generating a mixture of a rare earth phosphovanadate phosphor and an alkali metal vanadate, and removing the alkali metal vanadate.

Abstract translation: 本发明提供发光特性优异的稀土磷酸钒酸盐荧光体，从工业生产的观点出发，优选其制造方法。 稀土磷酸钒酸盐荧光体至少包括在颗粒表面上形成包括彼此平行的多条脊线的线性不均匀图案的初级颗粒。 此外，稀土磷酸钒酸盐荧光体的制造方法涉及产生稀土磷酸钒酸盐荧光体和碱金属钒酸盐的混合物，除去碱金属钒酸盐。

公开(公告)号：US08624479B2

公开(公告)日：2014-01-07

申请号：US13837388

申请日：2013-03-15

Applicant: Panasonic Corporation

Inventor： Kojiro Okuyama

IPC: H01J17/49

CPC classification number: H01J17/49 ,  C09K11/595 ,  C09K11/7776 ,  H01J11/42

Abstract: Provided is a high-efficiency plasma display panel having short decay time and high luminance and color purity. The plasma display panel includes a green phosphor layer emitting visible light when excited with vacuum ultraviolet rays, in which the green phosphor layer is formed of a green phosphor containing 30% by weight or more and 60% by weight or less of a phosphor represented by a general formula: dZnO.(2−d)MnO.eSiO2 (1.80≦d≦1.90, 1.00≦e≦1.02) and one of a phosphor represented by a general formula: aYO3/2.(3−a)CeO3/2.bAlO3/2.cGaO3/2.fWO3 (2.80≦a≦2.99, 3.00≦b≦5.00, 0≦c≦2.00, 0.003≦f≦0.020, where 4.00≦b+c≦5.00) and a phosphor represented by a general formula: aYO3/2.(3−a)CeO3/2.bAlO3/2.cGaO3/2.gK2WO4 (2.80≦a≦2.99, 3.00≦b≦5.00, 0≦c≦2.00, 0.003≦g≦0.015, where 4.00≦b+c≦5.00).

Abstract translation: 提供了具有短衰减时间和高亮度和色纯度的高效等离子体显示面板。 等离子体显示面板包括在用真空紫外线激发时发出可见光的绿色荧光体层，其中绿色荧光体层由含有30重量％以上且60重量％以下的绿色荧光体形成，荧光体以 通式为dZnO（2-d）MnO.eSiO 2（1.80×d @ 1.90,1.00e @ e @ 1.02）和由通式aYO 3/2表示的荧光体之一（3-a）CeO 3/2 .bAlO3 / 2.cGaO3 / 2.fWO3（2.80 @ a @ 2.99,3.00 @ b @ 5.00,0 @ c @ 2.00，0.003 @ f @ 0.020，其中4.00 @ b + c @ 5.00）和由 通式：aYO3 / 2。（3-a）CeO3 / 2.bAlO3 / 2.cGaO3 / 2.gK2WO4（2.80 @ a @ 2.99,3.00 @ b @ 5.00,0 @ c @ 2.00，0.003 @ g @ 0.015， 其中4.00 @ b + c @ 5.00）。

公开(公告)号：US20130069520A1

公开(公告)日：2013-03-21

申请号：US13701414

申请日：2012-02-17

Applicant: Yoshihisa Nagasaki ,  Yukihiko Sugio ,  Masaaki Akamatsu ,  Kazuhiko Sugimoto

Inventor： Yoshihisa Nagasaki ,  Yukihiko Sugio ,  Masaaki Akamatsu ,  Kazuhiko Sugimoto

IPC: H01J17/49 ,  H01J9/22

CPC classification number: H01J17/49 ,  C09K11/595 ,  H01J9/22 ,  H01J11/42 ,  H01J2211/12

Abstract: A phosphor layer of a plasma display panel has a green phosphor layer containing Zn2SiO4:Mn particles and (Y1-x, Gdx)3(Al1-y, Gay)5O12:Ce particles. The Zn2SiO4:Mn particles satisfy requirements of Zn3p/Si2p≧2.10 (1), and Zn2p/Si2p≧1.25 (2) wherein Zn3p represents an emission amount of photoelectrons emitted from a 3p orbit of a Zn element in a region up to 10 nm from surfaces of the particles, Zn2p represents an emission amount of photoelectrons emitted from a 2p orbit of the Zn element in a region up to 3 nm from the surfaces of the particles, and Si2p represents an emission amount of photoelectrons emitted from a 2p orbit of a Si element in the region up to 10 nm from the surfaces of the particles.

Abstract translation: 等离子体显示面板的荧光体层具有含有Zn2SiO4：Mn粒子和（Y1-x，Gdx）3（Al1-y，Gay）5O12：Ce粒子的绿色荧光体层。 Zn2SiO4：Mn粒子满足Zn3p /Si2p≥2.10（1），Zn2p /Si2p≥1.25（2）的要求，其中Zn3p表示从高达10nm的区域的Zn元素的3p轨道发射的光电子的发射量 从颗粒的表面，Zn2p表示从颗粒的表面至多3nm的区域中从Zn元素的2p轨道发射的光电子的发射量，Si 2p表示从2p轨道发射的光电子的发射量 在距颗粒表面高达10nm的区域中的Si元素。

公开(公告)号：US08361347B2

公开(公告)日：2013-01-29

申请号：US12675890

申请日：2009-07-03

Applicant: Kojiro Okuyama ,  Yayoi Okui ,  Seigo Shiraishi

Inventor： Kojiro Okuyama ,  Yayoi Okui ,  Seigo Shiraishi

IPC: C09K11/64 ,  H01J11/02 ,  H01J61/44

CPC classification number: H01J11/12 ,  C09K11/7736 ,  H01J11/42 ,  H01J61/44

Abstract: The blue phosphor of the present invention includes ZrO2 and a metal aluminate that is represented by the general formula aBaO.bSrO.(1−a−b)EuO.cMgO.dAlO3/2.eWO3, where 0.70≦a≦0.95, 0≦b≦0.15, 0.95≦c≦1.15, 9.00≦d≦11.00, 0.001≦e≦0.200, and a+b≦0.97 are satisfied. This blue phosphor has a ZrO2 content of 0.01 to 1.00% by weight. In the blue phosphor of the present invention, two peaks whose tops are located in a range of diffraction angle 2θ=13.0 to 13.6 degrees are present in an X-ray diffraction pattern obtained by measurement on the blue phosphor using an X-ray with a wavelength of 0.774 Å.

Abstract translation: 本发明的蓝色荧光体包括ZrO 2和由通式aBaO.bSrO表示的金属铝酸盐（1-a-b）EuO.cMgO.dAlO 3 / 2eWO 3，其中0.70和nlE; a＆nlE; 0.95,0和nlE ; b＆nlE; 0.15,0.95＆nlE; c＆nlE; 1.15,9.00和nlE; d＆nlE; 11.00,0.001和nlE; e＆nlE; 0.200和a + b＆nlE; 0.97。 该蓝色荧光体的ZrO 2含量为0.01〜1.00重量％。 在本发明的蓝色荧光体中，顶部位于衍射角2〜13.0〜13.6度的范围内的两个峰存在于通过使用X射线与蓝色荧光体测定而获得的X射线衍射图中 波长0.774Å。

公开(公告)号：US20120299461A1

公开(公告)日：2012-11-29

申请号：US13569681

申请日：2012-08-08

Applicant: Kojiro OKUYAMA

Inventor： Kojiro OKUYAMA

IPC: C09K11/80 ,  H01J61/44

CPC classification number: H01J11/12 ,  C09K11/7774 ,  H01J11/42 ,  H01J2211/42

Abstract: The present disclosure is a plasma display panel including a green phosphor layer. In this plasma display panel, the green phosphor layer includes a phosphor represented by a general formula: aYO3/2.(3−a)CeO3/2.bAlO3/2.cGaO3/2, where 2.80≦a≦2.99, 1.00≦b≦5.00, 0≦c≦4.00, and 4.00≦b+c≦5.00 are satisfied. In this phosphor, a peak whose peak top is located in a range of diffraction angle 2θ of not less than 16.7 degrees but not more than 16.9 degrees is present in an X-ray diffraction pattern obtained by measurement on the phosphor using an X-ray with a wavelength of 0.774 Å. The green phosphor layer also includes a phosphor represented by a general formula: dZnO.(2−d)MnO.eSiO2, where 1.80≦d≦1.90 and 1.00≦e≦1.02 are satisfied, in an amount of 30 wt % or more and 80 wt % or less of the total weight of green phosphors.

Abstract translation: 本公开是包括绿色荧光体层的等离子体显示面板。 在该等离子体显示面板中，绿色荧光体层包括由以下通式表示的荧光体：aYO3 / 2。（3-a）CeO3 / 2.bAlO3 / 2.cGaO3 / 2，其中2.80和nlE; a＆nlE; 2.99,1.00＆ ; b＆nlE; 5.00,0＆nlE; c＆nlE; 4.00和4.00＆nlE; b + c＆nlE; 5.00。 在该荧光体中，峰顶位于衍射角2的范围内的峰; 在通过使用波长为0.774的X射线对荧光体进行测量而获得的X射线衍射图中存在不小于16.7度但不大于16.9度的光。 绿色荧光体层还包括由以下通式表示的荧光体：dZnO。（2-d）MnO.eSiO 2，其中满足1.80和nlE; d＆nlE; 1.90和1.00＆amp; nlE; e＆nlE; 1.02，其量为30重量％ 80重量％以下的绿色荧光体的总重量。

公开(公告)号：US20120187828A1

公开(公告)日：2012-07-26

申请号：US13237021

申请日：2011-09-20

Applicant: Young-Kwan Kim ,  Eun-Gi Heo ,  Kyung-Cheol Choi ,  Seong-Min Lee

Inventor： Young-Kwan Kim ,  Eun-Gi Heo ,  Kyung-Cheol Choi ,  Seong-Min Lee

IPC: H01J17/49 ,  H01J9/22

CPC classification number: H01J9/241 ,  H01J11/22 ,  H01J11/42 ,  H01J2211/42

Abstract: A plasma display panel includes first and second substrates opposite to each other; a plurality of address electrodes disposed on one surface of the first substrate; a plurality of display electrodes disposed in a perpendicular direction to the address electrodes on one surface of the second substrate; and red, green, and blue phosphor layers disposed in a discharge space between the first and second substrates. At least one of the phosphor layers include a phosphor coated with a metal.

Abstract translation: 等离子体显示面板包括彼此相对的第一和第二基板; 设置在所述第一基板的一个表面上的多个寻址电极; 多个显示电极，设置在与第二基板的一个表面上的寻址电极垂直的方向上; 以及设置在第一和第二基板之间的放电空间中的红色，绿色和蓝色荧光体层。 荧光体层中的至少一个包括涂覆有金属的荧光体。

公开(公告)号：US08174192B2

公开(公告)日：2012-05-08

申请号：US11795840

申请日：2006-12-27

Applicant: Kentaro Ueda ,  Nobutaka Hokazono ,  Masanori Suzuki ,  Toshifumi Nagino ,  Ryuichi Murai

Inventor： Kentaro Ueda ,  Nobutaka Hokazono ,  Masanori Suzuki ,  Toshifumi Nagino ,  Ryuichi Murai

IPC: H01J17/49

CPC classification number: G09G3/2983 ,  G09G3/2022 ,  G09G2300/0426 ,  G09G2300/0439 ,  G09G2300/0452 ,  H01J11/12 ,  H01J11/36 ,  H01J11/42

Abstract: A plasma display panel includes a front panel having a front substrate having a plurality of arrays of display electrodes each including a scanning electrode and a sustain electrode opposed to each other with a discharge gap being defined therebetween and a rear panel having a rear substrate opposed to a front substrate and having partition walls for partitioning a discharge space between the rear panel and the front panel, data electrodes formed between partition walls in such a fashion that the data electrodes intersect with the display electrodes, and phosphor layers formed between partition walls, wherein the rear panel forms partition walls so as to divide the discharge space in a plurality of regions along a direction parallel to the data electrodes, and blue phosphor layers are formed on boundary parts of the plural regions.

Abstract translation: 一种等离子体显示面板，包括具有前面基板的前面板，前面基板具有多个显示电极阵列，每个显示电极阵列包括彼此相对的扫描电极和维持电极，其间限定有放电间隙，后面板具有背面基板 前面基板，具有用于分隔后面板和前面板之间的放电空间的分隔壁，以数据电极与显示电极相交的方式在间隔壁之间形成的数据电极以及在间隔壁之间形成的荧光体层，其中 后面板形成分隔壁，以沿着与数据电极平行的方向在多个区域中分隔放电空间，蓝色荧光体层形成在多个区域的边界部分上。

公开(公告)号：US08138674B2

公开(公告)日：2012-03-20

申请号：US12655770

申请日：2010-01-06

Applicant: Seong-Hoon Han

Inventor： Seong-Hoon Han

IPC: H01J17/49

CPC classification number: H01J11/12 ,  H01J11/36 ,  H01J11/42 ,  H01J2211/368

Abstract: A plasma display panel has heights of barrier ribs prevented from abnormally increasing at positions where a phosphor dispensing process starts and ends, improving discharge performance and uniformity of a panel. A front substrate and a rear substrate face each other. Address electrodes and display electrodes extend separately from each other in a first direction and a second direction, respectively, in a space between the front substrate and the rear substrate, the first direction crossing the second direction. Barrier ribs partition a display area including a plurality of discharge cells in the space between the front substrate and the rear substrate. A non-display area is formed along a periphery of the display area. A phosphor layer is formed in each discharge cell. The non-display area includes a buffer area formed of at least a single region outside the display area.

Abstract translation: 等离子体显示面板具有防止在荧光体分配过程开始和结束的位置处防止异常增加的高度，从而改善了面板的放电性能和均匀性。 前基板和后基板彼此面对。 地址电极和显示电极分别在前基板和后基板之间的空间中沿第一方向和第二方向彼此分开延伸，第一方向与第二方向交叉。 阻挡肋在前基板和后基板之间的空间中分隔包括多个放电单元的显示区域。 沿着显示区域的周边形成非显示区域。 在每个放电单元中形成荧光体层。 非显示区域包括由显示区域外的至少一个区域形成的缓冲区域。

公开(公告)号：US08129905B2

公开(公告)日：2012-03-06

申请号：US12301321

申请日：2007-05-25

Applicant: Kojiro Okuyama ,  Masahiro Sakai ,  Seigo Shiraishi

Inventor： Kojiro Okuyama ,  Masahiro Sakai ,  Seigo Shiraishi

IPC: H01J17/49 ,  C09K11/54 ,  C09K11/55 ,  C09K11/59 ,  C09K11/78 ,  C09K11/79

CPC classification number: H01J11/42 ,  C09K11/7734 ,  H01J11/12 ,  H01J61/305 ,  H01J61/44 ,  H01J65/046

Abstract: The present invention provides a phosphor having high luminance, a property of low luminance degradation during driving of a light-emitting device, and chromaticity y comparable to that of BAM:Eu. The present invention is a phosphor represented by the general formula aAO.bEuO.DO.cSiO2, where A is at least one selected from Ca, Sr and Ba, D is at least one selected from Mg and Zn, and 2.970≦a≦3.500, 0.001≦b≦0.030, and 1.900≦c≦2.100 are satisfied. In this phosphor, a peak intensity at 1490 cm−1 is 0.02 to 0.8 when a peak intensity at 565 cm−1 is set to 1 in a spectrum obtained by measurement using photoacoustic spectroscopy.

Abstract translation: 本发明提供一种具有高亮度，在发光装置的驱动期间的低亮度劣化的性质以及与BAM：Eu相当的色度y的荧光体。 本发明是由通式aAO.bEuO.DO.cSiO 2表示的荧光体，其中A是选自Ca，Sr和Ba中的至少一种，D是选自Mg和Zn中的至少一种，以及2.970和nlE; a＆ 3.500，0.001＆nlE; b＆nlE; 0.030和1.900＆nlE; c＆nlE; 2.100。 在该荧光体中，当使用光声光谱测定得到的光谱中，当在565cm -1处的峰值强度为1时，在1490cm -1处的峰强度为0.02〜0.8。