公开(公告)号：US4003920A

公开(公告)日：1977-01-18

申请号：US420742

申请日：1973-11-30

Applicant: Ryuhei Ueeda

Inventor： Ryuhei Ueeda

IPC: B01J23/30 ,  B01J23/888 ,  B01J27/188 ,  B01J37/28 ,  C07C51/215 ,  C07C51/25 ,  C07D307/34 ,  C07D307/60

CPC classification number: C07D307/34 ,  B01J23/30 ,  B01J23/888 ,  B01J27/188 ,  B01J37/28 ,  C07C51/215 ,  C07C51/25 ,  C07C51/252

Abstract: Maleic anhydride is obtained by oxidizing an unsaturated hydrocarbon having at least 4 carbon atoms in the presence of a catalyst comprising the oxides of tungsten and phosphorus, and at least one catalyst promoter selected from the groups consisting of a compound of a metallic element belonging to groups III A, III B, IV A and VIII of the Periodic Table; arsenic, zirconium, antimony, and niobium.

Abstract translation: 马来酸酐通过在包含钨和磷的氧化物的催化剂存在下氧化具有至少4个碳原子的不饱和烃和至少一种催化剂促进剂来获得，所述催化剂助剂选自属于基团的金属元素的化合物 IIIA，IIIB，IVA和VIII号; 砷，锆，锑和铌。

公开(公告)号：US4002698A

公开(公告)日：1977-01-11

申请号：US605968

申请日：1975-08-19

Applicant: Warren W. Kaeding

Inventor： Warren W. Kaeding

IPC: B01J29/40 ,  B01J37/28 ,  C07C1/20 ,  C07C2/00 ,  C07C2/12 ,  C07C2/66 ,  C07C2/86 ,  C07C4/06 ,  C10G11/05 ,  C10G35/095 ,  C07C13/52 ,  C07C15/08

CPC classification number: C10G35/095 ,  B01J29/40 ,  B01J37/28 ,  C07C2/00 ,  C07C2/12 ,  C07C2/66 ,  C07C2/861 ,  C07C2/864 ,  C07C2/865 ,  C07C2/868 ,  C07C4/06 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  C10G2400/20 ,  Y02P20/52 ,  Y10S585/906

Abstract: Process for the methylation of toluene to selectively yield para-xylene by reacting toluene with a methylating agent, such as methanol, in the presence of a catalyst comprising a crystalline aluminosilicate zeolite, which zeolite has a silica/alumina ratio of at least about 12 and a constraint index, as hereinafter defined, within the approximate range of 1 to 12, the catalyst having been modified by the addition thereto of phosphorus in an amount of at least 0.5 percent by weight and activated by vapor phase treatment at a temperature between about 400.degree. C. and about 650.degree. C. for at least about 1 hour with a methanol/water mixture.

Abstract translation: 甲苯甲基化方法选择性地通过使甲苯与甲基化试剂如甲醇在含有结晶硅铝酸盐沸石的催化剂存在下反应生成对二甲苯，所述催化剂包含结晶硅铝酸盐沸石，该沸石的二氧化硅/氧化铝比至少为约12， 如下文定义的约1至12的约束指数，催化剂已经通过加入至少0.5重量％的磷而被改性，并通过气相处理在约400℃的温度下活化 在约60℃下用甲醇/水混合物至少约1小时。

公开(公告)号：US3972832A

公开(公告)日：1976-08-03

申请号：US508308

申请日：1974-09-23

Applicant: Stephen A. Butter ,  Warren W. Kaeding

Inventor： Stephen A. Butter ,  Warren W. Kaeding

IPC: B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J29/82 ,  B01J37/28 ,  C07C1/20 ,  C07C2/00 ,  C07C2/12 ,  C07C2/66 ,  C07C2/86 ,  C07C4/06 ,  C07C6/04 ,  C10G11/05 ,  C10G35/095 ,  B01J27/14 ,  B01J29/06

CPC classification number: C10G35/095 ,  B01J29/40 ,  B01J29/405 ,  B01J37/28 ,  C07C1/20 ,  C07C2/00 ,  C07C2/12 ,  C07C2/66 ,  C07C2/861 ,  C07C2/864 ,  C07C2/865 ,  C07C2/868 ,  C07C4/06 ,  C07C6/04 ,  B01J29/18 ,  B01J29/65 ,  B01J29/70 ,  B01J29/82 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  C10G2400/20 ,  Y02P20/52

Abstract: This specification discloses, as a composition of matter, a phosphorus-containing zeolite and discloses a method for preparing it. The composition is a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12, a constraint index of about 1 to 12, and containing phosphorus incorporated with the crystal structure thereof in an amount of at least about 0.78 percent by weight. The specification also discloses the use of the composition as a catalyst for the conversion of aliphatic compounds.

Abstract translation: 本说明书作为物质组合物公开了含磷沸石，并公开了其制备方法。 所述组合物是二氧化硅与氧化铝之比至少约为12，约束指数为约1至12，并含有至少约0.78重量％的晶体结构的磷的结晶硅铝酸盐沸石。 本说明书还公开了组合物作为脂族化合物转化的催化剂的用途。

公开(公告)号：US3941844A

公开(公告)日：1976-03-02

申请号：US491626

申请日：1974-07-25

Applicant: Hans Joachim Szymanski ,  Toni Dockner

Inventor： Hans Joachim Szymanski ,  Toni Dockner

IPC: C07B61/00 ,  B01J27/16 ,  B01J37/28 ,  C07C67/00 ,  C07C209/00 ,  C07C209/60 ,  C07C211/48 ,  C07C87/62

CPC classification number: C07C209/60 ,  B01J27/16 ,  B01J37/28

Abstract: N-alkylated arylamines are prepared by reaction of arylamines which have at least one hydrogen atom on the nitrogen, with olefins or cycloolefins which can have substituents which are inert under the reaction conditions, at temperatures from 180.degree. to 450.degree.C, in the presence of catalysts. The improvement is that silicic acid which contains from 0.1 to 30 percent by weight of phosphoric acids, based on silicic acid, is used as the catalysts and that catalytic amounts of water are employed. N-alkylated arylamines are starting materials for the manufacture of dyes, pesticides, plant protection agents and growth regulators, and can also be used as mineral oil additives.

Abstract translation: 在烷基化芳基胺的存在下，在180℃至450℃的温度下，通过使在氮气中具有至少一个氢原子的芳基胺与可在反应条件下为惰性的取代基的烯烃或环烯烃反应来制备N-烷基化芳基胺 的催化剂。 改进之处在于，使用含有0.1〜30重量％磷酸（以硅酸为基准）的硅酸作为催化剂，使用催化剂量的水。 N-烷基化芳胺是用于制造染料，农药，植物保护剂和生长调节剂的起始原料，也可用作矿物油添加剂。

公开(公告)号：US3862249A

公开(公告)日：1975-01-21

申请号：US24423172

申请日：1972-04-14

Applicant: HIBERNIA CHEMIE GMBH

Inventor： ESTER WILHELM ,  HEITMANN WILHELM

IPC: B01J21/16 ,  B01J27/16 ,  B01J37/28 ,  C07C29/04

CPC classification number: B01J37/28 ,  B01J21/16 ,  B01J27/16

Abstract: Improvements in the production of alcohols by hydration of their corresponding olefins, particularly olefins having three to six carbon atoms, in the presence of an acid catalyst, wherein the improvement resides in utilizing a catalyst which is a mineral acid, preferably phosphoric acid, impregnated into a substrate in a minimum proportion necessary to catalyze the reaction, which proportion is such that substantially no acid is removed from the catalyst under hydration reaction conditions.

Abstract translation: 在酸催化剂存在下，通过使相应的烯烃，特别是具有3-6个碳原子的烯烃进行水合，来改进醇的生产，其中改进在于利用无机酸，优选磷酸的催化剂， 催化反应所需的最小比例的底物，其比例使得在水合反应条件下基本上不从催化剂中除去酸。

公开(公告)号：US3846336A

公开(公告)日：1974-11-05

申请号：US27958572

申请日：1972-08-10

Applicant: CELANESE CORP

Inventor： LEVY L

IPC: B01J27/057 ,  B01J27/18 ,  B01J37/28 ,  C07C51/25 ,  B01J11/82

CPC classification number: B01J37/28 ,  B01J27/0576 ,  B01J27/18 ,  C07C51/252 ,  C07C57/04

Abstract: This disclosure relates to the oxidation of olefins to unsaturated aldehydes and unsaturated acids such as the conversion of propylene to acrolein and acrylic acid in the vapor phase and at an elevated temperature in the presence of a catalyst comprising phosphorus, molybdenum and tellurium dioxide supported with rhenium on an inert support and methods for preparation of the catalyst.

Abstract translation: 本公开涉及将烯烃氧化成不饱和醛和不饱和酸，例如在含有磷，钼和铼负载的二氧化钌的催化剂存在下，在气相和升高的温度下将丙烯转化为丙烯醛和丙烯酸 惰性载体和催化剂的制备方法。

公开(公告)号：US3824178A

公开(公告)日：1974-07-16

申请号：US35496773

申请日：1973-04-27

Applicant: SHELL OIL CO

Inventor： WALD M

IPC: B01J23/06 ,  B01J23/18 ,  B01J27/18 ,  B01J35/10 ,  B01J35/12 ,  B01J37/28 ,  C10G47/08 ,  C10G13/08 ,  B01J11/78

CPC classification number: B01J37/28 ,  B01J23/06 ,  B01J23/18 ,  B01J27/1802 ,  B01J35/12 ,  C10G47/08

Abstract: HIGHER MOLECULAR WEIGHT HYDROCARBBONACEOUS MATERIALS CONTAINING POLYNUCLEAR SUBSTANCES, SUCH AS HEAVY PETROLEUM CRUDES AND HIGHER BOILING PETROLEUM FRACTIONS, INCLUDING RESIDUAL FRACTIONS, SHALE OIL, TAR SAND OIL, OIL AND TAR FROM COAL AND COAL ITSELF ARE HYDROCRACKD AT AN ELEVATED TEPERATURE RANGING FROM 250*C. TO 500*C. AND IN THE PRESENCE OF HYDROGEN AT A HPRESSURE OF 200 TO 3000 P.S.I.G., WHILE INTIMATELY MIXED WITH A HOMOGENEOUS CONTINUOUS LIQUID PHASE CATALYST SYSTEM COMPRISING PREDOMINATELY ONE OR MORE PHOSPHORIC ACIDS THERMALLY STABLE UNDER THE HYDROCRACKING CONDITIONS, SUCH AS, PYROPHOSPHORIC ACID AND POLYPHOSPHORIC ACIDS HAVING AN EMPIRICAL ACID AND H2O:P2O5 OF 3 OR LESS, ANDA MINOR PROPORTION, E.G., 10% BY WEIGHT OF CERTAIN METAL POLYHALIDES WHICH ARE ACTIVE HYDROCRACKING CATALYST, E.G., ESPECIALLY ZINC, GALLIUM AND ANTIMONY HALIDES.

公开(公告)号：US2377092A

公开(公告)日：1945-05-29

申请号：US36189040

申请日：1940-10-19

Applicant: UNIVERSAL OIL PROD CO

Inventor： MCGREW EDWIN H

IPC: B01J27/16 ,  B01J37/28 ,  C10G11/04 ,  C10G35/06

CPC classification number: B01J37/28 ,  B01J27/16 ,  C10G11/04 ,  C10G35/06

公开(公告)号：US20250026991A1

公开(公告)日：2025-01-23

申请号：US18355794

申请日：2023-07-20

Applicant: Saudi Arabian Oil Company

Inventor： Miao Sun ,  Noor Al-Mana ,  Lianhui Ding ,  Eman Zaki Albaher ,  Guanghui Zhu ,  Ke Zhang

IPC: C10G47/12 ,  B01J21/04 ,  B01J21/06 ,  B01J23/00 ,  B01J23/745 ,  B01J23/83 ,  B01J23/883 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/28 ,  C10G47/04 ,  C10G69/06

Abstract: Systems and method for upgrading pyrolysis oil to produce greater value aromatic compounds includes combining heavy pyrolysis oil and a diluent to produce the pyrolysis oil feed withleast 30 wt. % multi-ring aromatic compounds boiling at greater than 360° C. The systems and methods include passing the pyrolysis oil feed to a fixed bed reactor having a hydrocracking catalyst that includes pellets having a particle size greater than or equal to 0.1 millimeter. The hydrocracking catalyst is a mixed metal oxide catalyst that includes a binder and mixed metal oxide particles or a supported metal oxide catalyst that includes molybdenum oxide and nickel oxide supported on a catalyst support material comprising a large-pore alumina. The methods may further include contacting the pyrolysis oil feed with the hydrogen in the presence of the hydrocracking catalyst at reaction conditions in the fixed bed reactor to produce a reaction effluent.

公开(公告)号：US20240042423A1

公开(公告)日：2024-02-08

申请号：US18266661

申请日：2021-12-02

Applicant: IFP ENERGIES NOUVELLES

Inventor： Elodie DEVERS

IPC: B01J38/48 ,  B01J38/02 ,  B01J38/12 ,  B01J38/62 ,  B01J37/28 ,  B01J37/20 ,  B01J27/19 ,  B01J27/28 ,  B01J21/04 ,  C10G47/20

CPC classification number: B01J38/485 ,  B01J38/02 ,  B01J38/12 ,  B01J38/62 ,  B01J37/28 ,  B01J37/20 ,  B01J27/19 ,  B01J27/285 ,  B01J21/04 ,  C10G47/20

Abstract: The invention relates to a process for rejuvenating an at least partially spent hydrotreating and/or hydrocracking catalyst, said catalyst comprising a group VIII metal, a group VIB metal and an oxide support, said process comprising the following steps:



a) the catalyst is regenerated,
b) said regenerated catalyst is then brought into contact with an impregnation solution consisting of a mixture of water, at least one precursor of a group VIB metal, at least one precursor of a group VIII metal and at least one organic compound, the amount of organic compound introduced into the regenerated catalyst being optimized with respect to the metals already present in the regenerated catalyst and with respect to the amount of metals introduced via the impregnation solution,
c) a drying step is then carried out without subsequently calcining it.