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    Oxygen Scavenging Compositions and Method of Preparation
    123.
    发明申请
    Oxygen Scavenging Compositions and Method of Preparation 审中-公开
    氧气清除组合物和制备方法

    公开(公告)号：US20080171169A1

    公开(公告)日：2008-07-17

    申请号：US11911288

    申请日：2006-04-07

    Applicant: Zhenguo Liu

    Inventor： Zhenguo Liu

    IPC: B32B1/02 ,  C08G63/66 ,  C08G63/52 ,  C09K3/00 ,  C08F120/00

    CPC classification number: C08G63/52 ,  B65D81/266 ,  C08G63/676 ,  C08K5/098 ,  C08K2201/012 ,  C08L23/02 ,  C08L67/02 ,  C08L67/06 ,  C08L77/00 ,  Y10T428/1352 ,  Y10T428/1397 ,  C08L2666/06 ,  C08L2666/18

    Abstract: The object of the invention is to provide a polyester composition that actively scavenges oxygen, with or without a transition metal catalyst. This was achieved by using a monomer selected from the group consisting of linear difunctional monomers having the general formula: X—(CH2)n—CH═CH—(CH2)m—X′ wherein X and X′ are each independently selected from the group consisting of OR and COOR, wherein R is selected from the group consisting of H and alkyl groups with one or more carbon atoms; and n and m are each independently 1 or more. The preferred monomer is 2-butene-1,4-diol (BEDO), and the preferred polyester is the reaction product of this diol with terephthalic acid to form poly(oxy-2-butene-1,4-diyloxycarbonyl-1,4-phenylenecarbonyl)—PBET. Copolymers of PBET are also within the scope of this invention. The polyester oxygen scavenging composition is then blended with conventional container resin such as polyesters, polyamides or polyolefins to make a container.

    Abstract translation: 本发明的目的是提供一种聚酯组合物，其有或没有过渡金属催化剂主动地清除氧气。 这通过使用选自以下通式的线性二官能单体：X - （CH 2）n - CH- CH-（CH 2） 其中X和X'各自独立地选自OR和COOR，其中R选自H和烷基 具有一个或多个碳原子; n和m各自独立地为1以上。 优选的单体是2-丁烯-1,4-二醇（BEDO），优选的聚酯是该二醇与对苯二甲酸的反应产物，以形成聚（氧-2-丁烯-1,4-二氧基羰基-1,4 - 苯基羰基）-PBET。 PBET的共聚物也在本发明的范围内。 然后将聚酯氧清除组合物与常规容器树脂如聚酯，聚酰胺或聚烯烃混合以制成容器。

    ENHANCED OXYGEN-SCAVENGING POLYMERS, AND PACKAGING MADE THEREFROM
    124.
    发明申请
    ENHANCED OXYGEN-SCAVENGING POLYMERS, AND PACKAGING MADE THEREFROM 有权
    增强型氧气聚合物及其包装

    公开(公告)号：US20080153939A1

    公开(公告)日：2008-06-26

    申请号：US12022319

    申请日：2008-01-30

    Applicant: Steven L. Schmidt ,  Brian Lynch ,  Keith Barker ,  Ronald Adams ,  Amit S. Agrawal

    Inventor： Steven L. Schmidt ,  Brian Lynch ,  Keith Barker ,  Ronald Adams ,  Amit S. Agrawal

    IPC: A23B7/00

    CPC classification number: B32B27/18 ,  A23L3/3436 ,  B32B27/08 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B33/00 ,  B32B2307/518 ,  B32B2439/70 ,  C08K3/08 ,  C08K5/098 ,  C08K2003/0843 ,  C08K2201/012 ,  Y10T428/1338 ,  Y10T428/1352 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/1379 ,  C08L77/00

    Abstract: Oxygen-scavenging polymers and packaging for holding oxygen-sensitive products. A heat treatment process has been found to significantly increase the oxygen-scavenging performance of the polymer. The enhanced scavenging polymer can be effectively incorporated into various packaging, including transparent multilayer containers for beer and juice. In one embodiment, a multilayer package made from the scavenger provides an actual reduction in oxygen content of a contents of the package, over a long period of time (e.g., 24 weeks). The package can be stored unfilled for an extended period (without significant loss of scavenging capability) and will scavenge substantially immediately upon filling with a liquid product. The package may incorporate a relatively low weight percentage of the scavenger, thus providing enhanced scavenging in a cost-effective manner.

    Abstract translation: 含氧清除聚合物和用于保存氧敏感产品的包装。 已经发现热处理工艺显着地提高了聚合物的清除氧气的性能。 增强的清除聚合物可以有效地结合到各种包装中，包括用于啤酒和果汁的透明多层容器。 在一个实施方案中，由清除剂制成的多层包装在长时间（例如24周）内提供包装内容物的氧含量的实际降低。 包装可以长时间储存​​（不会显着损失清除能力），并且在填充液体产品时将基本上立即清除。 包装可以包含相对较低重量百分比的清除剂，从而以成本有效的方式提供增强的清除。

    Transition metal carboxylates as catalysts for oxygen scavenging
    128.
    发明申请
    Transition metal carboxylates as catalysts for oxygen scavenging 有权
    过渡金属羧酸盐作为氧气清除的催化剂

    公开(公告)号：US20050104033A1

    公开(公告)日：2005-05-19

    申请号：US10717297

    申请日：2003-11-19

    Applicant: Richard Schmidt ,  James Solis ,  Ta Ching

    Inventor： Richard Schmidt ,  James Solis ,  Ta Ching

    IPC: B65D81/26 ,  C08K5/098 ,  H01K1/56

    CPC classification number: C08K5/098 ,  B65D81/266 ,  C08K2201/012

    Abstract: Disclosed herein are oxygen scavenging compositions and packaging articles that comprise (a) a metal catalyzed oxidizable compound and (b) at least one of a transition metal carboxylate, wherein the transition metal carboxylate comprises at least one carboxylate group and wherein each carboxylate group comprises between 20 and 30 carbon atoms, inclusive, such as cobalt behenate or cobalt arachidate.

    Abstract translation: 本文公开了除氧组合物和包装制品，其包含（a）金属催化的可氧化化合物和（b）过渡金属羧酸盐中的至少一种，其中过渡金属羧酸盐包含至少一个羧酸酯基团，并且其中每个羧酸酯基包括 20和30个碳原子（包括端值），如山嵛酸钴或花生四烯酸钴。

    Oxygen-scavenging polymer compositions
    129.
    发明申请
    Oxygen-scavenging polymer compositions 审中-公开
    清除氧气的聚合物组合物

    公开(公告)号：US20030212167A1

    公开(公告)日：2003-11-13

    申请号：US10140639

    申请日：2002-05-08

    Applicant: Teknor Apex Company

    Inventor： Dexi Weng ,  John A. Buono

    IPC: C08K011/00

    CPC classification number: C08K5/1545 ,  C08K2201/012 ,  C08L27/06

    Abstract: A polymer composition capable of depleting oxygen from adjacent spaces is disclosed. One or more botanical extracts, either naturally occurring or synthetic, that contain proanthocyanidin or its derivatives are added to a base polymer or polymer blend prior to processing to provide the polymer with oxygen-scavenging benefits without adverse effect to the characteristics of the base polymer or polymer blend.

    Abstract translation: 公开了能够从相邻空间中耗尽氧的聚合物组合物。 一种或多种含有原花色素或其衍生物的天然存在或合成的植物提取物在加工之前加入到基础聚合物或聚合物共混物中，以提供聚合物具有除氧效果，而不会对基础聚合物的特性产生不利影响，或 聚合物共混物。

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