Abstract:
The present invention relates to a process for making essentially ethylene and propylene comprising: a) providing an alcohol mixture (A) comprising about 20 w % to 100% isobutanol, b) introducing in a reactor (A) a stream comprising the mixture (A) mixed with methanol or dimethyl ether or mixture thereof, optionally water, optionally an inert component, c) contacting said stream with a catalyst (A1) in said reactor (A), the MTO reactor, at conditions effective to convert at least a part of the alcohol mixture (A) and at least a part of the methanol and/or dimethyl ether to olefins, d) recovering from said reactor (A) an effluent comprising: ethylene, propylene, butene, water, optionally unconverted alcohols, various hydrocarbons, and the optional inert component of step b), e) fractionating said effluent of step d) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
Abstract translation:本发明涉及一种基本上制备乙烯和丙烯的方法,包括:a)提供包含约20重量%至100重量%异丁醇的醇混合物(A),b)在反应器(A)中引入包含混合物(A )与甲醇或二甲醚或其混合物,任选的水,任选的惰性组分混合,c)使所述流与所述反应器(A)中的催化剂(A1),所述MTO反应器在有效地转化至少一部分 的醇混合物(A)和至少一部分甲醇和/或二甲醚至烯烃,d)从所述反应器(A)回收包含乙烯,丙烯,丁烯,水,任选未转化的醇,各种烃 和步骤b)的任选的惰性组分,e)将步骤d)的所述流出物分馏以产生至少一种乙烯流,丙烯料流,基本上由具有4个或更多个碳原子的烃组成的馏分,水和任选的惰性 com 步骤a)的方法,任选地在反应器(A)的入口处全部或部分地回收乙烯,任选地在反应器(A)的入口处循环基本上由具有4个或更多个碳原子的烃组成的馏分。
Abstract:
A method of removing mercury from a fluid stream comprising contacting the fluid stream with a sorbent comprising cupric sulfide. The cupric sulfide is formed from direct sulfidation of copper carbonate, without thermal decomposition of the copper carbonate to an oxide, at a temperature less than about 150° C.
Abstract:
The present invention relates to a method for producing a hydrocarbon product from coal and/or biomass comprising the following steps: converting the coal to a coal-oil and/or converting the biomass to bio-oil, optionally processing the coal-oil and/or bio-oil in a hydroprocessing reaction to remove one or more of oxygen, nitrogen or sulfur from hydrocarbon compounds in the coal-oil and/or bio-oil; and using at least a portion of the coal-oil and/or bio-oil as a feedstock in a cracking reaction to convert hydrocarbon compounds in the feedstock into a mixture of smaller hydrocarbon compounds comprising the hydrocarbon product.
Abstract:
The invention deals with hydrocarbon feedstock molecular weight increase via olefin oligomerization and/or olefin alkylation onto aromatic rings. Addition of a purification section allows improved unit working time and lower maintenance.
Abstract:
In various embodiments, the present disclosure describes methods for removing impurities from a hydrocarbon stream containing at least one vinyl aromatic compound such as, for example, styrene. The methods include pretreating at least one sorbent to make the at least one sorbent operable for adsorbing the impurities, contacting the hydrocarbon stream with the at least one sorbent in order to adsorb at least a portion of the impurities and separating the hydrocarbon stream from the at least one sorbent. Impurities include, for example, colored impurities, sulfur-containing impurities and combinations thereof.
Abstract:
A system for removing polar components from a process stream in a refinery process without cooling the stream is disclosed. The stream is fed to a first adsorber unit to remove contaminants containing sulfur from the stream at substantially the same elevated temperature. The stream is processed within the first adsorber unit by exposing the stream to at least one of a metal oxide and a mixed metal oxide to remove the sulfur containing contaminants and produce a metal sulfide and a desulfurized stream. The desulfurized stream is then fed through a second adsorber unit to remove contaminants containing nitrogen from the stream at substantially the same elevated temperature. The stream is processed within the second adsorber unit by exposing the stream to at least one of a molecular sieve and zeolites to remove nitrogen containing contaminants from the stream.
Abstract:
A process, comprising: a. taking a sample from a continuous alkylation reactor process; b. measuring a content of a halide in the sample; and c. within 45 minutes from the taking a sample, adjusting a flow of a halide containing additive comprising the halide to control a ratio of a yield of an alkylate gasoline and a yield of a middle distillate. Also a process, comprising: a. taking a sample from an effluent of an alkylation reactor in an alkylation reactor process; b. measuring a content of a halide in the sample; and c. in response to the measured content of the halide, adjusting a flow of a halide containing additive to a predetermined range that has been selected to obtain a ratio of a yield of an alkylate gasoline and a yield of a middle distillate from 0.31 to 4.0 in a product from the alkylation reactor.
Abstract:
The present invention is directed to the upgrading of heavy hydrocarbon feedstock that utilizes a short residence pyrolytic reactor operating under conditions that cracks and chemically upgrades the feedstock. The method for upgrading a heavy hydrocarbon feedstock comprises introducing a particulate heat carrier into an upflow reactor, introducing the heavy hydrocarbon feedstock into the upflow reactor at a location above that of the particulate heat carrier so that a loading ratio of the particulate heat carrier to feedstock is from about 15:1 to about 200:1, allowing the heavy hydrocarbon feedstock to interact with the heat carrier with a residence time of less than about 1 second, to produce a product stream, separating the product stream from the particulate heat carrier, regenerating the particulate heat carrier, and collecting a gaseous and liquid product from the product stream.
Abstract:
The invention relates to a method for continuous use of a vacuumized water knockout circuit integrated with a contaminated hydraulic-oil reservoir.
Abstract:
A process is presented for producing a purified normal paraffin product stream. The process includes passing a hydrocarbon stream having the desired normal paraffins to an adsorption separation system. A process stream generated from the separation system and having the normal paraffins is passed to an adsorption unit for the selective adsorption of aromatic compounds from the process stream, thereby producing a purified product.