公开(公告)号：US10604723B2

公开(公告)日：2020-03-31

申请号：US15523700

申请日：2015-11-09

Applicant: Rohm and Haas Company ,  Union Carbide Corporation

Inventor： Josephine Eldredge ,  John Hayes ,  Emmett M. Partain, III ,  Jan E. Shulman ,  Jennifer J. Todd

IPC: C11D1/00 ,  C11D3/22 ,  C11D3/00 ,  C07C211/63 ,  C08L1/28

Abstract: A fabric care composition comprising a modified carbohydrate polymer having quaternary ammonium groups having at least one C8-C22 alkyl or alkenyl group. The modified carbohydrate polymer has a weight-average molecular weight of at least 500,000.

公开(公告)号：US10590290B2

公开(公告)日：2020-03-17

申请号：US15776808

申请日：2015-12-15

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Hu Li ,  Weijun Yang ,  Tao Wang ,  Xinhui Huang ,  Siyuan Jiang ,  Cheng Hui Chen

IPC: C09D7/41 ,  C09D7/65 ,  C09D5/02 ,  C08F265/04 ,  C09D151/00 ,  C08F220/18 ,  C09D7/61 ,  C09D7/43 ,  C09D133/06

Abstract: This invention generally relates to a multi-stage polymer suitable for a grinding additive, a method for producing the multi-stage polymer, a composition and a paint composition comprising the multi-stage polymer and a use of the multi-stage polymer for a grinding additive of a paint composition.

公开(公告)号：US10590271B2

公开(公告)日：2020-03-17

申请号：US15556302

申请日：2015-03-31

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company ,  UCAR Emulsion Systems FZE

Inventor： Shiling Zhang ,  Lukasz Zukowski ,  Yujiang Wang ,  Dong Yun ,  Ling Li ,  Youjun Wu

IPC: C08L33/00 ,  C08L33/02 ,  C09D133/02

Abstract: The present invention further provides a binder composition comprising a first binder and a second binder. The first binder comprises, by dry weight based on total dry weight of the binder composition, from 1% to 98% polymer particles, from 0.3% to 20% an anionic polyelectrolyte, and from 0.1% to 20% a colorant; and the second binder comprises, by dry weight based on total dry weight of the binder composition, from 0.5% to 70% a clay, and from 0.03% to 10% a dispersant. It also provides a paint formulation comprising the binder composition.

公开(公告)号：US20200071558A1

公开(公告)日：2020-03-05

申请号：US16556572

申请日：2019-08-30

Applicant: Rohm and Haas Company

Inventor： James K. Bardman ,  David G. Kelly ,  Michael W. Leonard

IPC: C09D133/06 ,  C09D7/40

Abstract: The present invention relates to a composition comprising an aqueous dispersion of multistage polymer particles comprising a first and a second phase, wherein the first phase comprises structural units of a carboxylic acid monomer or a salt thereof, and a nonionic ethylenically unsaturated monomer; and wherein the second phase comprises a first and second polymer, wherein the first phase or the second phase first polymer or both comprise structural units of a high Tg hydrophobic monomer; and wherein the second phase second polymer comprises at least 80 percent structural units of styrene. The high Tg hydrophobic monomer is defined as being one or more of the following monomers: cyclohexyl methacrylate, isobornyl methacrylate, 4-t-butyl methacrylate, t-butylstyrene, or n-butyl methacrylate. The multistage polymer particles are useful as opaque polymers, which are used in pigmented coating formulations to reduce the load of TiO2. The particles exhibit excellent collapse resistance and unusually low dry bulk density, and do not require acrylonitrile to achieve this desired combination of properties.

公开(公告)号：US20200071439A1

公开(公告)日：2020-03-05

申请号：US16556607

申请日：2019-08-30

Applicant: Rohm and Haas Company

Inventor： James K. Bardman ,  David G. Kelly ,  Michael W. Leonard

IPC: C08F220/18 ,  C08F2/22 ,  C08F220/14 ,  C08F20/70 ,  C08F20/56 ,  C08K3/22 ,  C08F6/02

Abstract: The present invention relates to a method of preparing an aqueous dispersion of multistage polymer particles comprising contacting under emulsion polymerization conditions and in a staged fashion an aqueous dispersion of carboxylic acid functionalized core polymer particles with first monomers and second monomers. The core comprises structural units of a high Tg hydrophobic monomer and/or the first monomers comprise a high Tg hydrophobic monomer, and the second monomers comprise at least 80 percent styrene. The high Tg hydrophobic monomer is cyclohexyl methacrylate, isobornyl methacrylate, 4-t-butyl methacrylate, t-butylstyrene, or n-butyl methacrylate, or a combination thereof. The multistage polymer particles are useful as opaque polymers, which are used in pigmented coating formulations to reduce the load of TiO2. The particles exhibit excellent collapse resistance and unusually low dry bulk density, and do not require acrylonitrile to achieve this desired combination of properties.

公开(公告)号：US10563059B2

公开(公告)日：2020-02-18

申请号：US15840145

申请日：2017-12-13

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Muhunthan Sathiosatham

IPC: C08K3/22 ,  C09D151/00 ,  C08F265/06 ,  C08L51/00 ,  C09D5/00

Abstract: The present invention relates to a composition comprising a stable aqueous dispersion of polymer particles comprising structural units of a polymerizable amino acid and structural units of an acid monomer or a salt thereof. The composition of the present invention is useful in improving lipstick stain resistance in coatings compositions.

公开(公告)号：US20200048386A1

公开(公告)日：2020-02-13

申请号：US16342355

申请日：2017-11-06

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： John David Finch ,  James A. Jagodzinski

IPC: C08F212/08

Abstract: Provided is a method of making a collection of polymer beads comprising (a1) forming a first collection of monomer droplets in an aqueous medium in a container, wherein the first collection of monomer droplets has volume-average diameter DAV1 and has uniformity coefficient less than 1.3; (a2) forming a second collection of monomer droplets in the aqueous medium in the container, wherein the second collection of monomer droplets has volume-average diameter DAV2 and has uniformity coefficient less than 1.3, wherein DAV1 and DAV2 differ by 10 μm or more; wherein either step (a1) and step (a2) are performed simultaneously; or step (a2) is performed after step (a1), while the first collection of monomer droplets remains in the container; or a combination thereof; and (b) after steps (a1) and (a2), polymerizing the monomer droplets by suspension polymerization to form the polymer beads.

公开(公告)号：US10550064B2

公开(公告)日：2020-02-04

申请号：US15769568

申请日：2016-11-01

Applicant: Rohm and Haas Company ,  Dow Global Technologies LLC

Inventor： Collin H. Martin ,  Stephen Pease ,  Daryl J. Gisch ,  Stanislas Baudouin

IPC: C07C51/47 ,  B01D15/36 ,  C07H3/00 ,  B01D15/34 ,  C07H3/02 ,  B01J20/26 ,  B01J20/28 ,  C07C59/265 ,  C07C55/10 ,  C07C59/08

Abstract: A process of separating carboxylic acids comprising two steps. The first step is to provide an aqueous solution comprising (i) one or more mono-carboxylic acids, (ii) one or more di-carboxylic acids, and (iii) one or more tri-carboxylic acids. The second step is to pass the aqueous solution through a collection of resin particles, where the resin particles comprise covalently bound quaternary ammonium groups, and wherein the collection of resin particles has uniformity coefficient of 1.5 or less.

公开(公告)号：US20200024458A1

公开(公告)日：2020-01-23

申请号：US16511061

申请日：2019-07-15

Applicant: Rohm and Haas Company

Inventor： Jonathan DeRocher ,  Andrew Hejl ,  Jessica Levin ,  John J. Rabasco ,  Antony K. Van Dyk ,  Kimy Yeung

IPC: C09D4/06 ,  C09D133/10 ,  C09D7/65

Abstract: The present invention relates to a composition comprising an aqueous dispersion of multistage polymer particles with a first phase comprising structural units of a carboxylic acid monomer and a nonionic ethylenically unsaturated monomer; and a second phase with a calculated Tg of less than 50° C. and comprising a mixture of polymers which together comprise structural units of styrene or methyl methacrylate or both; structural units of one or of n-butyl acrylate, 2-ethylhexyl acrylate, ethyl acrylate, or n-butyl methacrylate; and structural units of a carboxylic acid monomer. The composition is useful as an open time additive in coatings formulations.

公开(公告)号：US20200024440A1

公开(公告)日：2020-01-23

申请号：US16511069

申请日：2019-07-15

Applicant: Rohm and Haas Company

Inventor： Jonathan DeRocher ,  Andrew Hejl ,  Jessica Levin ,  John J. Rabasco ,  Antony K. Van Dyk ,  Kimy Yeung

IPC: C08L33/12 ,  C09D7/65 ,  C09D5/14

Abstract: The present invention relates to a process for preparing an aqueous dispersion of neutralized multistage polymer particles comprising the steps of:1) contacting under emulsion polymerization conditions a) a aqueous dispersion of first polymer particles comprising structural units of a carboxylic acid monomer, and structural units of a nonionic monomer with b) first monomers comprising styrene or methyl methacrylate or a combination thereof, and a carboxylic acid monomer; to form an aqueous dispersion of 2-stage polymer particles; then2) contacting under emulsion polymerization conditions the aqueous dispersion of first multistage polymer particles with second monomers comprising a) methyl methacrylate; b) n-butyl acrylate, 2-ethylhexyl acrylate, ethyl acrylate, or n-butyl methacrylate, or a combination thereof; c) a carboxylic acid monomer; and d) less than 20 weight percent styrene, to form an unneutralized aqueous dispersion of 3-stage polymer particles; then3) neutralizing the unneutralized aqueous dispersion of 3-stage polymer particles with a base to form an aqueous dispersion of neutralized 3-stage polymer particles, wherein the first and second monomers form a shell having a calculated Tg of less than 50° C.The process of the present invention is useful in preparing a composition that is useful as an open time additive in coatings formulations.