Abstract:
Digestion of cellulosic biomass to produce a hydrolysate may be accompanied by the formation of cellulosic fines which may be damaging to system components. Biomass conversion systems that may address the issue of cellulosic fines may comprise a fluid circulation loop comprising: a hydrothermal digestion unit; a solids separation unit that is in fluid communication with an outlet of the hydrothermal digestion unit; where the solids separation unit comprises a centripetal force-based separation mechanism that comprises a fluid outlet and a solids outlet; and a catalytic reduction reactor unit that is in fluid communication with the fluid outlet of the centripetal force-based separation mechanism and an inlet of the hydrothermal digestion unit.
Abstract:
Digestion of cellulosic biomass to produce a hydrolysate may be accompanied by the formation of cellulosic fines which may be damaging to system components. Biomass conversion systems that may address the issue of cellulosic fines may comprise a fluid circulation loop comprising: a hydrothermal digestion unit; a solids separation unit that is in fluid communication with an outlet of the hydrothermal digestion unit; where the solids separation unit comprises a plurality of filters and the filters are in fluid communication with the fluid circulation loop in both a forward and a reverse flow direction; and a catalytic reduction reactor unit that is in fluid communication with an outlet of the solids separation unit and an inlet of the hydrothermal digestion unit; where at least one of the plurality of filters is in fluid communication with an inlet of the catalytic reduction reactor unit.
Abstract:
The present invention describes a method of producing fatty acid alkyl esters and glycerin implementing a set of transesterification reactions between a vegetable or animal oil and an aliphatic monoalcohol in the presence of a heterogeneous solid catalyst so as to obtain an effluent comprising at least alkyl esters, free glycerol, bonded glycerol and alcohol, wherein at least one stage of separation of at least a portion of the effluent is carried out in order to separate the ester produced and the bonded glycerol, said separation occurring through a membrane.
Abstract:
The instant invention pertains to the use of formic acid in new processes for treating feedstocks comprising holocellulose, as well as, new compositions suitable for, for example, bioalcohol production. The processes may comprise first mixing the feedstock with an aqueous acid solution comprising formic acid and then producing a hydrolysis product comprising monosaccharides and water-soluble oligosaccharides. The compositions typically comprise a feedstock comprising holocellulose and an aqueous acid solution comprising formic acid. Advantageously, the processes and compositions of the present invention may be used in more environmentally friendly, cost-efficient production of fuels.
Abstract:
This invention is a method for converting biomass derived pyrolysis oil (bio-oil) into materials that will be more useful for transportation fuels including the following two steps: 1) solubilizing and extracting bio-oil oxygenates, and 2) zeolite catalyzed hydrogenation of the oxygenates into renewable fuel range materials.
Abstract:
Aspects of the present invention relate to methods, systems, and compositions for preparing a solid biomass for fast pyrolysis. The method includes contacting the solid biomass with an inorganic material present in an effective amount for increasing fast pyrolysis yield of an organic liquid product (e.g., bio-oil). In various embodiments, the inorganic material is selected from the group consisting of aluminum sulfate, aluminum nitrate, aluminum chloride, aluminum hydroxide, ammonium hydroxide, magnesium hydroxide, potassium hydroxide, and combinations thereof.
Abstract:
A method is provided for growing microalgae from wastewater for oil production in a three-step wastewater treatment facility. In the method, two carbon sources are selected for addition to the wastewater, which contains naturally-occurring bacteria. Specifically, the first carbon source is selected to increase the carbon-to-nitrogen ratio and the carbon-to-phosphorous ratio within the microalgae. The first carbon source serves as a food source for the microalgae, and the second carbon source promotes the breakdown of carbon nitrogen and phosphorous by the bacteria cells into a more easily digestible form for the microalgae. Due to the added carbon, the wastewater supports growth of the microalgae and the production of oils therein.
Abstract:
The present invention provides a liquid fuel composition comprising a distillation fraction of a component having at least one C4+ compound derived from a water-soluble oxygenated hydrocarbon prepared by a method comprising: providing water and a water-soluble oxygenated hydrocarbon comprising a C1+O1+ hydrocarbon in an aqueous liquid phase and/or a vapor phase; providing H2; catalytically reacting in the liquid and/or vapor phase the oxygenated hydrocarbon with the H2 in the presence of a deoxygenation catalyst at a deoxygenation temperature and deoxygenation pressure to produce an oxygenate comprising a C1+O1-3 hydrocarbon in a reaction stream; and catalytically reacting in the liquid and/or vapor phase the oxygenate in the presence of a condensation catalyst at a condensation temperature and condensation pressure to produce the C4+ compound, wherein the C4+ compound comprises a member selected from the group consisting of C4+ alcohol, C4+ ketone, C4+ alkane, C4+ alkene, C5+ cycloalkane, C5+ cycloalkene, aryl, fused aryl, and a mixture thereof; wherein the liquid fuel composition is selected from: a gasoline composition having an initial boiling point in the range of from 15° C. to 70° C. (IP123), a final boiling point of at most 230° C. (IP123), a RON in the range of from 85 to 110 (ASTM D2699) and a MON in the range of from 75 to 100 (ASTM D2700); a diesel fuel composition having an initial boiling point in the range of from 130° C. to 230° C. (IP123), a final boiling point of at most 410° C. (IP123) and a cetane number in the range of from 35 to 120 (ASTM D613); and a kerosene composition having an initial boiling point in the range of from 80 to 150° C., a final boiling point in the range of from 200 to 320° C. and a viscosity at −20° C. in the range of from 0.8 to 10 mm2/s (ASTM D445).
Abstract:
The present invention relates to a process of obtainment of aviation biokerosene and a composition of aviation kerosene containing the aviation biokerosene thus produced. The process consists of simultaneously combining three basic conditions: raw material selection, processing conditions, and control of specific properties of the product. The composition is classified as a semisynthetic composition of aviation kerosene and may contain up to 20% by weight of aviation biokerosene, satisfying the limits determined in the international specifications for aviation kerosene.
Abstract:
Mixed alcohol formulas can be used as a fuel additive in petroleum-based hydrocarbon liquid fuels, synthetic or bio-derived gasoline, diesel fuels, jet fuel, aviation gasoline, heating oil, bunker oil, coal, petroleum coke, heavy crude oil, bitumen, or as a neat fuel in and of itself. The mixed alcohol formulations can be blended with ground petroleum coke, coal, heavy crude oil, or bitumen to form a thixotropic slurry for ease of transportation. The mixed alcohol formulations can also be used to shurry transport ground biomass. The mixed alcohol formulations can contain a blend of C1-C5 alcohols, or C1-C8 alcohols or higher C1-C10 alcohols in order to further boost energy content.