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    Block oligomers containing 1-hydrocarbyloxy-2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials
    171.
    发明授权
    Block oligomers containing 1-hydrocarbyloxy-2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials 有权
    含有1-烃氧基-2,2,6,6-四甲基-4-哌啶基的嵌段低聚物作为有机材料的稳定剂

    公开(公告)号：US06409941B1

    公开(公告)日：2002-06-25

    申请号：US09424141

    申请日：1999-11-18

    Applicant: James Peter Galbo ,  Nicola Lelli ,  Valerio Borzatta ,  Jean-Pierre Wolf ,  Michael Ackerman ,  Piero Piccinelli

    Inventor： James Peter Galbo ,  Nicola Lelli ,  Valerio Borzatta ,  Jean-Pierre Wolf ,  Michael Ackerman ,  Piero Piccinelli

    IPC: C07D40112

    CPC classification number: C07D401/14 ,  C08G73/0644 ,  C08K5/34926 ,  C08L23/02 ,  C08L79/02 ,  C08L2201/08 ,  C08L2666/20

    Abstract: A product obtainable by transferring groups of formula (G-I) being present in a block oligomer having a polydispersity {overscore (M)}w/{overscore (M)}n of 1 to 1.7 and corresponding to formula (I) to groups of formula (Gu-II), wherein R1 is a hydrocarbyl radical or —O—R1 is oxyl; said transfer is carried out by reaction of the block oligomer with a hydroperoxide in a hydrocarbon solvent in the presence of a peroxide decomposing catalyst; n is a number from 2 to 14; R2 is for example C2-C12alkylene; A is for example —N(R4)(R5); R4 and R5 are for example C1-C18alkyl; R is preferably a group of formula (G-I) and B and B* have one of the meanings given for A; with the proviso that in the individual recurrent units of formula (I), each of the radicals B, R and R2 has the same or a different meaning. The products are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.

    Abstract translation: 通过将具有多分散性（超核（M）} w / {超核（M）} n为1〜1.7，对应于式（I）的嵌段齐聚物中的式（GI） （Gu-II），其中R1是烃基或-O-R1是氧基; 所述转移通过在过氧化物分解催化剂存在下在烃溶剂中使嵌段低聚物与氢过氧化物反应来进行; n是从2到14的数字; R2是例如C 2 -C 12亚烷基; A是例如-N（R4）（R5）; R4和R5是例如C1-C18烷基; R优选为式（G-I）的基团，而B和B *具有对A给出的含义之一; 条件是在式（I）的各个反复单元中，基团B，R和R 2各自具有相同或不同的含义。 该产品可用作有机材料的光稳定剂，热稳定剂和氧化稳定剂，特别是合成聚合物。

    Stabilized metallocene polypropylene
    172.
    发明申请
    Stabilized metallocene polypropylene 有权
    稳定的茂金属聚丙烯

    公开(公告)号：US20020077394A1

    公开(公告)日：2002-06-20

    申请号：US09973425

    申请日：2001-10-09

    Inventor： Francois Gugumus ,  Nicola Lelli

    IPC: C08K005/34

    CPC classification number: C08K5/34926 ,  C08L23/10 ,  C08L2201/08 ,  C08L2314/06 ,  C08L2666/20

    Abstract: A composition containing polypropylene prepared by polymerization over a metallocene catalyst or a polypropylene copolymer prepared by polymerization over a metallocene catalyst, and a stabilizer mixture comprising (A) for example the compound of the formula (A-I-1-a) 1 wherein n1 is a number from 2 to 20; and (B) for example the compound of the formula (B-I-2-a). 2

    Abstract translation: 通过在金属茂催化剂上聚合制备的聚丙烯组合物或通过在金属茂催化剂上聚合制备的聚丙烯共聚物，和包含（A）例如其中n1为数 从2到20; 和（B）例如式（B-I-2-a）的化合物。

    Polyolefin composition resistant to high energy radiation, and articles produced therefrom
    173.
    发明授权
    Polyolefin composition resistant to high energy radiation, and articles produced therefrom 失效
    耐高能辐射的聚烯烃组合物，以及由其制造的制品

    公开(公告)号：US6017986A

    公开(公告)日：2000-01-25

    申请号：US841014

    申请日：1997-04-29

    Applicant: Lester P. J. Burton

    Inventor： Lester P. J. Burton

    IPC: C08K5/01 ,  C08K5/00 ,  C08K5/17 ,  C08K5/20 ,  C08L9/00 ,  C08L23/02 ,  C08L23/10 ,  C08L23/12 ,  C08L23/16 ,  C08L89/00 ,  C08L91/00 ,  D01F1/02 ,  D01F6/06 ,  C08K5/10

    CPC classification number: C08K5/0016 ,  C08L23/10 ,  C08L23/12 ,  D01F1/106 ,  D01F6/04 ,  C08L2201/08 ,  C08L23/16 ,  C08L9/00 ,  C08L91/00

    Abstract: A radiation-resistant polyolefin composition which includes (i) a polyolefin; and (ii) a radiation-stabilizing amount of at least one aliphatic, unsaturated compound having at least one unsaturation site, the compound having a molecular weight of at least 200 and an iodine number of at least 25. Suitable aliphatic, unsaturated compounds include soybean oil, safflower oil, squalene, polybutadiene, a tertiary amine having at least one aliphatic, unsaturated fatty-acid-derived substituent, oleamide, calcium oleate, erucyl erucamide and glycerol monooleate. A saturated mobilizing compound is preferably included in the composition, which can advantageously be used in the manufacture of fibers, films, and medical devices such as syringes, tube assemblies, tissue culture flasks, and packaging film.

    Abstract translation: 耐辐射聚烯烃组合物，其包含（i）聚烯烃; 和（ii）辐射稳定量的至少一种具有至少一个不饱和位点的脂族不饱和化合物，所述化合物具有至少200的分子量和至少25的碘。合适的脂族不饱和化合物包括大豆 油，红花油，角鲨烯，聚丁二烯，具有至少一种脂肪族，不饱和脂肪酸衍生取代基的叔胺，油酰胺，油酸钙，芥酸酰基芥酸酰胺和甘油单油酸酯。 组合物中优选含有饱和动员化合物，其可有利地用于纤维，膜和医疗装置如注射器，管组件，组织培养瓶和包装膜的制造中。

    Polysiloxane light stabilizers
    174.
    发明授权
    Polysiloxane light stabilizers 失效
    聚硅氧烷光稳定剂

    公开(公告)号：US5837792A

    公开(公告)日：1998-11-17

    申请号：US662578

    申请日：1996-06-13

    Applicant: Roger Meuwly ,  Andreas Valet

    Inventor： Roger Meuwly ,  Andreas Valet

    IPC: C08K5/17 ,  C08G77/26 ,  C08G77/28 ,  C08G77/38 ,  C08G77/388 ,  C08K5/3472 ,  C08K5/3475 ,  C08K5/3477 ,  C08K5/3492 ,  C08K5/544 ,  C08L101/00

    CPC classification number: C08K5/5442 ,  C08G77/388 ,  C08L101/00 ,  C08L2201/08

    Abstract: Oligomeric or polymeric siloxanes of the formula I ##STR1## if X is a monovalent radical, or which are correspondingly crosslinked, if X is a polyvalent radical, whose repeating units are arranged randomly or in blocks, which contain hydroxy-phenyl-diaryl-s-triazine moieties, are useful as stabilizers for organic material against damage thereto by light, oxygen and heat; and especially as stabilizers for coating materials.

    Abstract translation: 如果X是一价基团，或者如果X是多价基团，则它们相应地交联，其重复单元是随机或嵌段排列的，其中含有羟基苯基 - 苯基的式I（I）的低聚或聚合硅氧烷， 二芳基-s-三嗪部分可用作有机材料的稳定剂，以防止其受光，氧和热的损害; 特别是作为涂料的稳定剂。

    Piperidine polymers and use thereof as stabilizers
    180.
    发明授权
    Piperidine polymers and use thereof as stabilizers 失效
    哌啶聚合物及其用作稳定剂

    公开(公告)号：US4413075A

    公开(公告)日：1983-11-01

    申请号：US358487

    申请日：1982-03-15

    Applicant: Piero Di Battista

    Inventor： Piero Di Battista

    IPC: C07D211/48 ,  C08G65/00 ,  C08G65/22 ,  C08K5/3435 ,  C08L1/00 ,  C08L23/00 ,  C08L23/02 ,  C08L27/00 ,  C08L27/04 ,  C08L71/00 ,  C08L77/00 ,  C08L101/00 ,  C07D401/12 ,  C08K5/34

    CPC classification number: C08K5/3435 ,  C08G65/22 ,  C08L101/00 ,  C08L2201/08

    Abstract: There are disclosed new polymers of piperidine having the general formula: ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4, each independently of the others, are an alkyl radical having 1 to 4 C, or R.sub.1 and R.sub.2, and/or R.sub.3 and R.sub.4 form a cycloalkylene radical having 3 to 12 C, R.sub.5 is hydrogen, an alkyl, hydroxyalkyl or alkyl-oxy radical having 1 to 6 C, or an aryl or an aryl-alkyl radical having 6 to 18 C, an alkenyl radical having 2 to 6 C or a --(CH.sub.2).sub.X --CO.sub.2 --R.sub.7 radical in which X is a number from 0 to 12, and R.sub.7 =H, a metal, an alkyl, alkylene, alkenyl, alkenylene radical containing 1 to 20 C; R.sub.6 =H or an alkyl having 1 to 4 C and n is an integer from 2 to 100.Use of the piperidine polymers having general formula (I) as stabilizers of polymeric substances, and polymeric compositions stabilized with said piperidine derivatives are also disclosed.

    Abstract translation: 公开了具有以下通式的新的具有以下通式的哌啶聚合物：其中R 1，R 2，R 3，R 4各自独立地为具有1至4个碳原子的烷基，或R 1和R 2，和/或R 3 并且R 4形成具有3至12个碳的亚环烷基，R 5是氢，具有1-6个碳原子的烷基，羟基烷基或烷基 - 氧基，或具有6-18个碳原子的芳基或芳基 - 烷基， 2至6个C或 - （CH 2）X -CO 2 R 7基团，其中X为0至12的数，R7 = H，含有1至20个C的金属，烷基，亚烷基，烯基，亚烯基; R6 = H或具有1至4℃的烷基，n为2至100的整数。还公开了具有通式（I）的哌啶聚合物作为聚合物质的稳定剂的用途，以及用所述哌啶衍生物稳定的聚合物组合物。

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