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    Solid oxide fuel cell(SOFC) for coproducing syngas and electricity by the internal reforming of carbon dioxide by hydrocarbons and electrochemical membrane reactor system
    14.
    发明申请
    Solid oxide fuel cell(SOFC) for coproducing syngas and electricity by the internal reforming of carbon dioxide by hydrocarbons and electrochemical membrane reactor system 审中-公开
    通过碳氢化合物和电化学膜反应器系统通过二氧化碳的内部重整来共同生产合成气和电力的固体氧化物燃料电池（SOFC）

    公开(公告)号：US20090061078A1

    公开(公告)日：2009-03-05

    申请号：US12222478

    申请日：2008-08-11

    Applicant: Dong Ju Moon ,  Jong Woo Ryu ,  Jong Min Park ,  Byung Gwon Lee ,  Sang Deuk Lee

    Inventor： Dong Ju Moon ,  Jong Woo Ryu ,  Jong Min Park ,  Byung Gwon Lee ,  Sang Deuk Lee

    IPC: B05D5/12

    CPC classification number: H01M4/9066 ,  H01M4/8621 ,  H01M4/8885 ,  H01M4/90 ,  H01M4/9033

    Abstract: The present invention relates to a solid oxide fuel cell for internal reforming of hydrocarbons and carbon dioxide, in particular, to a solid oxide fuel cell in which one side of solid oxide electrolyte (YSZ) is attached to an air electrode (La0.8Sr0.2MnO3) and its other side is attached to a catalyst electrode of Ni-YSZ type or perovskite type metal oxide. The electrochemical conversion system using the solid oxide fuel cell permits the occurrence of internal reforming of hydrocarbons and carbon dioxide concomitantly with the coproduction of a syngas and electricity, and overcomes the shortcomings associated with the catalytic deactivation due to carbon deposition and the high-energy consumption.

    Abstract translation: 本发明涉及一种用于碳氢化合物和二氧化碳的内部重整的固体氧化物燃料电池，特别是固体氧化物燃料电池，其中固体氧化物电解质（YSZ）的一侧附着到空气电极（La0.8Sr0。 2MnO3），其另一面附着在Ni-YSZ型或钙钛矿型金属氧化物的催化剂电极上。 使用固体氧化物燃料电池的电化学转化系统允许在合成气和电力的共同生成的同时发生碳氢化合物和二氧化碳的内部重整，并且克服了由于碳沉积和高能量消耗引起的催化失活相关的缺点 。

    Solid oxide fuel cell(SOFC) for coproducing syngas and electricity by the internal reforming of carbon dioxide by hydrocarbons and electrochemical membrane reactor system
    15.
    发明授权
    Solid oxide fuel cell(SOFC) for coproducing syngas and electricity by the internal reforming of carbon dioxide by hydrocarbons and electrochemical membrane reactor system 失效
    通过碳氢化合物和电化学膜反应器系统通过二氧化碳的内部重整来共同生产合成气和电力的固体氧化物燃料电池（SOFC）

    公开(公告)号：US07410717B2

    公开(公告)日：2008-08-12

    申请号：US10830225

    申请日：2004-04-23

    Applicant: Dong Ju Moon ,  Jong Woo Ryu ,  Jong Min Park ,  Byung Gwon Lee ,  Sang Deuk Lee

    Inventor： Dong Ju Moon ,  Jong Woo Ryu ,  Jong Min Park ,  Byung Gwon Lee ,  Sang Deuk Lee

    IPC: H01M8/10 ,  H01M4/86 ,  H01M4/90 ,  H01M8/04

    CPC classification number: H01M4/9066 ,  H01M4/8621 ,  H01M4/8885 ,  H01M4/90 ,  H01M4/9033

    Abstract: The present invention relates to a solid oxide fuel cell for internal reforming of hydrocarbons and carbon dioxide, in particular, to a solid oxide fuel cell in which one side of solid oxide electrolyte (YSZ) is attached to an air electrode (La0.8Sr0.2MnO3) and its other side is attached to a catalyst electrode of Ni-YSZ type or perovskite type metal oxide. The electrochemical conversion system using the solid oxide fuel cell permits the occurrence of internal reforming of hydrocarbons and carbon dioxide concomitantly with the coproduction of a syngas and electricity, and overcomes the shortcomings associated with the catalytic deactivation due to carbon deposition and the high-energy consumption.

    Abstract translation: 本发明涉及一种用于碳氢化合物和二氧化碳的内部重整的固体氧化物燃料电池，特别涉及一种固体氧化物燃料电池，其中固体氧化物电解质（YSZ）的一侧连接到空气电极（La 0.8 Sr 2 O 2 MnO 3 3），其另一面与Ni-YSZ型或钙钛矿型金属氧化物的催化剂电极连接。 使用固体氧化物燃料电池的电化学转化系统允许在合成气和电力的共同生成的同时发生碳氢化合物和二氧化碳的内部重整，并且克服了由于碳沉积和高能量消耗引起的催化失活相关的缺点 。

    Method for producing nitrogen trifluoride using jet-loop reactors
    16.
    发明授权
    Method for producing nitrogen trifluoride using jet-loop reactors 失效
    使用喷射环流反应器生产三氟化氮的方法

    公开(公告)号：US07083773B2

    公开(公告)日：2006-08-01

    申请号：US10620902

    申请日：2003-07-16

    Applicant: Young-soo Kwon ,  Hong-gon Kim ,  Sang-deuk Lee ,  Jae-woo Lee ,  Jong-yev Hong ,  Hyung-sik Lim ,  Byoung-sung Ahn

    Inventor： Young-soo Kwon ,  Hong-gon Kim ,  Sang-deuk Lee ,  Jae-woo Lee ,  Jong-yev Hong ,  Hyung-sik Lim ,  Byoung-sung Ahn

    IPC: C01B21/06

    CPC classification number: C01C1/162 ,  C01B21/0835

    Abstract: Nitrogen trifluoride is produced with a high yield by the method comprising forming a fast stream of micro droplets of a fused ammonium fluoride salt by rapidly ejecting the fused ammonium fluoride salt into a reactor through a nozzle while circulating the fused ammonium fluoride salt in the reactor from a lower portion to an upper portion; and contacting micro droplets of the fused ammonium fluoride salt with fluorine gas sucked in the reactor through a suction pipe for fluorine by a negative pressure formed around the nozzle due to an ejection of the fused ammonium fluoride salt, whereby excessive generation and regional accumulation of the heat of reaction are prevented, reducing the reaction temperature by 10˜30° C. compared with those of the existing methods, and a side reaction occurs only to a slight extent according to the lowered reaction temperature.

    Abstract translation: 通过以下方法制备三氟化氮，该方法包括通过将熔融氟化铵盐快速喷射到反应器中，同时使熔融氟化铵盐在反应器中循环而形成快速的熔融氟化铵盐的微滴流 下部到上部; 并且由于熔融氟化铵铵的喷射，熔融氟化铵盐的微滴与吸附在反应器中的氟气通过由喷嘴形成的负压而通过氟吸附管接触，由此过度产生和区域积累 防止反应热，与现有方法相比，将反应温度降低10〜30℃，根据降低的反应温度仅发生副反应的轻微反应。

    Simultaneous preparation of tetrafluoroethylene and hexafluoropropylene
    17.
    发明授权
    Simultaneous preparation of tetrafluoroethylene and hexafluoropropylene 失效
    同时制备四氟乙烯和六氟丙烯

    公开(公告)号：US06924402B2

    公开(公告)日：2005-08-02

    申请号：US10414740

    申请日：2003-04-16

    Applicant: Dong Ju Moon ,  Jung Jo Jung ,  Yong Joon Lee ,  Sang Deuk Lee ,  Byoung Sung Ahn

    Inventor： Dong Ju Moon ,  Jung Jo Jung ,  Yong Joon Lee ,  Sang Deuk Lee ,  Byoung Sung Ahn

    IPC: C07C17/269 ,  C07C17/02 ,  C07C17/00 ,  C07C17/04 ,  C07C17/08 ,  C07C21/18

    CPC classification number: C07C17/269 ,  C07C21/185 ,  C07C21/18

    Abstract: The present invention relates to a process for simultaneously preparing tetrafluoroethylene and hexafluoropropylene by the pyrolysis of difluorochloromethane mixed in the molar ratio of super-heated steam/pre-heated difluorochloromethane ([H2O]/[R22]) of 5-10 under the conditions such as a temperature of 730° C. to 760° C. and a residence time of 0.01 to 0.2 seconds, where the unreacted R22 and produced HFP are recycled and controlled to have an appropriate molar ratio of HFP/R22 of 0.01 to 0.1 in order to obtain a high yield of HFP. Thus, the pyrolysis process of the present invention is efficient for preparing TFE and HFP, which are essential monomers in fluorinated resin industry.

    Abstract translation: 本发明涉及一种通过以过热蒸汽/预热二氟氯甲烷（[H 2 O 2] / [R 22]的摩尔比）混合的二氟氯甲烷的热解同时制备四氟乙烯和六氟丙烯的方法， ）为5-10，在730℃至760℃的温度和停留时间为0.01至0.2秒的条件下，将未反应的R22和所制备的HFP循环并控制为具有适当的摩尔比 HFP / R22为0.01〜0.1，以获得高产量的HFP。 因此，本发明的热解方法对于制备作为氟树脂工业中必需单体的TFE和HFP是有效的。

    Refrigerant mixtures containing difluoromethane (HFC-32), pentafluoroethane (HFC-125) and 1,1,1,2-Tetrafluoroethane (HFC-134a)
    18.
    发明授权
    Refrigerant mixtures containing difluoromethane (HFC-32), pentafluoroethane (HFC-125) and 1,1,1,2-Tetrafluoroethane (HFC-134a) 失效
    含有二氟甲烷（HFC-32），五氟乙烷（HFC-125）和1,1,1,2-四氟乙烷（HFC-134a）的制冷剂混合物，

    公开(公告)号：US06508950B1

    公开(公告)日：2003-01-21

    申请号：US09692189

    申请日：2000-10-20

    Applicant: Jong-Sung Lim ,  Byung-Gwon Lee ,  Jae-Duck Kim ,  Sang-Deuk Lee ,  Hoon-Sik Kim

    Inventor： Jong-Sung Lim ,  Byung-Gwon Lee ,  Jae-Duck Kim ,  Sang-Deuk Lee ,  Hoon-Sik Kim

    IPC: C09K504

    CPC classification number: C09K5/045 ,  C09K2205/12 ,  C09K2205/43

    Abstract: The present invention relates to novel refrigerant mixtures as a substitute for chlorodifluoromethane (CHClF2, HCFC-22). More specifically, the invention is directed to refrigerant mixtures that comprise: difluoromethane (CH2F2, HFC-32) as the first component; pentafluoroethane (CHF2CF3, HFC-125) as the second component; 1,1,1,2-tetrafluoroethane (CH2FCF3, HFC-134a) as the third component; any one of cyclopropane (C3H6, RC-270), 1,1-difluoroethane (CH3CHF2, HFC-152a), 1,1,1,2,3,3,3-heptafluoropropane (CF3CHFCF3, HFC-227ea), 1,1,1,2,2-pentafluoropropane (CH3CF2CF3, HFC-245cb), octafluorocyclobutane (C4F8, RC-318), 1,1,1,2,3,3-hexafluoropropane (CHF2CHFCF3, HFC-236ea), bis(difluoromethyl)ether (CHF2OCHF2, HFE-134), pentafluoroethylmethylether (CF3CF2OCH3, HFE-245), n-pentane (C5H12, R-601) and isopentane ((CH3)2CHCH2CH3, R-601a) as the fourth component. The refrigerant mixtures of the invention have working effects equal to that of HCFC-22 but does not have the risk of causing destruction to the ozone layer and can therefore be used as alternative refrigerants to HCFC-22.

    Abstract translation: 本发明涉及作为氯二氟甲烷（CHClF 2，HCFC-22）的替代物的新型制冷剂混合物。 更具体地说，本发明涉及制冷剂混合物，其包含：作为第一组分的二氟甲烷（CH 2 F 2，HFC-32）;作为第二组分的五氟乙烷（CHF 2 CF 3，HFC-125）; 1,1,1,2-四氟乙烷 ，HFC-134a）作为第三成分;环丙烷（C 3 H 6，RC-270），1,1-二氟乙烷（CH 3 CHF 2，HFC-152a），1,1,1,2,3,3,3-七氟丙烷 （CF 3 CHFCF 3，HFC-227ea），1,1,1,2,2-五氟丙烷（CH 3 CF 2 CF 3，HFC-245cb），八氟环丁烷（C 4 F 8，RC-318），1,1,1,2,3,3-六氟丙烷 CHF2CHFCF3，HFC-236ea），双（二氟甲基）醚（CHF2OCHF2，HFE-134），五氟乙基甲基醚（CF3CF2OCH3，HFE-245），正戊烷（C5H12，R-601）和异戊烷（（CH 3）2CHCH2CH3，R-601a ）作为第四个组成部分。 本发明的制冷剂混合物具有与HCFC-22相当的工作效果，但不具有对臭氧层造成破坏的风险，因此可用作HCFC-22的替代制冷剂。

    Process for preparing n,n'-disubstituted urea using selenium-based catalyst
    19.
    发明授权
    Process for preparing n,n'-disubstituted urea using selenium-based catalyst 有权
    使用硒基催化剂制备n，n'-二取代脲的方法

    公开(公告)号：US6127575A

    公开(公告)日：2000-10-03

    申请号：US395388

    申请日：1999-09-13

    Applicant: Hoon Sik Kim ,  Yong Jin Kim ,  Hyun Joo Lee ,  Moon Jo Chung ,  Sang Deuk Lee

    Inventor： Hoon Sik Kim ,  Yong Jin Kim ,  Hyun Joo Lee ,  Moon Jo Chung ,  Sang Deuk Lee

    IPC: C07C273/04 ,  C07C273/18 ,  C07C275/06 ,  C07C275/18 ,  C07C275/24 ,  C07C273/00

    CPC classification number: C07C273/1809 ,  C07C2101/14

    Abstract: A process is disclosed for preparing N,N'-disubstituted urea by reacting an amine and CO/O.sub.2 mixture gas in the presence of a catalyst system comprising at least one selenium compound selected from SeO.sub.2, (CH.sub.3 O)Se(O)(OH) and (CH.sub.3 CH.sub.2 O)Se(O)(OH), and M.sub.2 CO.sub.3 (M=alkali metal) as a co-catalyst. The process enables less active aromatic amine with a low reactivity as well as an aliphatic amine to be easily transformed into disubstituted urea avoiding the use of expensive precious metal catalysts.

    Abstract translation: 公开了一种通过在包含至少一种选自SeO 2，（CH 3 O）Se（O）（OH））的硒化合物的催化剂体系存在下使胺和CO / O 2混合气体反应来制备N，N'-二取代的脲的方法， 和（CH 3 CH 2 O）Se（O）（OH）和作为助催化剂的M2CO3（M =碱金属）。 该方法使得具有低反应性的较少活性的芳族胺以及脂族胺易于转化为二取代的脲，避免使用昂贵的贵金属催化剂。

    Method for preparation of carbamates
    20.
    发明授权
    Method for preparation of carbamates 失效
    氨基甲酸酯的制备方法

    公开(公告)号：US5962721A

    公开(公告)日：1999-10-05

    申请号：US69285

    申请日：1998-04-29

    Applicant: Hoon Sik Kim ,  Sang Deuk Lee ,  Hyun-joo Lee ,  In-Seok Seo ,  Yong Jin Kim

    Inventor： Hoon Sik Kim ,  Sang Deuk Lee ,  Hyun-joo Lee ,  In-Seok Seo ,  Yong Jin Kim

    IPC: C07C269/04 ,  C07C271/24 ,  C07C271/28 ,  C07C271/36 ,  C07C261/00

    CPC classification number: C07C269/04

    Abstract: A method of preparing carbamates by reacting amine with alcohol and mixed gas of CO/O.sub.2 in the presence of one or more catalyst selected from the group consisting of monovalent copper halide having the structural formula of Cu�NCMe.sub.4 !X, K�CuX.sub.2 !, �CuX(S)! (wherein X=Cl, Br, or I; S=solvent) or monovalent copper compound having carbonyl group having the structural formula of �Cu(CO)X.sub.a L.sub.b !.sub.m Y.sub.n (wherein, X=CF.sub.3 CO.sub.2, Cl, HB(pz).sub.3 (wherein, pz=pyrazoyl,C.sub.3 H.sub.3 N.sub.2), LBF.sub.2, {LBF.sub.2 =difluoro-3,3'-(trimethylenedinitrilo)bis(2-butanone oximato)borate}; L=en, diene; Y=BPh.sub.4, AsF.sub.6 ; a,b=0,1; m=1-4; n=0,1).

    Abstract translation: 在一种或多种催化剂存在下，通过使胺与醇和CO 2 O 2的混合气体反应制备氨基甲酸酯的方法，所述催化剂选自具有结构式为Cu [NCMe4] X，K [CuX2]， [CuX（S）]（其中X = Cl，Br或I; S =溶剂）或具有结构式为[Cu（CO）XaLb] mYn的羰基的一价铜化合物（其中，X = CF 3 CO 2， HB（pz）3（其中，pz =吡唑基，C3H3N2），LBF2，{LBF2 =二氟-3,3' - （三亚甲基二亚硝基）双（2-丁酮肟基）硼酸酯}; L =烯，二烯; Y = BPh4， AsF6; a，b = 0,1; m = 1-4; n = 0,1）。

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