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公开(公告)号:US10300345B2
公开(公告)日:2019-05-28
申请号:US15904497
申请日:2018-02-26
Applicant: Acushnet Company
Inventor: Michael J. Sullivan , Brian Comeau , Douglas S. Goguen , Shawn Ricci , Mark L. Binette , Michael Michalewich
Abstract: Multi-layered golf balls having a core made of a foamed composition, preferably polyurethane foam, are provided. The ball includes a dual-layered core having a foam inner core (center) and surrounding outer core layer. The outer core layer may be made from a non-foamed thermoset material such as polybutadiene rubber. The ball further includes an inner cover, preferably made from an ionomer composition comprising an O/X-type acid copolymer, wherein O is α-olefin, and X is a C3-C8 α,β-ethylenically unsaturated carboxylic acid. The outer cover may be made from a non-foamed thermoset or thermoplastic material such as polyurethane. Preferably, the specific gravity of the inner cover is greater than the specific gravity of the outer core, which is greater than the specific gravity of the inner core. The finished ball has good distance and low-spin properties.
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公开(公告)号:US10183198B2
公开(公告)日:2019-01-22
申请号:US15918129
申请日:2018-03-12
Applicant: Acushnet Company
Inventor: Michael Michalewich , Brian Comeau , Shawn Ricci , Manjari Kuntimaddi , Matthew F. Hogge , Nicholas M. Nardacci , Michael R. Madson
Abstract: Disclosed herein are polyurethane golf ball compositions. The compositions are prepared by adding a UV absorber to a polyol prior to reacting the polyol with an isocyanate to form a prepolymer, which is then reacted with a curing agent to form the polyurethane.
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公开(公告)号:US20180353815A1
公开(公告)日:2018-12-13
申请号:US15618456
申请日:2017-06-09
Applicant: Acushnet Company
Inventor: Shawn Ricci , Brian Comeau , Mark L. Binette
IPC: A63B37/00
CPC classification number: A63B37/0074 , A63B37/0024 , A63B37/0027 , A63B37/0039 , A63B37/0075 , A63B37/0076 , A63B45/00
Abstract: Golf ball comprising cast layer of thermoset polymer mixture having centering time Ct1 and consisting of: (i) a thermoset polymer composition consisting of polyurethane composition, polyurea composition, and/or polyurethane/polyurea hybrid composition; and (ii) a treated fumed silica compound in an amount such that centering time Ct1 is independent of the thermoset polymer mixture's degree of cure and lower than a centering time Ct2 of the thermoset polymer composition (which is dependent on its gel window Gw). The treated fumed silica compound may be surface treated with at least one of polydimethylsiloxane, hexamethyldisilazane, and dimethyldichlorosilane. In some embodiments, delta time Δt1 between a dispensing time Dt1 of the thermoset polymer mixture and centering time Ct1 is less than a delta time Δt2 between Ct1 and centering time Ct2. Centering time Ct1 and dispensing time Dt1 may differ by less than 10 seconds or even by 5 seconds or less.
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公开(公告)号:US10112080B2
公开(公告)日:2018-10-30
申请号:US15141873
申请日:2016-04-29
Applicant: Acushnet Company
Inventor: Michael J. Sullivan , Mark L. Binette , Brian Comeau , Douglas S. Goguen , Michael Michalewich , Shawn Ricci
Abstract: Multi-layered golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The outer core layer is preferably formed from a non-foamed thermoset composition such as polybutadiene rubber. The core layers have different hardness and specific gravity levels. The specific gravity (density) of the foam inner core is preferably less than the density of the outer core layer. The core assembly preferably has a positive hardness gradient extending across the entire assembly. The core structure and resulting ball have relatively good resiliency.
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公开(公告)号:US20180178084A1
公开(公告)日:2018-06-28
申请号:US15904497
申请日:2018-02-26
Applicant: Acushnet Company
Inventor: Michael J. Sullivan , Brian Comeau , Douglas S. Goguen , Shawn Ricci , Mark L. Binette , Michael Michalewich
CPC classification number: A63B37/0076 , A63B37/0039 , A63B37/0043 , A63B37/0045 , A63B37/0047 , A63B37/0058 , A63B37/0062 , A63B37/0064 , A63B37/0066 , A63B37/0091 , A63B37/0092 , A63B37/0094 , A63B45/00 , C08K5/098
Abstract: Multi-layered golf balls having a core made of a foamed composition, preferably polyurethane foam, are provided. The ball includes a dual-layered core having a foam inner core (center) and surrounding outer core layer. The outer core layer may be made from a non-foamed thermoset material such as polybutadiene rubber. The ball further includes an inner cover, preferably made from an ionomer composition comprising an O/X-type acid copolymer, wherein O is α-olefin, and X is a C3-C8 α,β-ethylenically unsaturated carboxylic acid. The outer cover may be made from a non-foamed thermoset or thermoplastic material such as polyurethane. Preferably, the specific gravity of the inner cover is greater than the specific gravity of the outer core, which is greater than the specific gravity of the inner core. The finished ball has good distance and low-spin properties.
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公开(公告)号:US20170312586A1
公开(公告)日:2017-11-02
申请号:US15140613
申请日:2016-04-28
Applicant: Acushnet Company
Inventor: Michael J. Sullivan , Mark L. Binette , Douglas S. Goguen , Brian Comeau , Michael Michalewich , Shawn Ricci , John D. Farrell
CPC classification number: A63B37/0063 , A63B37/0004 , A63B37/0039 , A63B37/004 , A63B37/0044 , A63B37/0045 , A63B37/0047 , A63B37/0051 , A63B37/0058 , A63B37/0064 , A63B37/0066 , A63B37/0076 , A63B37/0091 , A63B37/0092 , A63B45/00 , A63B2037/065
Abstract: Golf balls having a multi-layered core made of a foamed composition are provided. The core assembly preferably includes a foam inner core (center) and surrounding outer core layer. Preferably, a polyurethane foam composition is used to form the foam center. The core layers have different hardness gradients and specific gravity values. The foamed inner core assembly includes a geometric center, outer surface (skin), and thermal barrier layer that helps protect the foamed center region from the negative effects of high temperatures used during the ball-manufacturing process. Non-foamed thermoset materials such as polybutadiene rubber may be used to form the thermal barrier layer. The foam cores have good resiliency, thermal stability, and durability over a wide temperature range. The ball further includes a cover that may be multi-layered.
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公开(公告)号:US20170259124A1
公开(公告)日:2017-09-14
申请号:US15600991
申请日:2017-05-22
Applicant: Acushnet Company
Inventor: Mark L. Binette , Brian Comeau , Michael Michalewich , Shawn Ricci , Michael J. Sullivan , Douglas S. Goguen
CPC classification number: A63B37/0075 , A63B37/0039 , A63B37/0043 , A63B37/0044 , A63B37/0045 , A63B37/0047 , A63B37/0051 , A63B37/0058 , A63B37/0062 , A63B37/0063 , A63B37/0064 , A63B37/0066 , A63B37/0076 , A63B37/0091 , A63B37/0092 , C08L75/04 , C08L75/06 , C08L75/08 , C08L75/14
Abstract: Multi-piece golf balls having a solid core made of a foamed composition and a cover are provided. Preferably, the core is dual-layered having has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition containing mineral filler particulate, for example, nanoclay particles, is used to form the foam center. The concentration of clay particulate is preferably in a range of 0.1 to 60% by weight. The surrounding outer core layer may be made from non-foamed or foamed compositions. For example, polybutadiene rubber or highly neutralized olefin acid copolymers may be used in the outer core layer. The core layers have different hardness gradients and specific gravity values.
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公开(公告)号:US20170246511A1
公开(公告)日:2017-08-31
申请号:US15054222
申请日:2016-02-26
Applicant: Acushnet Company
Inventor: Shawn Ricci , John D. Farrell
CPC classification number: A63B37/0058 , A63B37/0022 , A63B37/0024 , A63B37/0039 , A63B37/0051 , A63B37/0075 , A63B37/0078 , C08G71/04 , C09D175/04
Abstract: A golf ball comprising at least one layer consisting of a non-isocyanate-containing polyurethane composition comprising the reaction product of: at least one amine or polyamine, having an average functionality of 2.0 or greater, and at least one cyclo-carbonate. The amine may be selected for example from the group consisting of: ethylenediamine, hexamethylenediamine, or tris(2-aimnoethyl)amine, or blends thereof; and the polyamine may be selected for example from the group consisting of polyoxypropylene diamines, polyoxypropylene triamines, and combinations thereof. The cyclo-carbonate may comprise for example bis(cyclo-carbonate). Other possible reaction products include: (i) the at least one amine or polyamine and at least one epoxy-cyclo-carbonate oligomer, wherein the non-isocyanate-containing polyurethane composition can be modified with at least one of acrylic or siloxane; or (ii) the at least one amine or polyamine and at least one cyclo-carbonated soybean oil; or (iii) at least one lignin-based polyamine and at least one cyclo-carbonated soybean oil.
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公开(公告)号:US09694244B2
公开(公告)日:2017-07-04
申请号:US14982574
申请日:2015-12-29
Applicant: Acushnet Company
Inventor: Michael J. Sullivan , Mark L. Binette , Brian Comeau , Douglas S. Goguen , Michael Michalewich , Shawn Ricci
CPC classification number: A63B37/0063 , A63B37/0024 , A63B37/0039 , A63B37/0043 , A63B37/0044 , A63B37/0045 , A63B37/0047 , A63B37/0051 , A63B37/0058 , A63B37/0062 , A63B37/0064 , A63B37/0066 , A63B37/0076 , A63B37/0091 , A63B37/0092
Abstract: Multi-layered golf ball core sub-assemblies and the resulting golf balls are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The intermediate core layer is preferably formed from a thermoplastic composition such as an ethylene acid copolymer ionomer resin; and the outer core layer is preferably formed from a thermoset composition such as polybutadiene rubber. The core layers have different hardness and specific gravity levels. The core assembly preferably has a positive hardness gradient extending across the entire assembly. The core structure and resulting ball have relatively good resiliency.
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公开(公告)号:US20170136311A1
公开(公告)日:2017-05-18
申请号:US14943314
申请日:2015-11-17
Applicant: Acushnet Company
Inventor: Mark L. Binette , Brian Comeau , Michael Michalewich , Shawn Ricci
CPC classification number: A63B37/0075 , A63B37/0076 , A63B45/00 , B29C67/24 , B29C67/246 , B29K2075/00 , B29K2105/0005 , B29L2031/546 , C08L83/00
Abstract: Golf ball and method for making it, comprising a first layer that comprises a first polymeric composition and is surrounded by and adjacent to a second layer comprising a second polymeric composition different than the first polymeric composition; with one of these layers further comprising at least one silane-containing adhesion promoter such as organosilanes and/or organosiloxanes throughout in an amount of from about 0.1 wt. % to about 5.0 wt. % of the entire layer. Neither layer is surface treated with at least one silane-containing adhesion promoter. The second layer may be the layer comprising the silane-containing adhesion promoter throughout, surrounded by a third layer that comprises a third polymeric composition that differs from the second polymeric composition and does not incorporate any silane-containing adhesion promoter. Strong interlayer bonding is therefore created both between the second layer and the first layer and between the second layer and the third layer.
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