公开(公告)号：US20230125610A1

公开(公告)日：2023-04-27

申请号：US17907402

申请日：2021-06-08

Applicant: BASF SE

Inventor： Holger TUERK ,  Susanne Carina ENGERT ,  Alexander Michael HAYDL ,  Eugen RISTO

IPC: C08G73/02 ,  C11D3/37

Abstract: Described herein is an amphiphilic alkoxylated polyethylene/-propylene imine copolymer. Also described herein is a process for manufacturing the amphiphilic alkoxylated polyethylene/-propylene imine copolymer and a method of using the amphiphilic alkoxylated polyethylene/-propylene imine copolymer.

公开(公告)号：US20160160158A1

公开(公告)日：2016-06-09

申请号：US14902776

申请日：2014-06-24

Applicant: BASF SE

Inventor： Holger TUERK ,  Heike WEBER ,  Juergen DETERING ,  Gazi TUERKOGLU

IPC: C11D3/37 ,  C11D3/20 ,  A47L15/00 ,  C11D1/72

CPC classification number: C11D3/3757 ,  A47L15/0007 ,  C11D1/72 ,  C11D1/721 ,  C11D3/2082 ,  C11D3/2086 ,  C11D3/33 ,  C11D3/3761 ,  C11D11/0023 ,  C11D17/0091

Abstract: Process for cleaning dishware soiled with fatty residue, characterized in that said process is carried out at a temperature in the range of from 45 to 65° C. and using at least one formulation, comprising (A) in the range of from 1 to 50% by weight of at least one complexing agent, selected from the alkali metal salts of citric acid, aminocarboxylic acids and from sodium tripolyphosphate, (B) in the range of from 2 to 8% by weight of at least one non-ionic surfactant of general formula (I) R1—CH(OH)—CH2—O-(AO)x—R2 (I) (C) in the range of from 0.25 to less than 4% by weight of a copolymer, being obtained from copolymerizing the following comonomers (a) at least one comonomer selected from ethylenically unsaturated C3-C4-carboxylic acids and ethylenically unsaturated C4-C8-dicarboxylic acids or their respective anhydrides, (b) at least one comonomer selected from isobutene, diisobutene, C2-C28-a-olefins, and C12-C24-alkyl esters of (meth)acrylic acid, (c) optionally, at least one further comonomer selected from non-ionic comonomers, the integers being defined as follows: R1 being selected from C4-C30-alkyl, straight-chain or branched, and from C4-C30-alkenyl, straight-chain or branched, with at least one C—C double bond, R2 being selected from C1-C30-alkyl, straight-chain or branched, and from C2-C30-alkenyl, straight-chain or branched, with at least one C—C double bond, x being selected from one to 100, AO being identical or different alkylene oxides, selected from CH2—CH2—O, (CH2)3—O, (CH2)4—O, CH2CH(CH3)—O, CH(CH3)—CH2—O— and CH2CH(n-C3H7)—O.

Abstract translation: 用于清洁用脂肪残渣污染的餐具的方法，其特征在于所述方法在45至65℃的温度下进行，并使用至少一种制剂，其包含（A）为1至50 至少一种选自柠檬酸，氨基羧酸的碱金属盐和三聚磷酸钠的络合剂的重量百分数（B）为2-8重量％的至少一种非离子表面活性剂 通式（I）R 1 -CH（OH）-CH 2 -O-（AO）x -R 2（I）（C）的共聚物的重均分子量为0.25〜小于4重量％ 以下共聚单体（a）至少一种选自烯键式不饱和C 3 -C 4羧酸和烯属不饱和C 4 -C 8 - 二羧酸或它们各自的酸酐的共聚单体，（b）至少一种选自异丁烯，二异丁烯，C 2 -C 28 - α-烯烃和（甲基）丙烯酸的C 12 -C 24烷基酯，（c）任选至少 选自非离子共聚单体的另外的共聚单体，整体定义如下：R 1选自C 4 -C 30 - 烷基，直链或支链，和C 4 -C 30 - 烯基，直链或支链，至少 一个C-C双键，R2选自C 1 -C 30 - 烷基，直链或支链，以及具有至少一个C-C双键的直链或支链C 2 -C 30烯基，x被选择 A 1是相同或不同的选自CH 2 -CH 2 -O，（CH 2）3 -O，（CH 2）4 -O，CH 2 CH（CH 3）-O，CH（CH 3）-CH 2 -O - 和CH 2 CH（n-C 3 H 7）-O。

公开(公告)号：US20150105437A1

公开(公告)日：2015-04-16

申请号：US14519307

申请日：2014-10-21

Applicant: BASF SE

Inventor： Holger TUERK ,  Cedric DIELEMAN ,  Hans-Guenter BOHRMANN ,  Sebastian KOLTZENBURG

IPC: A01N25/10 ,  A01N43/653 ,  A01N47/24 ,  C08F220/18

CPC classification number: A01N25/10 ,  A01N43/653 ,  A01N47/24 ,  C08F2/04 ,  C08F2/06 ,  C08F220/06 ,  C08F220/18 ,  C08F220/56 ,  C08F220/58 ,  A01N2300/00

Abstract: A process for the preparation of random radical copolymers which comprises a) at least one olefinically unsaturated sulfonic acid of the formula (I), where n is 0 to 10; X is O or NR5; R1 is hydrogen or methyl; R2, R3 independently of one another are hydrogen or C1- to C6-alkyl and R5 is hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, it being possible for the aryl radicals to be monosubstituted or polysubstituted, salts thereof or mixtures of acid and salts and b) at least two structurally different olefinically unsaturated monomers of the formula (II), where Y is O or NR7; R5 is hydrogen or methyl; R6 is alkyl, hydroxyalkyl, (di)alkylaminoalkyl or (di)alkylaminoaryl and R7 is hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, it being possible for the aryl radicals to be monosubstituted or polysubstituted, and c) if appropriate, one or more olefinically unsaturated monomers which differ structurally from components (a) and (b), d) at least one initiator being dissolved either (i) in a solvent mixture comprising water and a water-soluble organic solvent with a boiling point of less than 140° C. or (ii) being dissolved in one or more pure alcohols by heating, and being polymerized in solution, where the polymer formed remains in solution. The copolymers which are obtainable by the process are suitable as formulation adjuvants in agrochemical active substance compositions.

Abstract translation: 一种制备无规自由基共聚物的方法，其包括a）至少一种式（I）的烯属不饱和磺酸，其中n为0至10; X是O或NR5; R1是氢或甲基; R 2，R 3彼此独立地是氢或C 1 -C 6 - 烷基，R 5是氢，烷基，芳基，烷基芳基，芳基烷基，烷氧基烷基，芳氧基烷基，烷氧基芳基，羟基烷基，（二）烷基氨基烷基，（二）烷基氨基芳基，（二） 芳基氨基烷基，烷基芳基氨基烷基或烷基芳基氨基芳基，芳基可以是单取代或多取代的，其盐或酸和盐的混合物，以及b）至少两种结构不同的具有式（II）的烯属不饱和单体，其中Y是O或 NR7; R5是氢或甲基; R6是烷基，羟基烷基，（二）烷基氨基烷基或（二）烷基氨基芳基，R7是氢，烷​​基，芳基，烷基芳基，芳基烷基，烷氧基烷基，芳氧基烷基，烷氧基芳基，羟基烷基，（二）烷基氨基烷基，（二）烷基氨基芳基，（二） 烷基芳基氨基烷基或烷基芳基氨基芳基，芳基可以被单取代或多取代，以及c）如果合适的话，一种或多种在结构上与组分（a）和（b）不同的烯属不饱和单体，d）至少一个引发剂 （i）在包含水和沸点小于140℃的水溶性有机溶剂的溶剂混合物中溶解，或（ii）通过加热溶解在一种或多种纯醇中，并在溶液中聚合， 所形成的聚合物保留在溶液中。 可通过该方法获得的共聚物适合作为农药活性物质组合物中的制剂佐剂。