公开(公告)号：US20220115706A1

公开(公告)日：2022-04-14

申请号：US17537149

申请日：2021-11-29

Applicant: Battelle Memorial Institute

Inventor： Xia Cao ,  Ji-Guang Zhang ,  Wu Xu

IPC: H01M10/0569 ,  H01M10/0567 ,  H01M10/0568 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M4/38

Abstract: Electrolytes for lithium ion batteries with carbon-based, silicon-based, or carbon- and silicon-based anodes include a lithium salt; a nonaqueous solvent comprising at least one of the following components: (i) an ester, (ii) a sulfur-containing solvent, (iii) a phosphorus-containing solvent, (iv) an ether, (v) a nitrile, or any combination thereof, wherein the lithium salt is soluble in the solvent; a diluent comprising a fluoroalkyl ether, a fluorinated orthoformate, a fluorinated carbonate, a fluorinated borate, a fluorinated phosphate, a fluorinated phosphite, or any combination thereof, wherein the lithium salt has a solubility in the diluent at least 10 times less than a solubility of the lithium salt in the solvent; and an additive having a different composition than the lithium salt, a different composition than the solvent, and a different composition than the diluent. In some electrolytes, the nonaqueous solvent comprises an ester.

公开(公告)号：US11094966B2

公开(公告)日：2021-08-17

申请号：US16230531

申请日：2018-12-21

Applicant: Battelle Memorial Institute

Inventor： Xiaodi Ren ,  Wu Xu ,  Ji-Guang Zhang

IPC: H01M10/0569 ,  H01M4/133 ,  H01M4/131 ,  H01M10/0525 ,  H01M4/525 ,  H01M4/505 ,  H01M4/134 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0568

Abstract: Disclosed herein are embodiments of an electrolyte that is stable and efficient at high voltages. The electrolyte can be used in combination with certain cathodes that exhibit poor activity at such high voltages with other types of electrolytes and can further be used in combination with a variety of anodes. In some embodiments, the electrolyte can be used in battery systems comprising a lithium cobalt oxide cathode and lithium metal anodes, silicon anodes, silicon/graphite composite anodes, graphite anodes, and the like.

公开(公告)号：US20210218062A1

公开(公告)日：2021-07-15

申请号：US17144600

申请日：2021-01-08

Applicant: Battelle Memorial Institute

Inventor： Wu Xu ,  Ji-Guang Zhang ,  Hao Jia ,  Xianhui Zhang ,  Xia Cao ,  Sujong Chae ,  Ran Yi ,  Qiuyan Li ,  Won-Jin Kwak ,  Xiaolin Li

IPC: H01M10/0568 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M4/525 ,  H01M4/505

Abstract: Electrolytes for lithium ion batteries with carbon-based, silicon-based, or carbon- and silicon-based anodes include a lithium salt; a nonaqueous solvent comprising at least one of the following components: (i) an ester, (ii) a sulfur-containing solvent, (iii) a phosphorus-containing solvent, (iv) an ether, (v) a nitrile, or any combination thereof, wherein the lithium salt is soluble in the solvent; a diluent comprising a fluoroalkyl ether, a fluorinated orthoformate, a fluorinated carbonate, a fluorinated borate, or a combination thereof, wherein the lithium salt has a solubility in the diluent at least 10 times less than a solubility of the lithium salt in the solvent; and an additive having a different composition than the lithium salt, a different composition than the solvent, and a different composition than the diluent.

公开(公告)号：US20190252689A1

公开(公告)日：2019-08-15

申请号：US16337812

申请日：2017-10-11

Applicant: Battelle Memorial Institute

Inventor： Wu Xu ,  Bin Liu ,  Ji-Guang Zhang

IPC: H01M4/88 ,  H01M12/08 ,  H01M4/96 ,  H01M4/38

CPC classification number: H01M4/8878 ,  H01M4/04 ,  H01M4/382 ,  H01M4/88 ,  H01M4/96 ,  H01M12/08 ,  Y02E60/128

Abstract: A one-step in-situ electrochemical pre-charging strategy to generate thin protective films simultaneously on the surfaces of both carbon-based air-electrode and metal anode under an inert atmosphere is disclosed. The thin-films are formed from the decomposition of electrolyte during the in-situ electrochemical pre-charging process in an inert environment and can protect both a carbon air-electrode and a metal anode prior to conventional metal-oxygen discharge/charge cycling where reactive reduced oxygen species are formed. Lithium-oxygen cells after such pre-treatment demonstrate significantly extended cycle life which is far more than those without pre-treatment.

公开(公告)号：US09865900B2

公开(公告)日：2018-01-09

申请号：US14595065

申请日：2015-01-12

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Wu Xu ,  Hongfa Xiang ,  Jiguang Zhang ,  Ruiguo Cao

IPC: H01M10/0567 ,  H01M10/0564 ,  H01M10/0569 ,  H01M10/0525 ,  H01M10/0568 ,  H01M4/04 ,  H01M4/36 ,  H01M4/587

CPC classification number: H01M10/0567 ,  H01M4/0445 ,  H01M4/366 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0028 ,  H01M2300/0037 ,  Y02T10/7011

Abstract: An energy storage device comprising: (A) an anode comprising graphite; and (B) an electrolyte composition comprising: (i) at least one carbonate solvent; (ii) an additive selected from CsPF6, RbPF6, Sr(PF6)2, Ba(PF6)2, or a mixture thereof; and (iii) a lithium salt.

公开(公告)号：US09115435B2

公开(公告)日：2015-08-25

申请号：US13829615

申请日：2013-03-14

Applicant: Battelle Memorial Institute

Inventor： B. Peter McGrail ,  Praveen K. Thallapally ,  Wu Xu

IPC: B01D53/04 ,  B01D53/62 ,  C25B15/00 ,  B01D53/02 ,  B01D53/14 ,  B01D53/32 ,  F23J15/02

CPC classification number: C25B15/00 ,  B01D53/02 ,  B01D53/04 ,  B01D53/1475 ,  B01D53/32 ,  B01D53/326 ,  B01D2253/204 ,  B01D2257/504 ,  B01D2259/40083 ,  F23J15/02 ,  F23J2215/50 ,  F23J2219/60 ,  Y02C10/06 ,  Y02C10/08 ,  Y02E20/326 ,  Y02P20/152

Abstract: Methods for releasing associated guest materials from a metal organic framework are provided. Methods for associating guest materials with a metal organic framework are also provided. Methods are provided for selectively associating or dissociating guest materials with a metal organic framework. Systems for associating or dissociating guest materials within a series of metal organic frameworks are provided. Gas separation assemblies are provided.

Abstract translation: 提供了从金属有机骨架释放相关客体材料的方法。 还提供了将客体材料与金属有机骨架相关联的方法。 提供了用于选择性地将客体材料与金属有机骨架结合或解离的方法。 提供了一系列用于在一系列金属有机骨架内缔合或解离客体材料的系统。 提供气体分离组件。

公开(公告)号：US20130199940A1

公开(公告)日：2013-08-08

申请号：US13829615

申请日：2013-03-14

Applicant: Battelle Memorial Institute

Inventor： B. Peter McGrail ,  Praveen K. Thallapally ,  Wu Xu

IPC: C25B15/00

CPC classification number: C25B15/00 ,  B01D53/02 ,  B01D53/04 ,  B01D53/1475 ,  B01D53/32 ,  B01D53/326 ,  B01D2253/204 ,  B01D2257/504 ,  B01D2259/40083 ,  F23J15/02 ,  F23J2215/50 ,  F23J2219/60 ,  Y02C10/06 ,  Y02C10/08 ,  Y02E20/326 ,  Y02P20/152

Abstract: Methods for releasing associated guest materials from a metal organic framework are provided. Methods for associating guest materials with a metal organic framework are also provided. Methods are provided for selectively associating or dissociating guest materials with a metal organic framework. Systems for associating or dissociating guest materials within a series of metal organic frameworks are provided. Gas separation assemblies are provided.

Abstract translation: 提供了从金属有机骨架释放相关客体材料的方法。 还提供了将客体材料与金属有机骨架相关联的方法。 提供了用于选择性地将客体材料与金属有机骨架结合或解离的方法。 提供了用于在一系列金属有机骨架内缔合或解离客体材料的系统。 提供气体分离组件。

公开(公告)号：US12087910B2

公开(公告)日：2024-09-10

申请号：US18326738

申请日：2023-05-31

Applicant: Battelle Memorial Institute

Inventor： Xia Cao ,  Ji-Guang Zhang ,  Wu Xu

IPC: H01M10/0569 ,  H01M4/38 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0567 ,  H01M10/0568

CPC classification number: H01M10/0569 ,  H01M4/386 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0567 ,  H01M10/0568 ,  H01M2300/0042 ,  H01M2300/0051

Abstract: Electrolytes for lithium ion batteries with carbon-based, silicon-based, or carbon- and silicon-based anodes include a lithium salt; a nonaqueous solvent comprising at least one of the following components: (i) an ester, (ii) a sulfur-containing solvent, (iii) a phosphorus-containing solvent, (iv) an ether, (v) a nitrile, or any combination thereof, wherein the lithium salt is soluble in the solvent; a diluent comprising a fluoroalkyl ether, a fluorinated orthoformate, a fluorinated carbonate, a fluorinated borate, a fluorinated phosphate, a fluorinated phosphite, or any combination thereof, wherein the lithium salt has a solubility in the diluent at least 10 times less than a solubility of the lithium salt in the solvent; and an additive having a different composition than the lithium salt, a different composition than the solvent, and a different composition than the diluent. In some electrolytes, the nonaqueous solvent comprises an ester.

公开(公告)号：US20230187697A1

公开(公告)日：2023-06-15

申请号：US18163679

申请日：2023-02-02

Applicant: Battelle Memorial Institute

Inventor： Xia Cao ,  Ji-Guang Zhang ,  Wu Xu

IPC: H01M10/0567 ,  H01M10/0569 ,  H01M10/0525 ,  H01M10/0568

CPC classification number: H01M10/0567 ,  H01M10/0569 ,  H01M10/0525 ,  H01M10/0568 ,  H01M2300/0025

Abstract: Localized superconcentrated electrolytes (LSEs) and electrochemical devices including the LSEs are disclosed. The LSE includes an active salt, a solvent in which the active salt is soluble, and a diluent in which the active salt is insoluble or poorly soluble, wherein the diluent includes a fluorinated orthoformate.

公开(公告)号：US11127980B2

公开(公告)日：2021-09-21

申请号：US16247143

申请日：2019-01-14

Applicant: Battelle Memorial Institute

Inventor： Ji-Guang Zhang ,  Haiping Jia ,  Xiaolin Li ,  Wu Xu

IPC: H01M10/0569 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0567 ,  H01M4/36 ,  H01M4/587 ,  H01M4/62 ,  H01M4/38 ,  H01M4/134 ,  H01M10/42 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525

Abstract: Localized superconcentrated electrolytes (LSEs) for use in systems with silicon-based or carbon/silicon composite-based anodes are disclosed. The LSEs include an active salt, a nonaqueous solvent in which the active salt is soluble, and a diluent in which the active salt has a solubility at least 10 times less than solubility of the active salt in the nonaqueous solvent. Systems including the LSEs also are disclosed.