Synergistic Blends Of Anti-Agglomerant Gas Hydrate Inhibitors With Quaternary Benzyl Ammonium Compounds

    公开(公告)号:US20210179918A1

    公开(公告)日:2021-06-17

    申请号:US17099233

    申请日:2020-11-16

    Abstract: The present disclosure relates to a gas hydrate inhibitor composition comprising an amphiphile having a hydrophobic tail linked to a hydrophilic head group by a linking moiety, the amphiphile having the general formula (1) [R5-L-N(R1)(R2)(R3)]+X−  (1) wherein each of R1 and R2 is independently an alkyl group having from 1 to 5 carbon atoms; or wherein the nitrogen atom and the R1 and R2 groups together form a substituted or unsubstituted heterocyclic group; R3 is present or not as hydrogen or an alkyl group having from 1 to 8 carbon atoms which optionally bears a hydroxy group or a carboxy group in the 2-position; L is a linking moiety comprising an optionally substituted hydrocarbyl group having at least 2 adjacent carbon atoms, at least one heteroatom selected from nitrogen and oxygen, and optionally one or more further heteroatoms; R5 is a hydrocarbyl group having from 6 to 22 carbon atoms; and X− is present as an anion when R3 is present; and a cationic surfactant which is selected from quaternary benzyl ammonium salts having besides the benzyl group at least one C8-C18-alkyl group bound to the nitrogen atom and a method of using the gas hydrate inhibitor composition.

    Method Of And A Composition For Controlling Gas Hydrate Blockage Through The Addition Of A Synergistically Acting Blend With N-Alkanoyl-Polyhydroxyalkylamines

    公开(公告)号:US20210179923A1

    公开(公告)日:2021-06-17

    申请号:US17099560

    申请日:2020-11-16

    Abstract: The present disclosure relates to a gas hydrate inhibitor composition comprising A) a compound according to formula (1) wherein R1 is an alkyl group having from 1 to 5 carbon atoms; R2 is hydrogen or an alkyl group having from 1 to 5 carbon atoms; R3 is present or not as hydrogen and organic moieties having from 1 to 20 carbon atoms; R4 is selected from —(CH2)t-, —[(CH2-CHR6)t]-, —(CH2-CHR6O)u-(CH2)t- and combinations thereof; R5 is an alkyl or alkenyl group having 4 to 22 carbon atoms; R6 is hydrogen or an alkyl group having from 1 to 4 carbon atoms; R7 is hydrogen or an alkyl group having from 1 to 4 carbon atoms; R8 is present or not as hydrogen or organic moieties having from 1 to 20 carbon atoms; t is 2, 3 or 4; u is an integer between 0 and 100; n is 0 or 1 m is 0 or 2 o is 0 or 2 p is 0 or 1 X− is an anion, and and a a synergistic surfactant which is selected from the group consisting of N-acylated polyhydroxyalkylamines and a method of using the gas hydrate inhibitor composition.

    Method Of And A Composition For Controlling Gas Hydrate Blockage Through The Addition Of A Synergistically Acting Blend With A Quaternary Alkyl Ammonium Compound

    公开(公告)号:US20210179917A1

    公开(公告)日:2021-06-17

    申请号:US17099052

    申请日:2020-11-16

    Abstract: The present disclosure relates to a gas hydrate inhibitor composition, comprising A) a compound according to formula (1) wherein R1 is an alkyl group having from 1 to 5 carbon atoms; R2 is hydrogen or an alkyl group having from 1 to 5 carbon atoms; R3 is present or not as hydrogen and organic moieties having from 1 to 20 carbon atoms; R4 is selected from —(CH2)t—, —[CH2—CHR6)t]—, —(CH2—CHR6O)u—(CH2)t— and combinations thereof; R5 is an alkyl or alkenyl group having 4 to 22 carbon atoms; R6 is hydrogen or an alkyl group having from 1 to 4 carbon atoms; R7 is hydrogen or an alkyl group having from 1 to 4 carbon atoms; R8 is present or not as hydrogen or organic moieties having from 1 to 20 carbon atoms; t is 2, 3 or 4; u is an integer between 0 and 100; n is 0 or 1 m is 0 or 2 o is 0 or 2, p is 0 or 1 X− is an anion, and B) a compound that is a synergistic surfactant which comprises an quaternary alkyl ammonium compound.

    Synergistic Blends Of Anti-Agglomerant Gas Hydrate Inhibitors With Quaternary Alkyl Ammonium Compounds

    公开(公告)号:US20210179916A1

    公开(公告)日:2021-06-17

    申请号:US17098982

    申请日:2020-11-16

    Abstract: The present disclosure relates to a gas hydrate inhibitor composition comprising from an amphiphile having a hydrophobic tail linked to a hydrophilic head group by a linking moiety, the amphiphile having the general formula (1) [R5-L-N(R1)(R2)(R3)]+X−  (1) wherein each of R1and R2 is independently an alkyl group having from 1 to 5 carbon atoms; or wherein the nitrogen atom and the R1and R2 groups together form a substituted or unsubstituted heterocyclic group; R3 is present or not as hydrogen or an alkyl group having from 1 to 8 carbon atoms which optionally bears a hydroxy group or a carboxy group in the 2-position; L is a linking moiety comprising an optionally substituted hydrocarbyl group having at least 2 adjacent carbon atoms, at least one heteroatom selected from nitrogen and oxygen, and optionally one or more further heteroatoms; R5 is a hydrocarbyl group having from 6 to 22 carbon atoms; and X− is present as an anion when R3 is present; and from a cationic surfactant which is selected from di(C8-C18 alkyl)dimethyl ammonium salts.

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