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公开(公告)号：US20240254148A1
公开(公告)日：2024-08-01
申请号：US18413176
申请日：2024-01-16
Inventor： Joseph M. Falkowski , Mary S. Abdulkarim , Trong D. Pham , Julie J. Seo
CPC classification number: C07F7/00 , B01J20/226 , C07B2200/13
Abstract: Provided herein are methods of making metal-organic frameworks comprising combining a first pre-ligand and at least one of a second pre-ligand or a first ligand with a metal source comprising a metal component to provide a plurality of reactants where at least 50 wt % of the reaction mixture is the plurality of reactants after solvent has been added to the plurality of reactants. Also provided herein are methods of making metal-organic frameworks comprising combining a pre-ligand with a metal source selected from metal acetates, metal hydroxyacetates, metal carbonates, metal hydroxycarbonates, and mixtures thereof.
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12.发明公开公开(公告)号：US20230287278A1
公开(公告)日：2023-09-14
申请号：US17664177
申请日：2022-05-19
Inventor： Changyub Paek , Joseph M. Falkowski , Yogesh V. Joshi , Carmen C. Lasso
IPC: C10G25/00
CPC classification number: C10G25/003 , C10G2300/1062 , C10G2400/10
Abstract: This disclosure provides methods for separating multi-ring naphthenes from a hydrocarbon feedstock. The hydrocarbon feedstock includes at least normal paraffins, isoparaffins, 1-ring naphthenes attached with a paraffinic alkyl chain, and multi-ring naphthenes. The methods comprise passing the hydrocarbon feedstock and a solvent, at a temperature and pressure through a bed of an adsorbent comprising a metal-organic framework (MOF) adsorbent, to adsorb the multi-ring naphthenes from the hydrocarbon feedstock, thereby producing a base stock product that is depleted in multi-ring naphthenes. The metal-organic framework adsorbent is a porous crystalline material comprised of metal functionalities connected by organic linkers to form a repeating 2-D or 3-D lattice. The base stock product has a viscosity index (VI) greater than the viscosity index of the hydrocarbon feedstock. The methods of this disclosure upgrade Group II base stocks (also Group II+ base stocks) to Group III or Group III+ base stocks, and also upgrade Group III base stocks to Group III+ base stocks.
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公开(公告)号：US11739274B2
公开(公告)日：2023-08-29
申请号：US17634962
申请日：2020-07-14
Inventor： Brandon J. O'Neill , Joseph M. Falkowski , Allen W. Burton , Scott J. Weigel
CPC classification number: C10G47/10 , B01J31/1691 , C10G2300/4006 , C10G2300/4012 , C10G2300/70 , C10G2400/02
Abstract: A hydrocarbon feed stream, particularly one comprising heavier hydrocarbons, may be converted to valuable products such as motor gasoline and/or lubricating oil by employing one or more MOF catalysts, which may be prepared from a precursor metal-organic framework (MOF). A MOF catalyst may be prepared by exchanging one or more organic linking ligands of the precursor MOF for an organic linking ligand having a different acidity and/or electron-withdrawing properties, which, in turn, may affect catalytic activity.
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14.发明授权公开(公告)号：US12203034B2
公开(公告)日：2025-01-21
申请号：US17664177
申请日：2022-05-19
Inventor： Changyub Paek , Joseph M. Falkowski , Yogesh V. Joshi , Carmen C. Lasso
Abstract: This disclosure provides methods for separating multi-ring naphthenes from a hydrocarbon feedstock. The hydrocarbon feedstock includes at least normal paraffins, isoparaffins, 1-ring naphthenes attached with a paraffinic alkyl chain, and multi-ring naphthenes. The methods comprise passing the hydrocarbon feedstock and a solvent, at a temperature and pressure through a bed of an adsorbent comprising a metal-organic framework (MOF) adsorbent, to adsorb the multi-ring naphthenes from the hydrocarbon feedstock, thereby producing a base stock product that is depleted in multi-ring naphthenes. The metal-organic framework adsorbent is a porous crystalline material comprised of metal functionalities connected by organic linkers to form a repeating 2-D or 3-D lattice. The base stock product has a viscosity index (VI) greater than the viscosity index of the hydrocarbon feedstock. The methods of this disclosure upgrade Group II base stocks (also Group II+ base stocks) to Group III or Group III+ base stocks, and also upgrade Group III base stocks to Group III+ base stocks.
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公开(公告)号：US20240261759A1
公开(公告)日：2024-08-08
申请号：US18561646
申请日：2022-05-31
Inventor： Matthew T. Kapelewski , Joseph M. Falkowski , Dominick A. Zurlo , Mary S. Abdulkarim
CPC classification number: B01J20/226 , B01J20/28064 , B01J20/28066 , B01J20/28071 , B01J20/28073 , B01J20/3078 , B01J2531/48
Abstract: Provided are methods of making a MOF UiO-66 comprising reacting zirconium oxychloride with terephthalic acid or derivative thereof and acetic acid in a solvent to provide a reaction solution; diluting the reaction solution with water, heating the diluted reaction solution and reducing the reaction temperature of the reaction mixture to provide the MOF UiO-66 having a micropore volume greater than or equal to 0.45 cc/g and a crystal size of between about 20 nm and about 1000 nm. Also provided are methods of making a MOF UiO-66 where a zirconium hydroxide acetate and zirconium hydroxide are reacted with a carboxylic acid or derivative thereof and acetic acid in a solvent to produce the metal-organic framework MOF UiO-66 having a micropore volume at least 0.35 cc/gram.
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Patent Agency Ranking
公开(公告)号：US12036539B2
公开(公告)日：2024-07-16
申请号：US17621281
申请日：2020-05-28
Inventor： Joseph M. Falkowski , Yogesh V. Joshi , Mary S. Abdulkarim , Simon C. Weston
CPC classification number: B01J31/1691 , B01J35/617 , B01J35/618 , B01J35/633 , B01J35/635 , B01J35/643 , B01J35/647 , B01J37/04 , B01J37/30 , C07C5/03 , C07F3/06 , B01J2231/645 , B01J2531/0205 , B01J2531/0211 , B01J2531/0238 , B01J2531/26 , B01J2531/72 , B01J2531/845 , B01J2531/847 , C07C2531/22
Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers. MOFs having ambient condition stability may comprise a plurality of metal clusters comprising one or more M4O clusters (M is a metal), and a plurality of 4-pyrazolecarboxylate ligands coordinated to the plurality of metal clusters to define an at least partially crystalline network structure having a plurality of internal pores. The MOFs may have a Pa3 symmetry, which upon activation may convert into Fm3m symmetry. Methods for synthesizing the MOFs may comprise combining a metal source, such as a preformed metal cluster, with 4-pyrazolecarboxylic acid, and reacting the preformed metal cluster with the 4-pyrazolecarboxylic acid to form a MOF having an at least partially crystalline network structure with a plurality of internal pores defined therein and comprising a plurality of metal clusters coordinated to a multidentate organic ligand comprising 4-pyrazolecarboxylate.
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公开(公告)号：US20230357650A1
公开(公告)日：2023-11-09
申请号：US17755331
申请日：2020-07-22
Inventor： Changyub Paek , Joseph M. Falkowski , Randall D. Partridge , Yogesh V. Joshi , Carmen C. Lasso
CPC classification number: C10G25/003 , B01J20/226 , B01J20/3475 , B01J20/3425 , C10G25/12 , B01D15/426
Abstract: A process for separating one or more one-ring cycloparaffins and one or more multi-ring cycloparaffins from a hydrocarbon mixture is disclosed. The process comprises the steps of providing the hydrocarbon mixture; and contacting the hydrocarbon mixture with an adsorbent material comprising a metal organic framework to separate the one or more one-ring cycloparaffins and the one or more multi-ring cycloparaffins from the hydrocarbon mixture. The process is conducted in a liquid phase.
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18.发明授权公开(公告)号：US12172146B2
公开(公告)日：2024-12-24
申请号：US17607168
申请日：2020-05-26
Inventor： Joseph M. Falkowski , Yogesh V. Joshi , Mary S. Abdulkarim , Simon C. Weston
Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers, typically as a coordination polymer. Some highly porous MOFs lack stability at ambient conditions. MOFs having ambient condition stability may comprise a plurality of metal clusters (M4O clusters, M=a metal), and a plurality of 4-(1H-pyrazol-4-yl)benzoate ligands coordinated to the plurality of metal clusters to define an at least partially crystalline network structure having a plurality of internal pores. Methods for synthesizing these MOFs may comprise combining a metal source, such as a preformed metal cluster, with 4-(1H-pyrazol-4-yl)benzoic acid, and reacting the preformed metal cluster with the 4-(1H-pyrazol-4-yl)benzoic acid to form a MOF having an at least partially crystalline network structure with a plurality of internal pores defined therein and comprising a plurality of metal clusters coordinated to a multidentate organic ligand comprising 4-(1H-pyrazol-4-yl)benzoate.
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19.发明公开公开(公告)号：US20240286112A1
公开(公告)日：2024-08-29
申请号：US18572045
申请日：2022-06-23
Inventor： Joseph M. Falkowski , Mary S. Abdulkarim , Julie J. Seo
IPC: B01J20/22
CPC classification number: B01J20/226
Abstract: Provided herein are post-synthesis methods of thermally stabilizing a metal-organic framework having defects that decomposes after about 12 hours at a first temperature. The methods include contacting the metal-organic framework with a stabilizing solution to provide a treated metal-organic framework. The treated metal-organic framework is thermally stable after 12 hours at a second temperature at least about 50° C. greater than the first temperature. Also, the treated metal-organic framework has a PXRD pattern that is substantially the same as the PXRD pattern of the untreated metal-organic framework. Provided herein are also post-synthesis methods to improve CO2 adsorption of metal-organic frameworks. Provided herein are also modified EMM-71 metal-organic frameworks.
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公开(公告)号：US20240246060A1
公开(公告)日：2024-07-25
申请号：US18561619
申请日：2022-05-20
Inventor： Carter W. Abney , Julie J. Seo , Matthew T. Kapelewski , Dominick A. Zurlo , Joseph M. Falkowski
CPC classification number: B01J20/226 , B01D53/02 , B01J20/3078 , B01D2253/204 , B01D2257/7022
Abstract: Methods of making metal-organic frameworks in yields of at least about 50 percent by volume of metal-organic frameworks in a metal-organic framework material per liter of synthesis solution and/or about 75 molar percent of metal-organic frameworks in a metal-organic framework material are provided. Methods of making MOF Cu(Qc)2 in aqueous solutions are further provided where a solvent composition of less than about 30% volume water is combined with a buffer and a plurality of reagents to provide the synthesis solution.
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