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公开(公告)号：US11097239B2
公开(公告)日：2021-08-24
申请号：US16691946
申请日：2019-11-22
Applicant: PetroChina Company Limited
Inventor： Bin Ding , Xiangfei Geng , Jianhui Luo , Yang Shi , Bo Huang , Jianyong Xie , Yang Gao , Pingmei Wang , Baoliang Peng
Abstract: The invention discloses a core-shell structured non-ionic nanoemulsion system and the preparation and use thereof. The system comprises a non-ionic gemini surfactant, an oil phase material, a solubilizer, and water; wherein the microemulsion has a core-shell structure, with the outer shell being the non-ionic Gemini surfactant, and the inner core being the oil phase material. The non-ionic Gemini surfactant is di(octylphenol polyoxyethylene ether)-substituted dicarboxylic acid diphenyl ether having the structural formula: The non-ionic nanoemulsion system of the present invention is homogeneous and transparent, and has a spherical core-shell structure with nanometer-sized (3-40 nm) droplets, narrow particle size distribution, low tendency to agglomerate, good stability, and both an ultra-low interfacial tension and the ability to reduce viscosity of crude oil.
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公开(公告)号：US10759667B2
公开(公告)日：2020-09-01
申请号：US16029215
申请日：2018-07-06
Applicant: PetroChina Company Limited
Inventor： Jianhui Luo , Zongtao Zhang , Baoliang Peng , Runwei Wang , Lipeng He , Pingmei Wang , Bin Ding , Ying Wang , Xiangfei Geng
Abstract: The present invention provides an amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside and a production method thereof. The production method comprises: dispersing the ZSM-5 spherical nano-molecular sieve into toluene, adding thereto an organosilane containing a hydrophilic group and reacting at 40-80° C. for 2-16 h, to obtain a molecular sieve containing a hydrophilic group; placing the molecular sieve containing a hydrophilic group in an aqueous solution of sodium hydroxide and reacting at 50-90° C. for 10-50 min, to obtain a molecular sieve containing a hydrophilic group on the outside; dispersing the molecular sieve containing a hydrophilic group on the outside into toluene, adding thereto an organosilane containing a lipophilic group and reacting at 40-80° C. for 2-12 h, to obtain the amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside. The present invention also provides an amphiphilic molecular sieve obtained by the above production method, which contains a hydrophilic group on the outside and a lipophilic group on the inside.
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公开(公告)号：US10647586B2
公开(公告)日：2020-05-12
申请号：US16029170
申请日：2018-07-06
Applicant: PetroChina Company Limited
Inventor： Baoliang Peng , Zongtao Zhang , Pingmei Wang , Runwei Wang , Bin Ding , Jianhui Luo , Lipeng He , Ying Wang , Xiangfei Geng
Abstract: The present invention provides an amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside and a production method thereof. The production method comprises: dispersing the nano-ZSM-5 molecular sieve into toluene, adding an organosilane containing a lipophilic group and reacting at 60-100° C. for 4-16 h, to obtain a molecular sieve containing a lipophilic group; placing the molecular sieve containing a lipophilic group in a mixed solution of sodium hydroxide solution and ethanol and reacting at 60-95° C. for 20-60 min, to obtain a molecular sieve containing a lipophilic group on the outside; dispersing the molecular sieve containing a lipophilic group on the outside into toluene, adding an organosilane containing a hydrophilic group and reacting at 60-100° C. for 4-16 h, to obtain the amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside. The present invention also provides a molecular sieve obtained by the above production method, which does not destroy the characteristics of the original molecular sieve and has hydrophilic and lipophilic amphiphilic properties.
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公开(公告)号：US20190202704A1
公开(公告)日：2019-07-04
申请号：US16029170
申请日：2018-07-06
Applicant: PetroChina Company Limited
Inventor： Baoliang Peng , Zongtao Zhang , Pingmei Wang , Runwei Wang , Bin Ding , Jianhui Luo , Lipeng He , Ying Wang , Xiangfei Geng
CPC classification number: C01B39/026 , C01B39/38 , C01P2002/72 , C01P2004/03 , C01P2004/04 , C01P2004/90 , C01P2006/16
Abstract: The present invention provides an amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside and a production method thereof. The production method comprises: dispersing the nano-ZSM-5 molecular sieve into toluene, adding an organosilane containing a lipophilic group and reacting at 60-100° C. for 4-16 h, to obtain a molecular sieve containing a lipophilic group; placing the molecular sieve containing a lipophilic group in a mixed solution of sodium hydroxide solution and ethanol and reacting at 60-95° C. for 20-60 min, to obtain a molecular sieve containing a lipophilic group on the outside; dispersing the molecular sieve containing a lipophilic group on the outside into toluene, adding an organosilane containing a hydrophilic group and reacting at 60-100° C. for 4-16 h, to obtain the amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside. The present invention also provides a molecular sieve obtained by the above production method, which does not destroy the characteristics of the original molecular sieve and has hydrophilic and lipophilic amphiphilic properties.
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