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11.发明授权
公开(公告)号：US4379070A
公开(公告)日：1983-04-05
申请号：US371791
申请日：1982-04-26
Applicant: Paul A. Tick
Inventor： Paul A. Tick
CPC classification number: C09K11/06 , C03C3/247 , C03C4/04 , C03C4/12 , G02F1/15 , H01S3/168 , Y10S430/146
Abstract: A tin-phosphorous oxyfluoride glass in the Sn--P--O--F composition field is used as a supporting matrix for light-responsive polycyclic aromatic hydrocarbons, such as triplet state or lasing dyes. Dye compatibility with the glass is good, as evidenced by the fact that glasses containing the dyes exhibit luminescence characteristic of the dissolved dye in a rigid solvent.
Abstract translation: Sn-P-O-F组合物领域中的一种磷酸二氢锡玻璃用作光响应性多环芳烃如三线态或激光染料的支撑基质。 与玻璃的染料相容性是好的，如由含有染料的玻璃在刚性溶剂中表现出溶解的染料的发光特性的事实证明的。
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公开(公告)号：US4166745A
公开(公告)日：1979-09-04
申请号：US861129
申请日：1977-12-16
Applicant: Roger J. Araujo , Paul A. Tick
Inventor： Roger J. Araujo , Paul A. Tick
CPC classification number: C03C4/065 , C03C21/002 , Y10S501/903 , Y10T428/24992 , Y10T428/315
Abstract: Alkali boroaluminosilicate glass compositions providing refractive index-corrected copper-cadmium halide photochromic glasses of optical quality, particularly useful for making ophthalmic lenses, are described. Ion-exchange-strengthenable glasses exhibiting good chemical durability and a satisfactory liquidus-viscosity relationship in combination with good photochromic properties and the required refractive index are also provided.
Abstract translation: 描述了提供光学质量的折射率校正的铜 - 镉卤化物光致变色玻璃的碱性硼硅铝酸盐玻璃组合物，特别可用于制造眼镜。 还提供了具有良好的化学耐久性和良好的液相粘度关系以及良好的光致变色性能和所需折射率的离子交换强化玻璃。
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公开(公告)号：US5609660A
公开(公告)日：1997-03-11
申请号：US473611
申请日：1995-06-07
Applicant: Gaylord L. Francis , Ronald E. Johnson , Paul A. Tick , Lung-Ming Wu
Inventor： Gaylord L. Francis , Ronald E. Johnson , Paul A. Tick , Lung-Ming Wu
IPC: B29D11/00 , B29K503/04 , C08K3/32 , C08K3/34 , C08K3/40 , C08K9/02 , C08L101/00 , C08L101/12 , G02B6/28 , G02B6/38 , C03C17/22 , C03B8/04
CPC classification number: G02B6/2804 , C08K3/32 , C08K3/40 , C08K9/02 , G02B6/3801
Abstract: Polymeric compositions having a polymeric component and an inorganic filler which undergoes a crystal (phase) inversion within the operating temperature range of the composition are provided. The present invention relates to a method for reducing the water sensitivity of particles of a crystallized phosphate glass. The particles are composed of P.sub.2 O.sub.5 and one or more cations selected from the group consisting of magnesium, cobalt, arsenic, zinc, iron, aluminum, and zirconium. The method includes nitriding the particles.
Abstract translation: 提供了具有在组合物的工作温度范围内经历晶体（相）反转的聚合物组分和无机填料的聚合物组合物。 本发明涉及降低结晶磷酸盐玻璃颗粒的水敏感性的方法。 颗粒由P2O5和一种或多种选自镁，钴，砷，锌，铁，铝和锆的阳离子组成。 该方法包括氮化氮化颗粒。
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公开(公告)号：US5108477A
公开(公告)日：1992-04-28
申请号：US526236
申请日：1990-05-21
Applicant: Lauren K. Cornelius , Linda H. Marks , Teresa C. Nolet , Paul A. Tick , Donald M. Trotter, Jr.
Inventor： Lauren K. Cornelius , Linda H. Marks , Teresa C. Nolet , Paul A. Tick , Donald M. Trotter, Jr.
CPC classification number: C03B19/102 , C03B19/00 , C03B19/06 , C03B2201/70 , C03B2201/82 , Y10S65/15
Abstract: A method for foming glass articles of substantial thickness from unstable glass compositions which normally devitrify when formed by conventional casting or molding processes, is disclosed. The method includes the steps of quench-cooling the glass to form a crystal-free glass feedstock material, and then pressure-consolidating the feedstock at a temperature between the transition temperature and the crystallization temperature of the glass.
Abstract translation: 公开了一种用于通过常规铸造或模塑工艺形成的通常失透的不稳定玻璃组合物来形成实质厚度的玻璃制品的方法。 该方法包括骤冷冷却玻璃以形成无结晶玻璃原料的步骤，然后在玻璃的转变温度和结晶温度之间的温度下对原料进行压力固化。
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公开(公告)号：US5089446A
公开(公告)日：1992-02-18
申请号：US598001
申请日：1990-10-09
Applicant: Lauren K. Cornelius , Gaylord L. Francis , Paul A. Tick
Inventor： Lauren K. Cornelius , Gaylord L. Francis , Paul A. Tick
Abstract: Mill additions are disclosed which lower the CTE of, and are compatible with, tin-phosphorus oxyfluoride glasses. The sealing materials provide fusion-type seals having a CTE not over about 110.times.10.sup.-7 /.degree.C. and a sealing temperature not over about 350.degree. C.Also disclosed is a family of glass compositions in the tin-phosphorus oxyfluoride system that exhibit very low glass transition temperatures and coefficients of thermal expansion not over about 160.times.10-7/.degree.C. (25.degree.-150.degree. C.). In addition to the four basic elements, the glasses contain up to 11% Nb, and may additionally contain up to 10%, taken individually or in combination, of V, Fe and/or Mo to further decrease the Tg and CTE values.
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Patent Agency Ranking16.发明授权
公开(公告)号：US4752593A
公开(公告)日：1988-06-21
申请号：US60152
申请日：1987-06-10
Applicant: Paul A. Tick
Inventor： Paul A. Tick
CPC classification number: C03C3/325 , Y10S501/904
Abstract: Metal halide glasses of CdF.sub.2 -LiF-AlF.sub.3 -PbF.sub.2 composition but comprising KF and one or more of LaF.sub.3 and YF.sub.3 as stabilizers, and also including a minor amount of oxygen as a further stabilizer, exhibit excellent glass stability and low hydroxyl content as evidenced by high transmittance over the infrared wavelength range 2-6 microns.
Abstract translation: CdF2-LiF-AlF3-PbF2组合物的金属卤化物玻璃，但包含KF和LaF 3和YF 3中的一种或多种作为稳定剂，并且还包含少量的氧作为其它稳定剂，表现出优异的玻璃稳定性和低羟基含量，如 红外波长范围内的高透光率为2-6微米。
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公开(公告)号：US4420569A
公开(公告)日：1983-12-13
申请号：US483898
申请日：1983-04-11
Applicant: Paul A. Tick
Inventor： Paul A. Tick
CPC classification number: C03C3/247 , Y10S501/903
Abstract: This invention is directed to the production of glasses within the Li.sub.2 O-K.sub.2 O-ZrO.sub.2 -F-P.sub.2 O.sub.5 system having batch compositions as generally depicted in terms of mole percent in FIG. 2.
Abstract translation: 本发明涉及在Li 2 O-K 2 O-ZrO 2 -F-P 2 O 5系统内制备玻璃，其具有通常以图1中的摩尔％表示的批量组成。 2。
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公开(公告)号：US4362819A
公开(公告)日：1982-12-07
申请号：US327915
申请日：1981-12-07
Applicant: Anthony R. Olszewski , Paul A. Tick , Leon M. Sanford, deceased
Inventor： Anthony R. Olszewski , Paul A. Tick , Leon M. Sanford, deceased
CPC classification number: C03C3/247 , Y10S501/902 , Y10S501/903
Abstract: The present invention is directed to the production of essentially dry alkali metal (R.sup.1) aluminofluorophosphate glasses optionally containing at least one divalent metal (R.sup.2) which exhibits a transition temperature below about 350.degree. C., good chemical durability, resistance to weathering, and glass stability, and which demonstrate the capability of being molded at temperatures below 400.degree. C. into complex shapes. The alkali metal aluminofluorophosphate glasses consist essentially, as analyzed on an atomic basis, between about R.sup.1 AlP.sub.2 F.sub.2 O.sub.6 and R.sup.1 .sub.3.75 AlP.sub.3 F.sub.4 O.sub.9 with the requirement that the components comply with the following atomic ratios:F:Al >2 but 2 but 0.5 but 0.75 but
Abstract translation: 本发明涉及生产基本上干燥的碱金属（R1）铝氟磷酸盐玻璃，其任选地含有至少一种二价金属（R2），其转变温度低于约350℃，良好的化学耐久性，耐候性和玻璃 稳定性，并且表现出在低于400℃的温度下成型成复杂形状的能力。 碱金属铝氟磷酸盐玻璃基本上按原子基准分布在约R1AlP2F2O6和R13.75AlP3F4O9之间，要求组分符合以下原子比：F：Al> 2但<4（优选3 +/- 0.5 ）P：Al> 2但<3 R1：P> 0.5但<1.24（优选> 0.75但<1.1）以氧化物为基准分析的以重量百分比表示的那些值转换为以下近似范围：R12O13 -38 Al2O3 16-23 P2O5 46-64 F 17-23。
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公开(公告)号：US4226628A
公开(公告)日：1980-10-07
申请号：US61901
申请日：1979-07-30
Applicant: Roger F. Bartholomew , William G. Dorfeld , James A. Murphy , Joseph E. Pierson , Stanley D. Stookey , Paul A. Tick
Inventor： Roger F. Bartholomew , William G. Dorfeld , James A. Murphy , Joseph E. Pierson , Stanley D. Stookey , Paul A. Tick
Abstract: This invention is related to the production of glasses having compositions within the copper and/or silver-halide-phosphate field, wherein at least one halide is present selected from the group of fluoride, chloride, bromide, and iodide, such glasses exhibiting softening points below about 400.degree. C., coefficients of thermal expansion (25.degree.-300.degree. C.) in excess of about 180.times.10.sup.-7 /.degree.C., high electrical conductivity, and electrochromic behavior. The copper-containing glasses may also demonstrate thermochromic properties.
Abstract translation: 本发明涉及在铜和/或卤化银 - 磷酸盐领域中具有组成的玻璃的制备，其中至少一种卤化物存在选自氟化物，氯化物，溴化物和碘化物，这种玻璃表现出软化点 低于约400℃，热膨胀系数（25-300℃）超过约180×10 -7 /℃，高导电性和电致变色行为。 含铜玻璃也可以显示出热致变色性质。
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公开(公告)号：US4168339A
公开(公告)日：1979-09-18
申请号：US927956
申请日：1978-07-26
Applicant: David J. Kerko , Jean-Pierre Odile , Candace J. Quinn , Paul A. Tick
Inventor： David J. Kerko , Jean-Pierre Odile , Candace J. Quinn , Paul A. Tick
IPC: G02C7/10 , B29D11/00 , B32B17/10 , C03C3/11 , C03C3/118 , C03C4/06 , G02B1/00 , G02B1/04 , G02B5/23 , G02F1/17 , B32B7/02 , B32B27/36 , G02B3/00
CPC classification number: B32B17/10486 , B29D11/00634 , C03C3/108 , C03C4/06 , G02B1/04 , G02B1/041 , Y10S428/913 , Y10T428/31507 , Y10T428/31616
Abstract: This invention is directed to the production of photochromic glass microsheet which is particularly useful in the fabrication of transparent glass-plastic composite lenses. In such lenses, the photochromic microsheet will either be buried within the plastic or will act as a surface layer thereon. The microsheet consists essentially, in weight percent on the oxide basis as calculated from the batch, of 54-66% SiO.sub.2, 7-15% Al.sub.2 O.sub.3, 10-30% B.sub.2 O.sub.3, 3-15% Na.sub.2 O, 0.4-1.5% PbO, 0.2-0.5% Br, 0.5-1.2% Cl, 0.2-0.5% F, 0.008-0.03% CuO, and >0.03%-1% Ag.
Abstract translation: 本发明涉及制造透明玻璃 - 塑料复合透镜特别有用的光致变色玻璃微片。 在这种透镜中，光致变色微片将被埋在塑料内，或者作为其上的表面层。 该微片基本上以按批次计算的以氧化物为基准的重量百分比为54-66％SiO 2，7-15％Al 2 O 3，10-30％B 2 O 3，3-15％Na 2 O，0.4-1.5％PbO，0.2 -0.5％Br，0.5-1.2％Cl，0.2-0.5％F，0.008-0.03％CuO和> 0.03％-1％Ag。
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