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公开(公告)号:US20250083424A1
公开(公告)日:2025-03-13
申请号:US18721320
申请日:2022-12-12
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Jerome Vachon , Peter Neuteboom , Arkadiusz Zych
Abstract: The invention relates to a laminate comprising at least one layer a) comprising an oxygen barrier material, at least one layer b) adjacent to layer a), wherein layer b) comprises at least one ethylene-acrylate copolymer comprising recurring units derived from at least one acrylate comonomer represented by formula (I) or (II): CH2=CR1-COO—(CH2)n-OH (I) CH2=CR1-COO—(CH2)m-CHOH—CH2OH (II) wherein R1 is H or C1-C5 linear or branched alkyl, n is an integer of 1-10 and m is an integer of 0-10.
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公开(公告)号:US11174439B2
公开(公告)日:2021-11-16
申请号:US16326035
申请日:2017-08-23
Applicant: Ecolab USA, Inc. , SABIC Global Technologies B.V.
Inventor: Jerome Vachon , Anthoni van Zijl , Fabrice Cuoq , Steven Leen , Carlo Geijselaers , Andrew R. Neilson , Russell P Watson
IPC: C10G9/16 , C09K8/524 , C07C4/04 , C23F14/02 , C02F1/68 , C10G75/04 , C23F15/00 , C02F101/32 , C02F103/36
Abstract: Disclosed herein are methods for reducing fouling caused by process water present within a water recycling loop of a pyrolysis plant. Fouling is caused by phase separation and accumulation of materials from the process water on equipment surfaces. The method includes applying a total of about 5 ppm to 500 ppm total of a first polymerization inhibitor and second polymerization inhibitor to the process water to form a treated process water, wherein the first polymerization inhibitor has a pygas-water partition coefficient of about 0.0001 to 9 and the second polymerization inhibitor has a pygas-water partition coefficient of about 1000 to 50,000.
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公开(公告)号:US11130850B2
公开(公告)日:2021-09-28
申请号:US16474849
申请日:2017-12-12
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Diego Mauricio Castaneda Zuniga , Jerome Vachon , Jan Nicolaas Eddy Duchateau , Peter Neuteboom , Zeljko Knez
Abstract: The present invention relates to a process for recycling polyolefin, comprising the steps of: 1) feeding a solid post-consumer polyolefin composition comprising polyolefin and contaminants and a flow of an extraction fluid to an extractor having a pressure of 100-1000 bar and a temperature of 20-80° C. to obtain a solid extracted composition, 2) melting the solid extracted composition to obtain a melted composition, 3) providing particles from the melted composition by: 3a) mixing a flow of a supercritical fluid in the melted composition in a pressure vessel to obtain a solution saturated with the supercritical fluid and 3b) passing the solution from the pressure vessel through a throttling device to a spraying tower to expand the solution to obtain polyolefin particles in the spraying tower.
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公开(公告)号:US20170183248A1
公开(公告)日:2017-06-29
申请号:US15390987
申请日:2016-12-27
Applicant: Ecolab USA Inc. , SABIC Global Technologies B.V.
Inventor: Steven Leen , Fabrice Cuoq , Anthoni van Zijl , Jerome Vachon , Russell P. Watson , Theodore C. Arnst , Javier Florencio , Bhaskar R. Aluri
IPC: C02F5/10
CPC classification number: C02F5/10 , C02F5/12 , C02F2103/365
Abstract: Disclosed herein are methods for reducing fouling caused by process water present within a water recycling loop of a pyrolysis plant. The process water includes water, a pygas, and in some cases pygas byproducts. Fouling is caused by phase separation and accumulation of materials from the process water on equipment surfaces. The method includes applying a total of about 5 ppm to 500 ppm of one or more antifouling polymers to the process water to form a treated process water. The one or more antifouling polymers are selected from the group consisting of copolymers of unsaturated fatty acids, primary diamines, and acrylic acid; copolymers of methacrylamidopropyl trimethylammonium chloride with acrylic acid and/or acrylamide; copolymers of ethylene glycol and propylene glycol; and blends of two or more thereof.
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公开(公告)号:US20210130568A1
公开(公告)日:2021-05-06
申请号:US16474849
申请日:2017-12-12
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Diego Mauricio Castaneda Zuniga , Jerome Vachon , Jan Nicolaas Eddy Duchateau , Peter Neuteboom , Zeljko Knez
Abstract: The present invention relates to a process for recycling polyolefin, comprising the steps of: 1) feeding a solid post-consumer polyolefin composition comprising polyolefin and contaminants and a flow of an extraction fluid to an extractor having a pressure of 100-1000 bar and a temperature of 20-80° C. to obtain a solid extracted composition, 2) melting the solid extracted composition to obtain a melted composition, 3) providing particles from the melted composition by: 3a) mixing a flow of a supercritical fluid in the melted composition in a pressure vessel to obtain a solution saturated with the supercritical fluid and 3b) passing the solution from the pressure vessel through a throttling device to a spraying tower to expand the solution to obtain polyolefin particles in the spraying tower.
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公开(公告)号:US10858462B2
公开(公告)日:2020-12-08
申请号:US16062184
申请日:2016-12-07
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Diego Mauricio Castaneda Zuniga , Carolina de los Angeles Toloza Porras , Peter Neuteboom , Jan Nicolaas Eddy Duchateau , Jerome Vachon , Franciscus Petrus Hermanus Schreurs
IPC: C08F220/20 , C08F210/02 , C08F210/14 , C08J5/18 , C08F2/01 , C08F216/14 , C08F220/26 , C08K5/14 , C08K5/23 , C08F220/28
Abstract: The present invention relates to an ethylene copolymer comprising: (iv) ≥78.0 and ≤99.9 mol % of recurring units derived from ethylene; (v) ≥0.10 and ≤20.0 mol % of a recurring units derived from a comonomer A according to formula (I) wherein R1 is a moiety comprising 1-30 carbon atoms; R2 is selected from —H or —CH3; R3 is selected from —O—, —(CO)—(NH)— or —(CO)—O—; n=0 or 1; and m≥1 and ≤10; and (vi) ≥0.01 and ≤2.00 mol % of a recurring units derived from a comonomer B according to formula (II) wherein R1 is a moiety comprising 1-30 carbon atoms; each R2 may individually be selected from —H or —CH3; each of R3 is individually selected from —O—, —(CO)—(NH)— or —(CO)—O—; n=0 or 1; p=0 or 1; and m≥1 and ≤10; the mol % of each of (i), (ii) and (iii) being related to the sum of the mol % of (i), (ii) and (iii), the sum of the mol % of (i), (ii) and (iii) adding up to 100 mol %. Such ethylene copolymers have a reduced peak melting temperature and reduced enthalpy of fusion, indicating that these ethylene copolymers have a reduced degree of crystallinity and improved clarity and contact angle, combined with a desired melt mass-flow rate.
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公开(公告)号:US10696827B2
公开(公告)日:2020-06-30
申请号:US15754443
申请日:2016-07-21
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Jerome Vachon , Mark Johannes Boerakker , AT Kavya , Ajay Kumar Taraiya , Satishkumar Mahanth , Roshan Kumar Jha
IPC: A01N65/00 , C08K5/13 , C08L23/06 , C08L23/12 , A01N31/08 , A01N31/16 , C08K9/12 , C08K3/22 , A01N25/10 , C08K5/00 , F16L11/04
Abstract: The invention is directed to a composition comprising 90.00 to 99.95 wt % of a polyolefin and 0.05 to 10.00 weight % of an antimicrobial additive based on the total weight of the polyolefin composition wherein the antimicrobial additive comprises a phenolic group and wherein a carrier for the antimicrobial additive is present. The antimicrobial additive may be dispersed through the polyolefin composition. Preferred antimicrobial additives include for example eugenol, isoeugenol, thymol, carvacrol, sesamol, curcumin, p-hydroxybenzoic acid, gallic acid and its ester derivatives (propyl gallate, octyl gallate and dodecyl gallate), ferulic acid, syringic acid, coumaric acid, protocatechuic acid, caffeic acid and/or tannic acid.
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公开(公告)号:US20180244902A1
公开(公告)日:2018-08-30
申请号:US15754443
申请日:2016-07-21
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Jerome Vachon , Mark Johannes Boerakker , AT Kavya , Ajay Kumar Taraiya , Satishkumar Mahanth , Roshan Kumar Jha
Abstract: The invention is directed to a composition comprising 90.00 to 99.95 wt % of a polyolefin and 0.05 to 10.00 weight % of an antimicrobial additive based on the total weight of the polyolefin composition wherein the antimicrobial additive comprises a phenolic group and wherein a carrier for the antimicrobial additive is present. The antimicrobial additive may be dispersed through the polyolefin composition. Preferred antimicrobial additives include for example eugenol, isoeugenol, thymol, carvacrol, sesamol, curcumin, p-hydroxybenzoic acid, gallic acid and its ester derivatives (propyl gallate, octyl gallate and dodecyl gallate), ferulic acid, syringic acid, coumaric acid, protocatechuic acid, caffeic acid and/or tannic acid.
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