公开(公告)号：US3644480A

公开(公告)日：1972-02-22

申请号：US3644480D

申请日：1970-12-03

Applicant: TEXACO INC

Inventor： KABLAOUI MAHMOUD S

IPC: C07C69/14 ,  C07C69/157

CPC classification number: C07C67/00 ,  C07C2601/14 ,  C07C69/017 ,  C07C69/157

Abstract: A METHOD OF PREPARING 2-SUBSTITUTED BENZENE ACETATE OF THE FORMULA 1-(CH3-COO-),2-R-BENZENE WHERE R IS A MONOVALENT RADICAL OF UP TO 20 CARBONS SELECTED FROM THE GROUP CONSISTIN ALKYL, CYCLOALKYL AND -CH2COO(CH2)XCH3 WHERE X IS AN INTEGER FROM 0 TO 17 COMPRISING CONTACTING 2-SUBSTITUTED CYCLOHEXALNONE OF THE FORMULA:; 2-R-CYCLOHEXANONE WHERE R IS AS HERETOFORE DEFINED WITH MIXTURE OF ACETIC ANHYDRIDE, ACETIC ACID AND CONCENTRATED SULGURIC ACID AT A TEMPERATURE BETWEEN ABOUT 30 AND 140*C. UTILIZING A MOLE RATION OF SULFURIC ACID TO CYCLOHEXANONE OF AT LEAST 2:1 AND A MOLE RATIO OF ACETIC ACID TO ACETIC ANHYDRIDE OF AT LEAST ABOUT 1:1 AND RECOVERING SAID 2-SUBSTITUTED BENZENE ACETATE, THE 2-SUBTITUTED BENZENE ACETATE PRODUCT CAN BE READILY CONVERTED TO THE CORRESPONDING 2-SUBSTITUTED PHENOL BY HYDROLYSIS.

公开(公告)号：US3624137A

公开(公告)日：1971-11-30

申请号：US3624137D

申请日：1970-02-27

Applicant: TEXACO INC

Inventor： KABLAOUI MAHMOUD S

IPC: C07C69/16

CPC classification number: C07C69/16

Abstract: WHERE X represents said R1 and R2 in gem position, Y represents said R3 and R4 in gem position, and Z represents keto oxygen.

WHERE R1 and R2 are alkyl and R3 and R4 are both hydrogen or alkyl comprising contacting with a mixture of concentrated sulfuric acid and acetic anhydride, a gem polyalkylated cyclohexanedione of the general formula:

A method of preparing a non-gem polyalkylated benzene diacetate of the general formula:

公开(公告)号：US3920560A

公开(公告)日：1975-11-18

申请号：US48359974

申请日：1974-06-27

Applicant: TEXACO INC

Inventor： MCCOY DAVID R ,  KABLAOUI MAHMOUD S

IPC: C09K8/22 ,  C09K7/02

CPC classification number: C09K8/22 ,  Y10S516/03

Abstract: An aqueous drilling fluid dispersant and a method of drilling wells using as the drilling fluid dispersant a water soluble salt of a sulfonated, dialkyl substituted benzodioxole of prescribed type.

Abstract translation: 含水钻井液分散剂和使用作为钻井液分散剂的钻井的方法，其是规定类型的磺化二烷基取代的苯并间二氧杂环戊烯的水溶性盐。

公开(公告)号：US3895072A

公开(公告)日：1975-07-15

申请号：US35876473

申请日：1973-05-09

Applicant: TEXACO INC

Inventor： KABLAOUI MAHMOUD S ,  LACHOWICZ DONALD R

IPC: C07C45/04

CPC classification number: C07C201/14 ,  C07C2601/14 ,  C07C2601/18 ,  C07C2601/20 ,  C07C205/45

Abstract: A method of preparing nitrocycloalkanones by simultaneously contacting a solution containing a cycloalkene, a denitrating agent and an organic solvent with a mixture of dinitrogen tetroxide and oxygen, the mole ratio of denitrating agent to cycloalkene being above 0.1:1 and up to about 2:1, preferably about 0.5:1 to 1:1, as a one step nitrooxidation reaction. The nitrocycloalkanones so formed are useful as fuel and lubricant additives as well as intermediates in the preparation of cyclic lactams such as caprolactam.

Abstract translation: 通过将含有环烯烃，脱硝剂和有机溶剂的溶液与四氧化二氮和氧气的混合物同时接触来制备硝基环烷酮的方法，脱水剂与环烯烃的摩尔比大于0.1:1且高达约2:1 ，优选约0.5:1至1:1作为一步硝基氧化反应。 如此形成的硝基环烷酮可用作燃料和润滑剂添加剂以及制备环状内酰胺如己内酰胺的中间体。

公开(公告)号：US3892810A

公开(公告)日：1975-07-01

申请号：US42003573

申请日：1973-11-29

Applicant: TEXACO INC

Inventor： KABLAOUI MAHMOUD S ,  LACHOWICZ DONALD R

IPC: C07C45/04

CPC classification number: C07C201/14 ,  C07C2601/14 ,  C07C2601/18 ,  C07C2601/20 ,  C07C205/45

Abstract: A method of preparing nitrocycloalkanones by simultaneously contacting a solution containing a cycloalkene, a 2-pyrrolidinone denitrating agent and an organic solvent with a mixture of dinitrogen tetroxide and oxygen, the mole ratio of denitrating agent to cycloalkene being above 0.1:1 and up to about 2:1, preferably about 0.5:1 to 1:1, as a one step nitrooxidation reaction. The nitrocycloalkanones so formed are useful as fuel and lubricant additives as well as intermediates in the preparation of cyclic lactams such as caprolactam.

Abstract translation: 通过将含有环烯烃，2-吡咯烷酮脱硝剂和有机溶剂的溶液与四氧化二氮和氧气的混合物同时接触制备硝基环烷酮的方法，脱水剂与环烯烃的摩尔比高于0.1:1，最高约为 2:1，优选约0.5:1至1:1作为一步硝基氧化反应。 如此形成的硝基环烷酮可用作燃料和润滑剂添加剂以及制备环状内酰胺如己内酰胺的中间体。

公开(公告)号：US3873623A

公开(公告)日：1975-03-25

申请号：US20619871

申请日：1971-12-08

Applicant: TEXACO INC

Inventor： KABLAOUI MAHMOUD S ,  LACHOWICZ DONALD R

IPC: C07C45/02

CPC classification number: C07C201/14 ,  C07C205/45

Abstract: A method of preparing alpha-nitroketones by simultaneously contacting a solution of an alkene, a denitrating agent and an organic solvent with a mixture of dinitrogen tetroxide and oxygen, the mole ratio of denitrating agent to alkene being above 0.1:1 and up to about 2:1, preferably about 0.5:1 and 1:1 as a one step nitrooxidation reaction. The alpha-nitroketones so prepared are useful as fuel and lubricant additives as well as intermediates in the preparation of amides, acids, and nitroalkanes.

Abstract translation: 通过使烯烃，脱硝剂和有机溶剂的溶液与四氧化二氮和氧气的混合物同时接触来制备α-硝基酮的方法，脱硝剂与烯烃的摩尔比大于0.1:1且高达约2 ：1，优选约0.5:1和1:1作为一步硝基氧化反应。 如此制备的α-硝基酮可用作燃料和润滑剂添加剂以及制备酰胺，酸和硝基烷烃的中间体。

公开(公告)号：US3867464A

公开(公告)日：1975-02-18

申请号：US31199572

申请日：1972-12-04

Applicant: TEXACO INC

Inventor： KABLAOUI MAHMOUD S

IPC: C07C29/00 ,  C07C45/54 ,  C07C33/02

CPC classification number: C07C29/00 ,  C07C45/54 ,  C07C49/213 ,  C07C33/22

Abstract: WHERE W is as heretofore defined.

WHERE ACETATE DERIVATIVE R1, R2, R3, A and y are as heretofore defined, and subsequently hydrolizing said acetate derivate to form an aromatic compound of the formula:

WHERE W'' is a monovalent radical selected from the group consisting of

WHERE R3 is hydrogen or alkyl of from 1 to 9 carbons and y is an integer of from 0 to 10 with a mixture of acetic anhydride and concentrated sulfuric acid optionally in the additional presence of acetic acid at a temperature between about 30 and 145*C. utilizing a mole ratio of sulfuric acid to substituted cyclohexene of between about 1.1:1 and 3:1 and a mole ratio of acetic anhydride to cyclohexene of between about 1:1 and 10:1 to form an intermediate aromatic acetate derivative of the formula:

WHERE R1 and R2 are hydrogen or alkyl, A is alkanediyl of from 0 to 9 carbons and a keto group of from 3 to 22 carbons of the formula:

WHERE W is a monovalent radical selected from the group consisting of a hydroxyl group of from 1 to 10 carbons of the formula:

A method of aromatizing substituted cyclohexene to the corresponding aromatic compound comprising contacting a substituted cyclohexene of the formula:

Abstract translation: 将取代的环己烯芳构化成相应的芳族化合物的方法，包括使下式的取代的环己烯：

公开(公告)号：US3631227A

公开(公告)日：1971-12-28

申请号：US3631227D

申请日：1970-02-27

Applicant: TEXACO INC

Inventor： KABLAOUI MAHMOUD S ,  CHAFETZ HARRY

IPC: C07C37/055 ,  C07C45/30 ,  C07C45/63 ,  C07C69/16

CPC classification number: C07C45/30 ,  C07C37/0555 ,  C07C45/63 ,  C07C69/16 ,  C07C49/463 ,  C07C39/08

Abstract: METHOD OF PREPARING A CATECHOL DIACETATE OF THE FORMULA:

1,2-DI(CH3-COO-),3-R1,4-R2,5-R3-BENZENE

WHERE R1, R2, AND R3 ARE HYDROGEN OR ALKYL COMPRISING CONTACTING A HALOCYCLOHEXANONE OF THE FORMULA:

2-X3,2-X4,3-R1,4-R2,5-R3,6-X1,6-X2-CYCLOHEXANONE

WHERE R1, R2 AND R3 ARE AS HERETOFORE DEFINED AND X1, X2, X3 AND X4 ARE HYDROGEN OR HALOGEN AT LEAST ONE OF THE X MEMBERS BEING HALOGEN WITH ACETIC ANHYDRIDE IN THE PRESENCE OF A CATALYTIC AMOUNT OF A SUBSTANCE SELECTED FROM THE GROUP CONSISTING OF BORON TRIFLUORIDE ETHERATE, PYRIDINE, CONCENTRATED SULFURIC ACID AND HYDROCHLORIC ACID, SUBSEQUENTLY CONTACTING THE RESULTANT MIXTURE WITH CONCENTRATED SULFURIC ACID.