公开(公告)号：US09120999B2

公开(公告)日：2015-09-01

申请号：US14079526

申请日：2013-11-13

Applicant: The Clorox Company

Inventor： David R. Scheuing ,  Arun Agarwal ,  David E. Dabney ,  Gregory P. Dado ,  Lafayette D. Foland ,  Shuman Mitra ,  Jacqueline M. Pytel ,  William L. Smith ,  Erika Szekeres ,  Michael R. Terry ,  Kenneth L. Vieira

IPC: C11D1/02 ,  C11D3/10 ,  C11D3/395 ,  C11D3/34

CPC classification number: C11D3/3953 ,  C11D3/3418 ,  C11D3/3951 ,  C11D3/3956

Abstract: The invention relates to compositions including a hypohalite or hypochlorous acid and a soluble salt of 2,4,6 mesitylene sulfonate. The compositions may include a surfactant, a buffer, or combinations thereof. Other adjuvants may also be present. Such compositions do not require the inclusion of high concentrations of sodium hydroxide or other soluble hydroxide salts to drastically increase pH (and thus stability), although such hydroxides may be present if desired.

Abstract translation: 本发明涉及包含次卤酸盐或次氯酸和2,4,6-三甲苯磺酸盐的可溶性盐的组合物。 组合物可以包括表面活性剂，缓冲剂或其组合。 也可以存在其它佐剂。 这样的组合物不需要包含高浓度的氢氧化钠或其它可溶性氢氧化物盐，以显着增加pH（因而稳定性），尽管如果需要可存在这种氢氧化物。

公开(公告)号：US20140116918A1

公开(公告)日：2014-05-01

申请号：US13664033

申请日：2012-10-30

Applicant: THE CLOROX COMPANY

Inventor： David R. Scheuing ,  Travers Anderson ,  William L. Smith ,  Erika Szekeres ,  Rui Zhang

IPC: B65D85/00 ,  B65D25/04

CPC classification number: C11D1/008 ,  B65D81/32 ,  C11D1/02 ,  C11D3/3765 ,  C11D3/3953 ,  C11D3/3956 ,  C11D17/041

Abstract: The invention relates to a polymer-micelle complex. The polymer-micelle complexes include a negatively charged micelle that is electrostatically bound to a water-soluble polymer bearing a positive charge. The polymer does not comprise block copolymer, latex particles, polymer nanoparticles, cross-linked polymers, silicone copolymer, fluorosurfactant, or amphoteric copolymer. The compositions do not form a coacervate, and do not form a film when applied to a surface.

Abstract translation: 本发明涉及聚合物 - 胶束复合物。 聚合物 - 胶束复合物包括与带有正电荷的水溶性聚合物静电结合的带负电荷的胶束。 聚合物不包含嵌段共聚物，胶乳颗粒，聚合物纳米颗粒，交联聚合物，硅氧烷共聚物，含氟表面活性剂或两性共聚物。 组合物不形成凝聚层，并且当施加到表面时不形成膜。

公开(公告)号：US08486879B2

公开(公告)日：2013-07-16

申请号：US13720743

申请日：2012-12-19

Applicant: The Clorox Company

Inventor： Evan Rumberger ,  William L. Smith

IPC: A61Q11/02 ,  A61Q11/00 ,  A61K8/20 ,  C01B11/06

CPC classification number: A61K8/022 ,  A61K8/20 ,  A61K8/362 ,  A61Q11/02 ,  C11D1/22 ,  C11D3/10 ,  C11D3/2079 ,  C11D3/2082 ,  C11D3/33 ,  C11D3/3409 ,  C11D3/349 ,  C11D3/37 ,  C11D3/3761 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/3953 ,  C11D17/0073

Abstract: A solid composition including calcium and/or magnesium hypochlorite, a builder (e.g., one or more of carbonate, bicarbonate, sesquicarbonate), an acid, a water-soluble polymer, at least one anionic surfactant, and optionally, a hydrotrope. The composition does not include any potassium hypochlorite, sodium hypochlorite, lithium hypochlorite, N-halogenated compounds, peroxides, persulfates, hydantoins, isocyanurates, or carboxylic acids that also have hydroxyl, amino, amido, imino, or imido groups. Upon dissolution of the composition in water, the calcium and/or magnesium hypochlorite and acid react to form hypochlorous acid. The use of hypochlorous acid, rather than direct use of an alkaline or alkaline earth hypochlorite results in a composition that is typically acidic rather than basic, and that results in improved cleaning. The composition is particularly suited for cleaning and disinfecting dentures.

公开(公告)号：US20130165572A1

公开(公告)日：2013-06-27

申请号：US13772674

申请日：2013-02-21

Applicant: The Clorox Company

Inventor： David R. Scheuing ,  Thomas F. Fahlen ,  Jared Heymann ,  Mike Kinsinger ,  William Ouellette ,  William L. Smith

IPC: C09D133/02

CPC classification number: C09D147/00 ,  A01N25/10 ,  A01N33/12 ,  A01N59/00 ,  B01J45/00 ,  C09D5/14 ,  C09D5/1662 ,  C09D7/001 ,  C09D7/002 ,  C09D7/20 ,  C09D7/43 ,  C09D133/00 ,  C09D133/02 ,  C09D139/00 ,  C11D3/0036 ,  C11D3/227 ,  C11D3/3723 ,  C11D3/3757 ,  C11D3/3765 ,  C11D3/3769 ,  C11D3/3773 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/3942 ,  C11D3/3947 ,  C11D3/3953 ,  C11D3/3956 ,  C11D3/48

Abstract: The invention relates to compositions and methods of treatment employing compositions comprising polyelectrolyte complexes. The compositions include a water-soluble first polyelectrolyte bearing a net cationic charge or capable of developing a net cationic charge and a water-soluble second polyelectrolyte bearing a net anionic charge or capable of developing a net anionic charge. The total polyelectrolyte concentration of the first solution is at least 110 millimolar. The composition is free of coacervates, precipitates, latex particles, synthetic block copolymers, silicone copolymers, cross-linked poly(acrylic) and cross-linked water-soluble polyelectrolyte. The composition may be a concentrate, to be diluted prior to use to treat a surface.

Abstract translation: 本发明涉及使用包含聚电解质复合物的组合物的组合物和方法。 组合物包括具有净阳离子电荷或能够显影净阳离子电荷的水溶性第一聚电解质和带有净阴离子电荷或能够产生净阴离子电荷的水溶性第二聚电解质。 第一溶液的总聚电解质浓度至少为110毫摩尔。 该组合物不含凝聚层，沉淀物，胶乳颗粒，合成嵌段共聚物，硅氧烷共聚物，交联聚（丙烯酸）和交联的水溶性聚电解质。 组合物可以是在使用前稀释以处理表面的浓缩物。

公开(公告)号：US10858617B2

公开(公告)日：2020-12-08

申请号：US15953839

申请日：2018-04-16

Applicant: THE CLOROX COMPANY

Inventor： David R. Scheuing ,  Thomas F. Fahlen ,  Jared Heymann ,  Mike Kinsinger ,  William Ouellette ,  William L. Smith

IPC: C11D3/48 ,  C11D3/37 ,  C11D3/39 ,  C11D3/395 ,  C11D3/22 ,  A01N33/12 ,  C09D147/00 ,  A01N25/10 ,  A01N59/00 ,  C09D133/02 ,  B01J45/00 ,  C09D139/00 ,  C11D3/00 ,  C09D133/00 ,  C09D7/20 ,  C09D7/43 ,  C09D5/16

Abstract: The invention relates to compositions and methods of treatment employing compositions comprising polyelectrolyte complexes. The compositions include a water-soluble first polyelectrolyte bearing a net cationic charge or capable of developing a net cationic charge and a water-soluble second polyelectrolyte bearing a net anionic charge or capable of developing a net anionic charge. The total polyelectrolyte concentration of the first solution is at least 110 millimolar. The composition is free of coacervates, precipitates, latex particles, synthetic block copolymers, silicone copolymers, cross-linked poly(acrylic) and cross-linked water-soluble polyelectrolyte. The composition may be a concentrate, to be diluted prior to use to treat a surface.

公开(公告)号：US10563156B2

公开(公告)日：2020-02-18

申请号：US16238778

申请日：2019-01-03

Applicant: THE CLOROX COMPANY

Inventor： David R. Scheuing ,  William L. Smith ,  Michael Kinsinger ,  Jared Heymann

IPC: C11D17/04 ,  A01N33/12 ,  B08B1/00 ,  C11D3/37 ,  A61L15/10 ,  C07B57/00 ,  A01N59/00 ,  A01N59/16 ,  C11D3/48 ,  A01N37/02 ,  A01N43/16 ,  A01N43/36 ,  A61L15/46

Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide a cleaning benefit and surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions and at least one oxidant selected from the group: alkaline metal salts and/or alkaline earth metal salts of hypochlorous acid, hypochlorous acid, solubilized chlorine, any source of free chlorine, acidic sodium chlorite, active chlorine generating compound and any combinations or mixtures thereof. Also provided are means to form stable associative polyelectrolyte complexes with at least one oxidant in aqueous solutions having R values from about 0.10 to 20.

公开(公告)号：US20180355289A1

公开(公告)日：2018-12-13

申请号：US16053588

申请日：2018-08-02

Applicant: THE CLOROX COMPANY

Inventor： Dewain Garner ,  William L. Smith ,  Jared Heymann

IPC: C11D3/395 ,  C11D17/04 ,  A01N47/44 ,  C11D7/10 ,  C11D3/26 ,  C11D3/10 ,  C11D3/04 ,  C11D3/00 ,  B65D85/00 ,  B65D25/08 ,  B65D25/04 ,  B05C9/06 ,  A01N59/00 ,  C11D3/22

CPC classification number: C11D3/3951 ,  A01N47/44 ,  A01N59/00 ,  B05C9/06 ,  B65D25/04 ,  B65D25/08 ,  B65D85/70 ,  C11D3/0042 ,  C11D3/0047 ,  C11D3/048 ,  C11D3/10 ,  C11D3/22 ,  C11D3/26 ,  C11D3/3953 ,  C11D3/3955 ,  C11D3/3956 ,  C11D3/3958 ,  C11D7/10 ,  C11D7/105 ,  C11D17/041 ,  A01N25/32

Abstract: This invention relates to extend the benefits of using hypochlorite compounds such as sodium hypochlorite to clean and disinfect articles while reducing or eliminating the side effects of treating an article with a strong oxidant material. The invention relates to a single step process involving mixing of precursor compositions of a suitable hypohalite or hypohalous acid with a solution of a reducing agent. Optionally a buffer may be present in either or both precursor compositions, such that at time of use such active hypohalous acid concentration in the resulting aqueous mixture remains at a sufficient activity level to effect one or more desired benefits against a target substrate for a desired period of time. The oxidant is substantially consumed by reaction with the reducing agent after the time needed for achieving the desired benefit has passed.

公开(公告)号：US10066196B2

公开(公告)日：2018-09-04

申请号：US15721367

申请日：2017-09-29

Applicant: THE CLOROX COMPANY

Inventor： David R. Scheuing ,  William L. Smith ,  Michael Kinsinger ,  Jared Heymann

IPC: C11D17/04 ,  A01N33/12 ,  A01N43/04 ,  C07B57/00 ,  A01N59/00 ,  A01N59/16 ,  B08B1/00 ,  C11D3/37 ,  C11D3/48 ,  A01N37/02 ,  A01N43/16 ,  A01N43/36 ,  A61L15/10 ,  A61L15/46

CPC classification number: C11D17/049 ,  A01N33/12 ,  A01N37/02 ,  A01N43/16 ,  A01N43/36 ,  A01N59/00 ,  A01N59/16 ,  A61L15/10 ,  A61L15/46 ,  B08B1/006 ,  C07B57/00 ,  C11D3/3723 ,  C11D3/3757 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/48 ,  A01N25/10 ,  A01N25/22 ,  A01N25/24

Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide a cleaning benefit and surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellency, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions and at least one oxidant selected from the group: alkaline metal salts and/or alkaline earth metal salts of hypochlorous acid, hypochlorous acid, solubilized chlorine, any source of free chlorine, acidic sodium chlorite, active chlorine generating compound and any combinations or mixtures thereof. Also provided are means to form stable associative polyelectrolyte complexes with at least one oxidant in aqueous solutions having R values from about 0.10 to 20.

公开(公告)号：US09976109B2

公开(公告)日：2018-05-22

申请号：US15433775

申请日：2017-02-15

Applicant: THE CLOROX COMPANY

Inventor： David R. Scheuing ,  Thomas F. Fahlen ,  Jared Heymann ,  Mike Kinsinger ,  William Ouellette ,  William L. Smith

IPC: C11D7/00 ,  C11D3/48 ,  C11D3/395 ,  A01N25/10 ,  C11D3/37 ,  C11D3/00 ,  C11D3/39 ,  B01J45/00 ,  A01N33/12 ,  C09D133/02 ,  C09D139/00 ,  C09D5/14

CPC classification number: C09D147/00 ,  A01N25/10 ,  A01N33/12 ,  A01N59/00 ,  B01J45/00 ,  C09D5/14 ,  C09D5/1662 ,  C09D7/001 ,  C09D7/002 ,  C09D7/20 ,  C09D7/43 ,  C09D133/00 ,  C09D133/02 ,  C09D139/00 ,  C11D3/0036 ,  C11D3/227 ,  C11D3/3723 ,  C11D3/3757 ,  C11D3/3765 ,  C11D3/3769 ,  C11D3/3773 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/3942 ,  C11D3/3947 ,  C11D3/3953 ,  C11D3/3956 ,  C11D3/48

Abstract: The invention relates to compositions and methods of treatment employing compositions comprising polyelectrolyte complexes. The compositions include a water-soluble first polyelectrolyte bearing a net cationic charge or capable of developing a net cationic charge and a water-soluble second polyelectrolyte bearing a net anionic charge or capable of developing a net anionic charge. The total polyelectrolyte concentration of the first solution is at least 110 millimolar. The composition is free of coacervates, precipitates, latex particles, synthetic block copolymers, silicone copolymers, cross-linked poly(acrylic) and cross-linked water-soluble polyelectrolyte. The composition may be a concentrate, to be diluted prior to use to treat a surface.

公开(公告)号：US09963659B2

公开(公告)日：2018-05-08

申请号：US15612266

申请日：2017-06-02

Applicant: THE CLOROX COMPANY

Inventor： Evan Rumberger ,  Marisa MacNaughtan ,  William L. Smith ,  Kelsey Kornaus

IPC: C11D1/00 ,  C11D3/12 ,  C11D3/395 ,  C11D3/08 ,  C11D3/04 ,  C11D3/10 ,  C11D3/50 ,  C11D17/06 ,  A01N59/06 ,  A01N25/34 ,  C11D17/00

CPC classification number: C11D3/3953 ,  A01N25/08 ,  A01N25/34 ,  A01N59/06 ,  C01B11/064 ,  C01B11/066 ,  C11D1/00 ,  C11D3/04 ,  C11D3/042 ,  C11D3/044 ,  C11D3/046 ,  C11D3/08 ,  C11D3/10 ,  C11D3/12 ,  C11D3/1213 ,  C11D3/3757 ,  C11D3/3956 ,  C11D3/50 ,  C11D17/0073 ,  C11D17/041 ,  C11D17/06

Abstract: The invention relates to compositions, methods of use, and methods of manufacture for an intercalated bleach compound and compositions thereof. The intercalated bleach compound has the formula Mx(OCl)y(O)m(OH)n where M is an alkaline earth metal such as magnesium, calcium or mixture thereof. The values of x and y independently equal any number greater than or equal to 1 (e.g., 1, 2, 3, 4, etc.), and m and n independently equal any number greater than or equal to 0 (e.g., 0, 1, 2, 3, 4, etc.), but m and n are not both 0. In addition, the molar ratio of the alkaline earth metal (e.g., magnesium or calcium) to hypochlorite is at least 3:1. In other words, x is ≥3y. The compounds exhibit excellent stability, little or no chlorine bleach odor, exhibit excellent pH buffering characteristics, and less reactivity with organic materials as compared to alternative chlorine bleach products.