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公开(公告)号:US12024606B2
公开(公告)日:2024-07-02
申请号:US17789839
申请日:2020-11-12
Applicant: Toray Industries, Inc.
Inventor: Naokichi Imai , Masato Honma
Abstract: Provided is a composite prepreg including a region (A) containing a thermosetting resin (a) and a reinforcing fiber and a region (B) containing a thermosetting resin (b) and a reinforcing fiber, the composite prepreg satisfying conditions (i) and (ii) or satisfying conditions (ii) and (iii):
(i) The thermosetting resin (b) is a resin having a gel time Tb longer than a gel time Ta of the thermosetting resin (a), and in at least a part of a temperature range of 40° C. or more and 180° C. or less, satisfy Ta/Tb≤0.8;
(ii) A ratio of the region (A) on a surface of the composite prepreg is 20 to 80%; and
(iii) The thermosetting resin (b) is a resin having a higher heat generation starting temperature Eb than a heat generation starting temperature Ea of the thermosetting resin (a), and in a differential scanning calorimetry chart obtained by measuring at 5° C./min with 40° C. as a starting temperature, satisfy Eb−Ea≥30.-
公开(公告)号:US20230040874A1
公开(公告)日:2023-02-09
申请号:US17777691
申请日:2020-11-16
Applicant: Toray Industries, Inc.
Inventor: Naokichi Imai , Kotaro Shinohara , Masato Honma
Abstract: An object of the present invention is to obtain a fiber-reinforced composite material achieving both lightweight properties and mechanical properties at a high level. The present invention provides a fiber-reinforced composite material including a resin (A) and a reinforcing fiber (B), and having: a porous structure portion having micropores with an average pore diameter of 500 μm or less as measured by a mercury intrusion method; and a coarse cavity portion defined by the porous structure portion and having a maximum length of more than 500 μm as a cross-sectional opening portion.
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公开(公告)号:US10583640B2
公开(公告)日:2020-03-10
申请号:US15739364
申请日:2016-06-30
Applicant: TORAY INDUSTRIES, INC.
Inventor: Naokichi Imai , Masato Honma
IPC: B29C33/68 , B32B27/32 , B29C43/18 , C08J5/04 , B32B5/28 , B29C70/46 , B29C43/58 , B32B1/04 , B32B27/20 , B32B27/38 , C08J5/24
Abstract: A method for producing a fiber-reinforced composite material is provided. By satisfying particular conditions, this method is capable of suppressing the problem of poor appearance caused by the release film in the production of the fiber-reinforced composite material having a three-dimensional shape by heat-press molding to enable production of the fiber-reinforced composite material having a high quality appearance in high cycle.A method for manufacturing a fiber-reinforced composite material wherein a fiber-reinforced substrate containing a reinforcing fiber (A) and a thermosetting resin (B) is sandwiched between release films (C) to constitute a layered material, and the layered material is pressed in a mold heated to molding temperature to thereby cure the thermosetting resin (B), wherein the method satisfies the following (i), (ii), and (iii) or (i), (ii), and (iv): (i) the fiber-reinforced composite material has at least 1 bent part, (ii) the molding temperature is 130 to 180° C., and pressure application time is 0.5 to 20 minutes, (iii) the release film (C) has a thermal contraction rate satisfying the following expressions (1) and (2): 0
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公开(公告)号:US20180362760A1
公开(公告)日:2018-12-20
申请号:US16008926
申请日:2018-06-14
Applicant: Toray Industries, Inc.
Inventor: Naokichi Imai , Atsuki Tsuchiya , Masato Honma , Kohei Yamashita , Shunsuke Horiuchi , Koji Yamauchi
Abstract: Provided is a molding material which includes a composite of 1 to 50 wt % of a continuous reinforcing fiber bundle (A) and 0.1 to 20 wt % of a poly(phenylene ether ether ketone) oligomer (B); and 30 to 98.9 wt % of a thermoplastic resin (C) adhering to the composite, wherein the component (B) has a melting point of not higher than 270° C. Also provided are a method for molding the molding material, a method for producing the molding material, and a method for producing a fiber-reinforced composite material. A molded article having high heat resistance and dynamic properties can be easily produced without impairing the economic efficiency and productivity during the process for producing a molding material. In addition, a fiber-reinforced composite material can be produced with more ease and high productivity.
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公开(公告)号:US20180244879A1
公开(公告)日:2018-08-30
申请号:US15553804
申请日:2016-02-24
Applicant: Toray Industries, Inc.
Inventor: Tomohiro Takehara , Satoshi Seike , Masato Honma , Naokichi Imai , Satomi Hiasa
CPC classification number: C08J5/24 , B29C70/18 , B29C70/40 , B29C70/465 , B29C70/547 , B29K2063/00 , B29K2307/04 , B29K2905/00 , C08J5/04 , C08J5/042 , C08J2323/12 , C08J2363/02 , C08J2400/20
Abstract: A resin supply material used for press molding or vacuum-pressure molding of a fiber-reinforced resin, the resin supply material including a continuous porous material and a thermosetting resin, wherein an average pore cross-sectional area ratio P expressed by formula (I) is 1.1 or more: P=AII/AI (I) AI: average pore cross-sectional area in region I AII: average pore cross-sectional area in region II Region I: region occupying 10% of total volume of continuous porous material from surface layer on both surfaces thereof Region II: whole region of continuous porous material.
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公开(公告)号:US11926088B2
公开(公告)日:2024-03-12
申请号:US17778077
申请日:2020-11-16
Applicant: Toray Industries, Inc.
Inventor: Naokichi Imai , Kotaro Shinohara , Masato Honma
IPC: B29C53/24 , B29C70/34 , B29C70/54 , B32B3/28 , B32B5/02 , B29K105/00 , B29K105/12 , B29K105/24 , B29L7/00
CPC classification number: B29C53/24 , B29C70/34 , B29C70/54 , B32B3/28 , B32B5/022 , B29K2105/128 , B29K2105/24 , B29K2105/256 , B29L2007/002 , B32B2250/20 , B32B2260/021 , B32B2305/076 , B32B2307/732
Abstract: An object of the present invention is to provide a fiber-reinforced composite material achieving both lightweight properties and mechanical properties, a laminate thereof, and a prepreg capable of easily molding a sandwich structure thereof. The present invention is a prepreg comprising a reinforced fiber substrate (B) impregnated with a resin (A), wherein the reinforced fiber substrate (B) exists in a folded state having a plurality of folds with a fold angle of 0° or more and less than 90° in the prepreg.
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公开(公告)号:US11141893B2
公开(公告)日:2021-10-12
申请号:US16641436
申请日:2018-08-24
Applicant: Toray Industries, Inc.
Inventor: Takafumi Suzuki , Yuichiro Sento , Naokichi Imai , Mitsushige Hamaguchi , Masato Honma
IPC: B29C45/14 , B32B5/28 , B29K705/02 , B32B27/08
Abstract: In order to solve reduction in strength and rigidity at a weldline which is a problem of an injection molding body, and enable free design such as thin wall molding or complex shape molding of the injection molding body, there is provided an integrally molded body in which a substrate for reinforcement (a) having a discontinuous fiber (a1) and a resin (a2) and an injection molding body (b) having a discontinuous fiber (b1) and a resin (b2) are integrated, in which the substrate for reinforcement (a) has a difference in an orientation angle of the discontinuous fiber (a1) in each of regions obtained by dividing a major axis direction of the substrate for reinforcement (a) into 10 equal parts of within 10°, and the substrate for reinforcement (a) covers a part or all of a weldline of the injection molding body (b) to be integrated with the injection molding body (b).
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公开(公告)号:US10908651B2
公开(公告)日:2021-02-02
申请号:US15760735
申请日:2016-09-06
Applicant: TORAY INDUSTRIES, INC.
Inventor: Masato Honma , Yoshiki Takebe , Naokichi Imai , Takashi Fujioka
Abstract: An electronic device housing includes: a bottom cover; a top cover; a partition structure that is disposed in a space divided by the bottom cover and the top cover and has an opening; and a heat generation member. The partition structure is joined to the bottom cover or the top cover to form a hollow structure, and the heat generation member is disposed on a surface of the partition structure on the hollow structure side.
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公开(公告)号:US10472498B2
公开(公告)日:2019-11-12
申请号:US15873031
申请日:2018-01-17
Applicant: Toray Industries, Inc.
Inventor: Naokichi Imai , Kentaro Sano , Keisuke Inose
Abstract: A molded article includes 10 to 40% by mass of reinforcing fibers (A); and 60 to 90% by mass of a matrix resin (B) mainly including a polyarylene sulfide, the molded article satisfying conditions (I) to (IV) and having a tensile strength of 240 MPa or more in a main orientation direction of the reinforcing fibers (A) in the molded article: (I) strand tensile strength of the reinforcing fibers (A) is 1.5 to 5.5 OPa; (II) number average fiber length of the reinforcing fibers (A) in the molded article is 0.4 mm or more and less than 0.6 mm; (III) tensile elongation of the matrix resin (B) is 1.5 to 10%; and (IV) interfacial shear strength between the reinforcing fibers (A) and the matrix resin (B) is 20 MPa or more.
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公开(公告)号:US10093802B2
公开(公告)日:2018-10-09
申请号:US15032214
申请日:2014-10-24
Applicant: Toray Industries, Inc.
Inventor: Kentaro Sano , Keisuke Inose , Naokichi Imai , Atsuki Tsuchiya
Abstract: A molding material includes 5 to 50 parts by mass of reinforcing fibers (A) with a sizing agent (s) deposited thereon, 1 to 20 parts by mass of a component (B) containing a polycarbodiimide compound (B-1) that is liquid at 50° C., and 30 to 94 parts by mass of a thermoplastic resin (C) containing an element other than carbon in the repeating unit structure of the main chain, based on 100 parts by mass of the total of the components (A) to (C), wherein the molding material is a composite in which a composite fiber bundle (D) with the component (A) impregnated with the component (B) is covered with the component (C).
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