Abstract:
Hydrocarbon processing apparatuses and processes for producing n-pentane and isobutane are provided herein. In an embodiment, a process for producing n-pentane and isobutane includes providing a hydrocarbon feed stream that includes C4 and C5 hydrocarbons. A recycle stream that includes C4+ hydrocarbons and the hydrocarbon feed stream is combined to produce a combined feed stream. The combined feed stream is separated to produce an iC4 product stream, an nC5+ product stream, and an iC5/nC4 feed stream. The iC5/nC4 feed stream is simultaneously disproportionated and isomerized in an isomerization zone to produce an intermediate stream that includes C3-C6 hydrocarbons. The C3-C6 hydrocarbons in the intermediate stream are separated to produce a C3− stream and the recycle stream that includes C4+ hydrocarbons.
Abstract:
A process for producing a feed for a stream cracker. At least a portion of the C6 cyclic hydrocarbons are removed from a stream prior to it being passed into an isomerization zone. Disproportionation reaction selectivity is increased, producing valuable C3 hydrocarbons and C4 hydrocarbons. Also, a higher ring opening conversion of C5 cyclic hydrocarbons is observed. The yield may be adjusted by controlling an amount of C6 cyclic hydrocarbons passed to the isomerization zone. The catalyst in the isomerization zone is free of chloride, and the streams including effluent from the isomerization zone may be passed to a steam cracker without requiring chloride removal.
Abstract:
A riser includes a housing in communication with a entry conduit and an exit conduit. The housing is defined by a holdup chamber having a volume of between about 1133 liters and about 45307 liters. The riser is designed to receive a hydrocarbon feed and a catalyst. An apparatus for fluid catalytic cracking includes a riser in fluid communication with a reactor vessel. A hydrocarbon feed stream and a catalyst travel through a first section of the riser at a first velocity of between about 1.5 msec to about 10 msec and through a second section of the riser at a second velocity of more than about 15 msec. A process for fluid catalytic cracking uses a riser with a holdup chamber. A hydrocarbon feed and a catalyst decrease in velocity in the holdup chamber to between 1.5 msec and 10 msec.
Abstract:
A process for transalkylating a coal tar stream is described. A coal tar stream is provided, and is fractionated to provide at least one hydrocarbon stream having polycyclic aromatics. The hydrocarbon stream is hydrotreated in a hydrotreating zone, and then hydrocracked in a hydrocracking zone. A light aromatics stream is added to the hydrocracking zone. The light aromatics stream comprises one or more light aromatics having a ratio of methyl/aromatic available position that is lower than a ratio of methyl/aromatic available position for the hydrotreated stream. The hydrocracked stream is transalkylated in the hydrocracking zone.
Abstract:
A process for transalkylating a coal tar stream is described. A coal tar stream is provided, and is fractionated to provide at least one hydrocarbon stream having polycyclic aromatics. The hydrocarbon stream is hydrotreated in a hydrotreating zone, and then hydrocracked in a hydrocracking zone. A light aromatics stream is added to the hydrocracking zone. The light aromatics stream comprises one or more light aromatics having a ratio of methyl/aromatic available position that is lower than a ratio of methyl/aromatic available position for the hydrotreated stream. The hydrocracked stream is transalkylated in the hydrocracking zone.
Abstract:
A process for providing aromatics from a coal tar stream. A coal tar stream is provided, and the coal tar stream is fractionated into at least a naphtha range stream. The naphtha range stream is hydrotreated, and the hydrotreated naphtha range stream is separated to provide at least a naphthene rich stream. The naphthene rich stream is reformed or dehydrogenated to convert the naphthene. The dehydrogenated naphthene rich stream may be combined with a portion of a reformed crude oil hydrocarbon stream.
Abstract:
A process for pyrolyzing a coal feed is described. The coal feed is pyrolyzed into a coal tar stream and a coke stream in a pyrolysis zone. The coal tar stream is fractionated into at least a pitch stream. The pitch stream is hydrogenated, and the hydrogenated pitch stream is recycled into the pyrolysis zone. The hydrocarbon stream may be processed further by at least one of hydrotreating, hydrocracking, fluid catalytic cracking, alkylation, and transalkylation.
Abstract:
A process for gasifying and pyrolyzing coal is described. A first coal feed is pyrolyzed into a coal tar stream and a coke stream in a pyrolysis zone. A second coal feed is gasified in a gasification zone to produce an effluent stream. Contaminants are removed from the effluent stream to provide a purified effluent stream. The purified effluent stream is introduced to the pyrolysis zone.
Abstract:
A counter-current catalyst regenerator with at least two stages of counter-current contact along with a regenerator riser is proposed. Each stage may comprise a permeable barrier that allows upward passage of oxygen-containing gas and downward passage of coked catalyst into each stage, but inhibits upward movement of catalyst to mitigate back mixing and approximate true counter-current contact and efficient combustion of coke from catalyst. The regenerator riser may provide a passage to transport the catalyst and may serve as a secondary stage for coke combustion to provide the regenerated catalyst.
Abstract:
A counter-current catalyst regenerator with at least two stages of counter-current contact along with a regenerator riser is proposed. Each stage may comprise a permeable barrier that allows upward passage of oxygen-containing gas and downward passage of coked catalyst into each stage, but inhibits upward movement of catalyst to mitigate back mixing and approximate true counter-current contact and efficient combustion of coke from catalyst. The regenerator riser may provide a passage to transport the catalyst and may serve as a secondary stage for coke combustion to provide the regenerated catalyst.