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    PHOSPHINIC VANADIUM COMPLEX, CATALYTIC SYSTEM COMPRISING SAID PHOSPHINIC VANADIUM COMPLEX AND PROCESS FOR THE (CO) POLYMERIZATION OF CONJUGATED DIENES
    13.
    发明申请
    PHOSPHINIC VANADIUM COMPLEX, CATALYTIC SYSTEM COMPRISING SAID PHOSPHINIC VANADIUM COMPLEX AND PROCESS FOR THE (CO) POLYMERIZATION OF CONJUGATED DIENES 有权

    公开(公告)号：US20220177500A1

    公开(公告)日：2022-06-09

    申请号：US17556199

    申请日：2021-12-20

    Applicant: Versalis S.p.A.

    Inventor： Giovanni RICCI ,  Giuseppe LEONE ,  Anna SOMMAZZI ,  Alessandra FORNI ,  Francesco MASI

    IPC: C07F9/50 ,  C07F9/46 ,  C08F136/06 ,  C08F4/68 ,  C08F4/76 ,  C08F10/06 ,  C08F10/08 ,  C08F4/20 ,  C08F10/00

    Abstract: Vanadium phosphinic complex having general formula (I) or (II): V(X)3[P(R1)n(R2)3-n]2  (I) V(X)3[(R3)2P(R4)P(R3)2]  (II) wherein: X represents an anion selected from halogens; or is selected from the following groups: thiocyanate, isocyanate, sulfate, acid sulfate, phosphate, acid phosphate, carboxylate, dicarboxylate; R1, identical or different among them, represent a hydrogen atom, or an allyl group (CH2═CH—CH2—); or are selected from alkyl groups C1-C20, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups; n is an integer ranging from 0 to 3; R2, identical or different among them, are selected from optionally substituted aryl groups; R3, identical or different among them, represent a hydrogen atom, or an allyl group (CH2═CH—CH2—); or are selected from alkyl groups C1-C20, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R4 represents a group —NR5 wherein R5 represents a hydrogen atom, or is selected from C1-C20 alkyl groups, linear or branched; or R4 represents an alkylene group —(CH2)p- wherein p represents an integer ranging from 1 to 5; provided that in the general formula (I), in case n is equal to 1 and R1 is methyl, R2 is different from phenyl. Said phosphinic vanadium complex having general formula (I) or (II) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.

    PHOSPHINIC VANADIUM COMPLEX, CATALYTIC SYSTEM COMPRISING SAID PHOSPHINIC VANADIUM COMPLEX AND PROCESS FOR THE (CO) POLYMERIZATION OF CONJUGATED DIENES
    14.
    发明申请
    PHOSPHINIC VANADIUM COMPLEX, CATALYTIC SYSTEM COMPRISING SAID PHOSPHINIC VANADIUM COMPLEX AND PROCESS FOR THE (CO) POLYMERIZATION OF CONJUGATED DIENES 审中-公开

    公开(公告)号：US20190194233A1

    公开(公告)日：2019-06-27

    申请号：US16243686

    申请日：2019-01-09

    Applicant: Versalis S.p.A.

    Inventor： Giovanni RICCI ,  Giuseppe LEONE ,  Anna SOMMAZZI ,  Alessandra FORNI ,  Francesco MASI

    IPC: C07F9/50 ,  C08F10/08 ,  C08F10/06 ,  C08F4/76 ,  C07F9/46 ,  C08F4/68 ,  C08F4/20 ,  C08F10/00

    CPC classification number: C07F9/5045 ,  C07F9/46 ,  C08F4/20 ,  C08F4/68 ,  C08F4/68086 ,  C08F4/76 ,  C08F10/00 ,  C08F10/06 ,  C08F10/08 ,  C08F136/06

    Abstract: Vanadium phosphinic complex having general formula (I) or (II): V(X)3[P(R1)n(R2)3-n]2  (I) V(X)3[(R3)2P(R4)P(R3)2]  (II) wherein: X represents an anion selected from halogens such as, for example, chlorine, bromine, iodine, preferably chlorine; or is selected from the following groups: thiocyanate, isocyanate, sulfate, acid sulfate, phosphate, acid phosphate, carboxylate, dicarboxylate; R1, identical or different among them, represent a hydrogen atom, or an allyl group (CH2═CH—CH2—); or are selected from alkyl groups C1-C20, preferably C1-C15, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups; n is an integer ranging from 0 to 3; R2, identical or different among them, are selected from optionally substituted aryl groups; R3, identical or different among them, represent a hydrogen atom, or an allyl group (CH2═CH—CH2—); or are selected from alkyl groups C1-C20, preferably C1-C15, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R4 represents a group —NR5 wherein R5 represents a hydrogen atom, or is selected from C1-C20 alkyl groups, preferably C1-C15, linear or branched; or R4 represents an alkylene group —(CH2) p- wherein p represents an integer ranging from 1 to 5; provided that in the general formula (I), in case n is equal to 1 and R1 is methyl, R2 is different from phenyl. Said phosphinic vanadium complex having general formula (I) or (II) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.

    VANADIUM PYRIDINE-IMINE COMPLEX, CATALYTIC SYSTEM COMPRISING SAID VANADIUM PYRIDINE-IMMINE COMPLEX AND A (CO) POLYMERIZATION PROCESS OF CONJUGATED DIENES
    15.
    发明申请
    VANADIUM PYRIDINE-IMINE COMPLEX, CATALYTIC SYSTEM COMPRISING SAID VANADIUM PYRIDINE-IMMINE COMPLEX AND A (CO) POLYMERIZATION PROCESS OF CONJUGATED DIENES 审中-公开

    公开(公告)号：US20180282458A1

    公开(公告)日：2018-10-04

    申请号：US15765782

    申请日：2016-11-10

    Applicant: versalis S.p.A

    Inventor： Giovanni RICCI ,  Giuseppe LEONE ,  Anna SOMMAZZI ,  Francesco MASI

    IPC: C08F236/08 ,  C08F236/06 ,  C07F9/00

    Abstract: Vanadium pyridine-imine complex having general formula (I), wherein:—R1, R2, R3, R4, R5 and R6, equal to or different from each other, represent a hydrogen atom; or are selected from linear or branched C1-C20 alkyl groups, preferably C1-C15, optionally halogenated cycloalkyl groups optionally substituted, aryl groups optionally substituted;—X1, X2 and X3, equal to or different from each other, represent a halogen atom such as, for example, chlorine, bromine, iodine, preferably chlorine; or are selected from linear or branched C1-C20 alkyl groups, preferably C1-C15, —OCOR7 groups or —OR7 groups wherein R7 is selected from linear or branched C1-C20 alkyl groups, preferably C1-C15;—Y is selected from ethers such as, for example, diethylether, tetrahydrofuran (THF), dimethoxyethane, preferably is etrahydrofuran (THF);—n is 0 or 1. Said vanadium pyridine-imine complex having general formula (I) can be advantageously used in a catalytic system for the (co) polymerization of conjugated dienes.

    PHOSPHINIC VANADIUM COMPLEX, CATALYTIC SYSTEM COMPRISING SAID PHOSPHINIC VANADIUM COMPLEX AND PROCESS FOR THE (CO) POLYMERIZATION OF CONJUGATED DIENES
    17.
    发明申请
    PHOSPHINIC VANADIUM COMPLEX, CATALYTIC SYSTEM COMPRISING SAID PHOSPHINIC VANADIUM COMPLEX AND PROCESS FOR THE (CO) POLYMERIZATION OF CONJUGATED DIENES 审中-公开

    公开(公告)号：US20170275312A1

    公开(公告)日：2017-09-28

    申请号：US15518556

    申请日：2015-11-24

    Applicant: Versalis S.p.A.

    Inventor： Giovanni RICCI ,  Giuseppe LEONE ,  Anna SOMMAZZI ,  Alessandra FORNI ,  Francesco MASI

    IPC: C07F9/50 ,  C08F10/08 ,  C08F10/06 ,  C08F4/76

    CPC classification number: C07F9/5045 ,  C07F9/46 ,  C08F4/20 ,  C08F4/68 ,  C08F4/68086 ,  C08F4/76 ,  C08F10/00 ,  C08F10/06 ,  C08F10/08 ,  C08F136/06

    Abstract: Vanadium phosphinic complex having general formula (I) or (II): V(X)M3P̂WFys-nMO V(X)3[(R3)2P(R4)P(R3)2] (ID wherein: X represents an anion selected from halogens such as, for example, chlorine, bromine, iodine, preferably chlorine; or is selected from the following groups: thiocyanate, isocyanate, sulfate, acid sulfate, phosphate, acid phosphate, carboxylate, dicarboxylate; Ri, identical or different among them, represent a hydrogen atom, or an allyl group (CH2=CH—CH2-); or are selected from alkyl groups CrC2o, preferably CrĈ, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups; —n is an integer ranging from 0 to 3; R2, identical or different among them, are selected from optionally substituted aryl groups; R3, identical or different among them, represent a hydrogen atom, or an allyl group (CH2=CH—CH2-); or are selected from alkyl groups C1-C2o, preferably CrĈ, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R4 represents a group —NR5 wherein R5 represents a hydrogen atom, or is selected from C1-C20 alkyl groups, preferably CrC15, linear or branched; or R4 represents an alkylene group —(CH2) p- wherein p represents an integer ranging from 1 to 5; provided that in the general formula (I), in case n is equal to 1 and Ri is methyl, R2 is different from phenyl. Said phosphinic vanadium complex having general formula (I) or (II) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.

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