Methods of surface treating porous particles
    18.
    发明授权
    Methods of surface treating porous particles 有权
    表面处理多孔颗粒的方法

    公开(公告)号:US09078946B2

    公开(公告)日:2015-07-14

    申请号:US13504984

    申请日:2010-11-23

    Abstract: A method of treating porous particles, each porous particle having an external surface and a multiplicity of pores with interior pore surfaces, by contacting the external surface with a hydrophobic agent while causing the interior pore surfaces to remain substantially free of the hydrophobic agent. In certain illustrative embodiments, treating the external surfaces of the porous particles includes exposing the porous particles to at least one of water vapor, methanol vapor, or ethanol vapor; and subsequently exposing the porous particles to a second vapor comprising a reactive organosilane compound which reacts to form the hydrophobic agent. In some particular illustrative embodiments, at least a portion of the external surface of the treated porous particle includes hydrophobic groups, the hydrophobic groups selected from at least one of alkyl or aryl groups optionally substituted with fluorine, and siloxanes having alkyl groups, aryl groups, or combinations thereof.

    Abstract translation: 一种处理多孔颗粒的方法,每个多孔颗粒具有外表面和具有内孔表面的多个孔,通过使外表面与疏水剂接触,同时使内孔表面基本上不含疏水剂。 在某些示例性实施例中,处理多孔颗粒的外表面包括将多孔颗粒暴露于水蒸气,甲醇蒸气或乙醇蒸气中的至少一种; 随后将多孔颗粒暴露于包含反应性有机硅烷化合物的第二蒸气中,所述反应性有机硅烷化合物反应形成疏水剂。 在一些具体的说明性实施方案中,经处理的多孔颗粒的外表面的至少一部分包括疏水基团,选自任选被氟取代的烷基或芳基中的至少一个的疏水基团和具有烷基的硅氧烷,芳基, 或其组合。

    MEMBRANES
    20.
    发明申请
    MEMBRANES 审中-公开
    膜片

    公开(公告)号:US20140212940A1

    公开(公告)日:2014-07-31

    申请号:US14119723

    申请日:2011-05-25

    Abstract: Mixed matrix pervaporation membranes are described which include i) a matrix phase comprising a polymeric material, and ii) a zeolitic imidazolate framework (ZIF) dispersed in the matrix phase. In membranes described, the thickness of the membrane is greater than 0.5 μm. The membranes may in examples be used in a process for separating an organic compound from an aqueous liquid mixture. An example process includes contacting the liquid mixture on one side of a mixed matrix pervaporation membrane to cause the organic compound to permeate the mixed matrix membrane, and removing from the other side of the membrane a permeate composition comprising a portion of the organic compound which permeated the membrane. Example membranes described have relatively good selectivity for separation of the organic compound from the liquid mixture.

    Abstract translation: 描述了混合基质渗透蒸发膜,其包括i)包含聚合物材料的基质相,和ii)分散在基质相中的沸石咪唑化物骨架(ZIF)。 在所述的膜中,膜的厚度大于0.5μm。 膜可以用于从含水液体混合物中分离有机化合物的方法。 示例性方法包括使混合基质渗透蒸发膜的一侧上的液体混合物接触,以使有机化合物渗透到混合基质膜中,并从膜的另一侧除去渗透物组合物,该渗透物组合物包含渗透的一部分有机化合物 膜。 所述实施例的膜对于从液体混合物中分离有机化合物具有相当好的选择性。

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