公开(公告)号：US20170022310A1

公开(公告)日：2017-01-26

申请号：US15301137

申请日：2015-03-10

Applicant: Univation Technologies, LLC

Inventor： Richard B. Pannell ,  David M. Glowczwski ,  Chi-I Kuo ,  Timothy R. Lynn ,  F. David Hussein ,  Phuong A. Cao ,  Wesley R. Mariott ,  Michael D. Awe

IPC: C08F210/16

CPC classification number: C08F210/16 ,  B01J31/0202 ,  B01J31/0237 ,  B01J31/0271 ,  B01J31/04 ,  B01J31/1805 ,  B01J31/2295 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F2410/01 ,  C08F2410/02 ,  C08F2/005 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/07

Abstract: Continuity compositions are provided as are methods of their preparation. The compositions comprise at least one metal carboxylate salt which is modified with at least one molten fatty amine. These compositions find advantageous use in olefin polymerization processes.

Abstract translation: 连续性组合物的制备方法也是如此。 组合物包含至少一种金属羧酸盐，其被至少一种熔融脂肪胺改性。 这些组合物在烯烃聚合方法中有利地使用。

公开(公告)号：US09469658B2

公开(公告)日：2016-10-18

申请号：US13983718

申请日：2012-02-05

Applicant: Zengquan Qin ,  Steven Luo ,  Joshua S. Dickstein

Inventor： Zengquan Qin ,  Steven Luo ,  Joshua S. Dickstein

IPC: C08F4/54 ,  C07F5/00 ,  C08F36/06 ,  C08F4/52 ,  C08F136/06 ,  C08F236/06

CPC classification number: C07F5/003 ,  B01J31/1805 ,  B01J31/2243 ,  B01J2531/0252 ,  B01J2531/37 ,  B01J2531/38 ,  C08F4/52 ,  C08F4/545 ,  C08F36/06 ,  C08F136/06 ,  C08F236/06

Abstract: A novel class of lanthanide metal salen complexes can be used as an ingredient of a catalyst system. The catalyst system can be used in polymerizations of ethylenically unsaturated hydrocarbon monomers.

Abstract translation: 一类新型的镧系元素金属盐配合物可用作催化剂体系的成分。 催化剂体系可用于烯属不饱和烃单体的聚合。

公开(公告)号：US09468919B2

公开(公告)日：2016-10-18

申请号：US14940643

申请日：2015-11-13

Applicant: Takasago International Corporation

Inventor： Taichiro Touge ,  Hideki Nara ,  Tomohiko Hakamada

IPC: C07F15/00 ,  C07C303/40 ,  C07C311/20 ,  C07C311/07 ,  C07C311/08 ,  C07C29/145 ,  B01J31/18 ,  C07C29/143 ,  C07C209/52 ,  C07C253/30 ,  C07D307/42 ,  C07D311/22 ,  C07F19/00 ,  B01J31/22

CPC classification number: B01J31/1805 ,  B01J31/2295 ,  B01J2231/326 ,  B01J2231/643 ,  B01J2231/646 ,  B01J2531/0208 ,  B01J2531/821 ,  B01J2540/32 ,  C07C29/143 ,  C07C209/52 ,  C07C253/30 ,  C07D307/42 ,  C07D311/22 ,  C07F15/0046 ,  C07F19/00 ,  H01L2924/0002 ,  H01L2924/00

Abstract: Provided is a catalyst for asymmetric reduction, which can be produced by a convenient and safe production method, has a strong catalytic activity, and has excellent stereoselectivity. The present invention relates to a ruthenium complex represented by the following formula (1): wherein R1 represents an alkyl group or the like; Y represents a hydrogen atom; X represents a halogen atom or the like; j and k each represent 0 or 1; R2 and R3 each represent an alkyl group or the like; R11 to R19 each represent a hydrogen atom, an alkyl group or the like; Z represents oxygen or sulfur; n1 represents 1 or 2; and n2 represents an integer from 1 to 3, a method for producing the ruthenium complex, a catalyst for asymmetric reduction formed from the ruthenium complex, and methods for selectively producing an optically active alcohol and an optically active amine using the catalyst for asymmetric reduction.

公开(公告)号：US20160222141A1

公开(公告)日：2016-08-04

申请号：US15097355

申请日：2016-04-13

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Qing Yang ,  Randy S. Muninger ,  Elizabeth A. Benham ,  Kathy S. Clear

IPC: C08F110/02

CPC classification number: C08F210/16 ,  B01J27/00 ,  B01J27/053 ,  B01J27/10 ,  B01J27/12 ,  B01J27/16 ,  B01J31/143 ,  B01J31/1608 ,  B01J31/1616 ,  B01J31/1805 ,  B01J31/2226 ,  B01J31/2295 ,  B01J35/0006 ,  B01J2531/0225 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/02 ,  C08F110/02 ,  C08F210/06 ,  C08F210/08 ,  C08F2420/01 ,  Y02P20/52 ,  C08F4/025 ,  C08F4/65916 ,  C08F210/14

Abstract: Silica-coated alumina activator-supports, and catalyst compositions containing these activator-supports, are disclosed. Methods also are provided for preparing silica-coated alumina activator-supports, for preparing catalyst compositions, and for using the catalyst compositions to polymerize olefins.

Abstract translation: 公开了二氧化硅涂覆的氧化铝活化剂 - 载体和含有这些活化剂 - 载体的催化剂组合物。 提供了用于制备二氧化硅涂覆的氧化铝活化剂 - 载体，用于制备催化剂组合物和使用催化剂组合物聚合烯烃的方法。

公开(公告)号：US20160200746A1

公开(公告)日：2016-07-14

申请号：US14986928

申请日：2016-01-04

Applicant: REGENTS OF THE UNIVERSITY OF MINNESOTA

Inventor： Ian A. Tonks ,  Zachary W. Gilbert

IPC: C07F7/28 ,  C07D207/323 ,  C07F7/08 ,  C07D209/44 ,  C07D207/333 ,  B01J31/18 ,  C07D209/52

CPC classification number: C07F7/28 ,  B01J31/1805 ,  B01J2231/321 ,  B01J2231/324 ,  B01J2531/46 ,  C07D207/323 ,  C07D207/333 ,  C07D209/44 ,  C07D209/52 ,  C07F7/0814

Abstract: The present disclosure provides Titanium (IV) compounds and methods of making heterocyclic compounds such as pyrroles using Titanium (IV) compounds. In certain embodiments, the Titanium (IV) compound is present in catalytic amounts.

Abstract translation: 本公开提供钛（IV）化合物和使用钛（IV）化合物制备杂环化合物如吡咯的方法。 在某些实施方案中，钛（IV）化合物以催化量存在。

公开(公告)号：US20160200726A1

公开(公告)日：2016-07-14

申请号：US14913736

申请日：2014-08-14

Applicant: NIPPON SODA CO., LTD.

Inventor： Masaya AKASHI ,  Tsutomu INOUE ,  Hirohito OOOKA

IPC: C07D471/08

CPC classification number: C07D471/08 ,  B01J31/1805 ,  B01J31/1815 ,  B01J31/189 ,  B01J31/24 ,  B01J31/2409 ,  B01J31/2447 ,  B01J2231/643 ,  B01J2531/821 ,  C07B53/00 ,  C07D451/14

Abstract: A 9-azabicyclo[3.3.1]nonan-3-one derivative is reacted with a hydrogen in the presence of a catalyst composed of a ruthenium complex to obtain, at a low cost, an endo-9-azabicyclo[3.3.1]nonan-3-ol derivative useful as a production intermediate for agrochemical agents or medicines.

Abstract translation: 在由钌络合物组成的催化剂存在下，将9-氮杂双环[3.3.1]壬-3-酮衍生物与氢气反应，以低成本获得内-9-氮杂双环[3.3.1] 壬烷-3-醇衍生物，可用作农药或药物的生产中间体。

公开(公告)号：US09364822B2

公开(公告)日：2016-06-14

申请号：US13930736

申请日：2013-06-28

Applicant: Rohm and Haas Electronic Materials LLC

Inventor： Kristen M. Milum ,  Donald E. Cleary ,  Maria Anna Rzeznik

IPC: C23C18/18 ,  B01J31/18 ,  C23C18/20 ,  C23C18/30 ,  B01J31/28 ,  C23C18/32 ,  C23C18/38 ,  B01J31/22 ,  B01J31/02 ,  C23C18/16

CPC classification number: B01J31/1805 ,  B01J31/0247 ,  B01J31/2243 ,  B01J31/28 ,  B01J2531/17 ,  B01J2531/824 ,  B01J2531/828 ,  C23C18/1653 ,  C23C18/1837 ,  C23C18/1844 ,  C23C18/1886 ,  C23C18/2073 ,  C23C18/208 ,  C23C18/2086 ,  C23C18/30 ,  C23C18/32 ,  C23C18/38

Abstract: Catalysts include five-membered nitrogen containing heterocyclic compounds as ligands for metal ions which have catalytic activity. The catalysts are used to electrolessly plate metal on metal clad and un-clad substrates.

Abstract translation: 催化剂包括五元含氮杂环化合物作为具有催化活性的金属离子的配体。 催化剂用于在金属包覆和非包层基板上无电镀金属。

公开(公告)号：US09315755B2

公开(公告)日：2016-04-19

申请号：US14118172

申请日：2012-04-23

Applicant: Yong Tang ,  Wenjie Tao ,  Xiuli Sun ,  Junfang Li ,  Zheng Wang

Inventor： Yong Tang ,  Wenjie Tao ,  Xiuli Sun ,  Junfang Li ,  Zheng Wang

IPC: C10M105/04 ,  B01J31/22 ,  B01J31/18 ,  C07C323/45 ,  C07C251/08 ,  C07C251/20 ,  C10G45/48 ,  C10G45/52 ,  C10G50/00 ,  C10G69/12 ,  C08F10/00 ,  C07F15/04 ,  C07C251/24

CPC classification number: C10M105/04 ,  B01J31/1805 ,  B01J31/2295 ,  B01J2231/20 ,  B01J2531/824 ,  B01J2531/847 ,  B01J2540/225 ,  B01J2540/30 ,  C07C251/08 ,  C07C251/20 ,  C07C251/24 ,  C07C323/45 ,  C07C2603/20 ,  C07C2603/26 ,  C07F15/04 ,  C07F15/045 ,  C08F8/04 ,  C08F10/00 ,  C08F110/02 ,  C08F110/08 ,  C10G45/48 ,  C10G45/52 ,  C10G50/00 ,  C10G50/02 ,  C10G69/126 ,  C10G2300/1088 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/10 ,  C10M107/10 ,  C10M177/00 ,  C10M2205/028 ,  C10M2205/0285 ,  C10N2270/00 ,  C08F4/7006 ,  C08F2500/02 ,  C08F2500/10 ,  C08F2500/17 ,  C08F110/06

Abstract: The present invention discloses a catalytic system for preparing highly branched alkane from olefin, which contains novel nickel or palladium complexes. In the presence of the catalytic system, highly branched oily alkane mixture can be efficiently obtained from olefins (such as ethylene) under mild conditions. The alkane mixture has a low bromine number, and can be used as a processing aid(s) and lubricant base oil with high-performance. Provides also was a method for preparing the catalyst and a method for preparing an oily olefin polymer.

Abstract translation: 本发明公开了一种由烯烃制备高分支烷烃的催化体系，其中含有新的镍或钯络合物。 在催化体系的存在下，在温和条件下，可以从烯烃（如乙烯）中有效地获得高度支化的油状烷烃混合物。 烷烃混合物具有低溴值，可用作加工助剂和具有高性能的润滑剂基础油。 也提供了制备催化剂的方法和制备油性烯烃聚合物的方法。

公开(公告)号：US09284336B1

公开(公告)日：2016-03-15

申请号：US14966769

申请日：2015-12-11

Applicant: Kenneth K. Laali

Inventor： Kenneth K. Laali

IPC: C07C323/31 ,  C07F5/02 ,  C07C67/00 ,  C07C381/00 ,  B01J31/02 ,  B01J31/18

CPC classification number: C07F5/022 ,  B01J31/0204 ,  B01J31/0275 ,  B01J31/1805 ,  B01J2231/4283 ,  C07C67/00 ,  C07C323/31 ,  C07C381/00 ,  C07D249/06

Abstract: 4-(pentafluorosulfanyl)benzenediazonium tetrafluoroborate salt was synthesized and isolated. The pentafluorosulfanyl salt was examined in a wide assortment of reactions to form novel SF5-bearing alkenes, alkynes, and biaryl derivatives using Heck-Matsuda, Sonogashira, and Suzuki coupling protocols. Dediazoniation of the salt furnished the corresponding p-SF5—C6H4X, C6H4OS(O)(CF3)═NSO2CF3, and p-SF5—C6H4—NTf2 derivatives. The azide derivative p-SF5—C6H4N3 entered into click chemistry with phenylacetylenes to furnish the corresponding triazoles. Various SF5-bearing alkenes were synthesized by coupling reactions using a metal catalyst. Fluorodediazoniation selectively furnished the fluoro derivative p-SF5—C6H4F. Homolytic dediazoniation gave the unsymmetrical biaryls, thus demonstrating the broad utility of pentafluorosulfanyl diazonium salts as building blocks of SF5-aromatics that are in high demand in many branches of chemistry including biomedicine and materials chemistry.

Abstract translation: 合成并分离出4-（五氟硫烷基）苯二氮鎓四氟硼酸盐。 使用Heck-Matsuda，Sonogashira和Suzuki偶联方案，在各种各样的反应中检查五氟硫烷基盐以形成新的含SF5的烯烃，炔烃和联芳基衍生物。 盐的淡化提供相应的对应的SF-C6H4X，C6H4OS（O）（CF3）= NO2O2CF3和p-SF5-C6H4-NTf2衍生物。 叠氮衍生物p-SF5-C6H4N3与苯乙炔进行点击化学反应，得到相应的三唑。 通过使用金属催化剂的偶联反应合成了各种含SF5的烯烃。 氟代氮化选择性提供氟衍生物p-SF5-C6H4F。 均相脱氮化得到不对称的联芳基，从而证明五氟硫烷基重氮盐作为SF5芳族化合物的结构单元的广泛用途，其在包括生物医学和材料化学在内的许多化学分支中具有高需求。

公开(公告)号：US20160038925A1

公开(公告)日：2016-02-11

申请号：US14921220

申请日：2015-10-23

Applicant: Rohm and Haas Electronic Materials LLC

Inventor： Kristen M. Milum ,  Donald E. Cleary ,  Maria A. Rzeznik

IPC: B01J31/18

CPC classification number: B01J31/1805 ,  B01J31/0247 ,  B01J31/2243 ,  B01J31/28 ,  B01J2531/17 ,  B01J2531/824 ,  B01J2531/828 ,  C23C18/1653 ,  C23C18/1837 ,  C23C18/1844 ,  C23C18/1886 ,  C23C18/2073 ,  C23C18/208 ,  C23C18/2086 ,  C23C18/30 ,  C23C18/32 ,  C23C18/38

Abstract: Catalysts include five-membered nitrogen containing heterocyclic compounds as ligands for metal ions which have catalytic activity. The catalysts are used to electrolessly plate metal on metal clad and un-clad substrates.