公开(公告)号：US5529760A

公开(公告)日：1996-06-25

申请号：US355043

申请日：1994-12-13

Applicant: William A. Burris

Inventor： William A. Burris

IPC: B01J19/08 ,  C01B13/11 ,  B01J19/00

CPC classification number: C01B13/11 ,  B01J19/088 ,  B01J2219/0849 ,  C01B2201/12 ,  C01B2201/24 ,  C01B2201/32 ,  C01B2201/34 ,  Y10S422/907

Abstract: A corona discharge ozone generator has an inter-electrode gap established by dielectric spacers that engage gap confronting surfaces and are distributed in the gap so that the electrodes need not be self-supporting. Also, gas flow impedance material, which can include the gap spacers, is distributed in the gap to ensure substantially uniform flow of an oxygen containing gas.

Abstract translation: 电晕放电臭氧发生器具有通过介电间隔物建立的电极间隙，该电介质间隔件接合间隙面对面并分布在间隙中，使得电极不需要自支撑。 此外，可以包括间隙隔离物的气流阻抗材料分布在间隙中以确保含氧气体的基本上均匀的流动。

公开(公告)号：US5516493A

公开(公告)日：1996-05-14

申请号：US964082

申请日：1992-10-20

Applicant: Maxwell G. Bell ,  Stephen J. Smith ,  David T. Pratt ,  Matthew P. Sharpe ,  Dale C. Cable

Inventor： Maxwell G. Bell ,  Stephen J. Smith ,  David T. Pratt ,  Matthew P. Sharpe ,  Dale C. Cable

IPC: C01B13/11 ,  C02F1/78

CPC classification number: C01B13/11 ,  C01B2201/14 ,  C01B2201/22 ,  C01B2201/34 ,  C01B2201/64 ,  C01B2201/66 ,  C02F1/78 ,  Y10S422/907

Abstract: The present invention relates to a tubular ozone generator which uses a novel electrode structure wherein a wound electrode has a solid insulator between the turns of the windings.

Abstract translation: PCT No.PCT / AU92 / 00061 Sec。 371日期：1993年1月29日 102（e）日期1993年1月29日PCT提交1992年2月21日PCT公布。 WO92 / 14677 PCT出版物 本发明涉及一种管状臭氧发生器，其使用新颖的电极结构，其中绕组电极在绕组匝之间具有固体绝缘体。

公开(公告)号：US5316639A

公开(公告)日：1994-05-31

申请号：US989480

申请日：1992-12-07

Applicant: Sachiko Okazaki ,  Masuhiro Kogoma ,  Masahiro Hirakawa

Inventor： Sachiko Okazaki ,  Masuhiro Kogoma ,  Masahiro Hirakawa

IPC: C01B13/11 ,  C23C16/34 ,  C23C16/40 ,  C23C14/00

CPC classification number: C01B13/11 ,  C23C16/345 ,  C23C16/402 ,  C01B2201/12 ,  C01B2201/14 ,  C01B2201/34

Abstract: This invention concerns a SiO.sub.2, SiN.sub.x protection film formed by a CVD or PVD gas phase glowing method capable of preventing melting of the matrix ingredients at the surface of a dielectric material in electric discharge of an ozone generator and it relates to a dielectric material used for an ozone generator capable of overcoming the problems for the abrasion of electrode and dielectric material or melting of ions or molecules of during electric discharge, as well as a method of forming a protection film therefor based on the finding that an SiO.sub.2 film or SiN.sub.x film can be formed easily on a surface of a predetermined electric material or, further, on a surface of electrode by processing a specific reaction gas, for example, comprising a crude gas such as SiH.sub.4, SiCl.sub.4, N.sub.2, NH.sub.3 or TEOS or further incorporated with an inert gas or like by means of an atmospheric CVD process such as CVD or heat CVD and, in particular, on the finding that the protection film can be disposed directly to the surface of the dielectric material and the electrode in an ozone generator after the completion of assembling.

Abstract translation: 本发明涉及通过CVD或PVD气相发光法形成的SiO 2，SiN x保护膜，其能够防止在臭氧发生器的放电中电介质材料的表面处的基体成分熔化，并且涉及用于 能够克服电极和介电材料的磨损或放电期间的离子或分子熔化的问题的臭氧发生器，以及形成保护膜的方法基于SiO 2膜或SiN x膜可以 可以容易地形成在预定电材料的表面上，或者通过加工特定的反应气体，例如包含诸如SiH 4，SiCl 4，N 2，NH 3或TEOS的粗气体，或进一步与 惰性气体或类似物，通过诸如CVD或热CVD的大气CVD工艺，并且特别地，基于保护膜可以直接设置在sur 在组装完成后的臭氧发生器中的电介质材料和电极的表面。

公开(公告)号：US5254317A

公开(公告)日：1993-10-19

申请号：US669939

申请日：1991-03-15

Applicant: Melchior Fischer ,  Paul Kostinger

Inventor： Melchior Fischer ,  Paul Kostinger

IPC: C01B13/11 ,  B01J19/12

CPC classification number: C01B13/11 ,  C01B2201/14 ,  C01B2201/32 ,  C01B2201/34

Abstract: In an ozone generator, spring elements (5) of metal pointing transversely to the longitudinal direction of the tube are provided for spacing the dielectric (3) from the metallic outer electrode (1). These spring elements are either bonded directly to the dielectric (3) and are stuck onto a tape-shaped carrier which is attached to the dielectric (3) and at their free ends rest against the inside wall of the outer electrode (1). In this manner, the discharge gap is only minimally constricted and the assembly of the inner tubes (2a, 2b) is simplified.

Abstract translation: 在臭氧发生器中，提供横向于管的纵向方向的金属弹簧元件（5），用于将电介质（3）与金属外电极（1）间隔开。 这些弹簧元件或者直接结合到电介质（3）上，并且被粘贴到附着到电介质（3）上并且其自由端靠在外电极（1）的内壁上的带状载体上。 以这种方式，放电间隙仅被最小限度地缩小并且内管（2a，2b）的组装被简化。

公开(公告)号：US5147614A

公开(公告)日：1992-09-15

申请号：US515440

申请日：1990-04-27

Applicant: Richard H. Conrad

Inventor： Richard H. Conrad

IPC: C01B13/11

CPC classification number: C01B13/11 ,  C01B2201/14 ,  C01B2201/34 ,  C01B2201/74

Abstract: A self-contained and self-supporting cell for generating ozone by corona discharge which consists basically of two open-ended straight tubes. An inner metal tube serves as a first electrode and is cooled by a fluid flowing through its core. An outer glass or ceramic tube concentrically surrounds and is shorter than the inner tube, carries a second electrode on its outer surface, and is cooled by a flow of fluid across its outer surface. The inner metal tube serves as a supporting column on which all other components are mounted and aligned. It carries a collar near each of its ends, and across each collar are clamped outer end-pieces carrying coolant seals and fittings, the inner side of the clamp assembly comprising flat aligning plates. Short cylinders of non-conductive inert material, bearing seals on each face and dry gas inlet/ozone outlet ports, fit concentrically around the inner tube and are clamped between the surfaces of clamping-plates. The ends of the dielectric tube fit inside sealing rings in the inner faces of the short cylinders. The invention also includes an extension coupling which allows the mounting of two or more dielectric tubes in series on a single metal tube.

Abstract translation: 用于通过电晕放电产生臭氧的独立和自支撑电池，其基本上由两个开放式直管组成。 内金属管用作第一电极，并且被流过其芯的流体冷却。 外部玻璃或陶瓷管同心地围绕并短于内管，在其外表面上承载第二电极，并且通过其流体流过其外表面而被冷却。 内金属管用作支撑柱，其上安装和对准所有其它部件。 它在其每个端部附近带有一个轴环，并且穿过每个轴环夹紧着承载冷却剂密封件和配件的外部端部件，夹具组件的内侧包括平的对准板。 不导电惰性材料的短圆柱体，每个表面上的轴承密封件和干燥气体入口/臭氧出口端口均匀地配合在内管周围并夹紧在夹紧板的表面之间。 电介质管的端部装配在短气缸内表面的密封环内。 本发明还包括延伸耦合，其允许将两个或更多个电介质管串联安装在单个金属管上。

公开(公告)号：US4970056A

公开(公告)日：1990-11-13

申请号：US298077

申请日：1989-01-18

Applicant: Robert D. Wooten ,  John C. Egermeier

Inventor： Robert D. Wooten ,  John C. Egermeier

IPC: C01B13/11 ,  H01T23/00

CPC classification number: C01B13/11 ,  C01B2201/12 ,  C01B2201/34 ,  C01B2201/74 ,  Y10S422/907

Abstract: An ozone generating cell which utilizes a quartz dielectric for providing high purity ozone. The quarts dielectric is cemented to one of the electrodes of the cell, and is then ground to a desired dimension.

Abstract translation: 一种利用石英电介质提供高纯度臭氧的臭氧发生电池。 石英电介质胶合到电池的一个电极，然后研磨成所需的尺寸。

公开(公告)号：US4737885A

公开(公告)日：1988-04-12

申请号：US821919

申请日：1986-01-21

Applicant: Kensuke Akutsu

Inventor： Kensuke Akutsu

IPC: B01J19/08 ,  C01B13/11 ,  H05H1/48 ,  H05H1/24

CPC classification number: B01J19/088 ,  C01B13/11 ,  H05H1/48 ,  C01B2201/22 ,  C01B2201/24 ,  C01B2201/32 ,  C01B2201/34 ,  Y10S422/907

Abstract: A plasma generator including an excitation electrode and an opposite electrode confronting the excitation electrode such that plasma is generated upon impression of a high voltage between the excitation electrode and the opposite electrode. The plasma generator further includes granular material which is at least partially composed of dielectric grains and is provided between the excitation electrode and the opposite electrode.

Abstract translation: 一种等离子体发生器，其包括激励电极和面对激励电极的相对电极，使得在激励电极和相对电极之间的高电压压印时产生等离子体。 等离子体发生器还包括至少部分地由电介质晶粒组成并且设置在激励电极和相对电极之间的颗粒材料。

公开(公告)号：US4417966A

公开(公告)日：1983-11-29

申请号：US320497

申请日：1981-11-12

Applicant: Ralf Krauss ,  Rainer Koehne

Inventor： Ralf Krauss ,  Rainer Koehne

IPC: C01B13/11 ,  H01T19/00 ,  C01B13/10

CPC classification number: H01T19/00 ,  C01B13/11 ,  C01B2201/22 ,  C01B2201/34 ,  C01B2201/62

Abstract: An apparatus for producing ozone, comprising: a first electrode; a second, annular electrode surrounding the first electrode and spaced therefrom; a first tubular wall of electrically insulating material disposed between the electrodes; a first sealed glow discharge chamber surrounding one of the electrodes, formed at least in part by the tubular wall, and filled with a charge of an ionizable gas; an ozonization chamber disposed between the electrodes, formed at least in part by the tubular wall, and having an inlet for an oxygen charged medium and an outlet for the medium as ozone enriched; and, electrical conductors for connecting the electrodes to an electrical power source, whereby ionized gas in the glow discharge chamber forms a plasma electrode. The apparatus is preferably energized by applying an electrical potential between the electrodes in the form of voltage pulses at a frequency in the range of 10 to 60 KHz. In further embodiments, both electrodes are disposed in sealed glow discharge chambers filled with an ionizable gas, whereby the apparatus functions with at least two plasma electrodes.

Abstract translation: 一种用于生产臭氧的装置，包括：第一电极; 围绕所述第一电极并与其间隔开的第二环形电极; 设置在电极之间的电绝缘材料的第一管状壁; 围绕所述电极之一的第一密封辉光放电室，至少部分地由所述管状壁形成，并且填充有可电离气体的电荷; 设置在所述电极之间的臭氧化室，至少部分地由所述管状壁形成，并且具有用于充氧介质的入口和用于所述介质的作为富含臭氧的出口; 以及用于将电极连接到电源的电导体，由此辉光放电室中的电离气体形成等离子体电极。 优选通过以10至60KHz的频率以电压脉冲的形式在电极之间施加电势来激励该装置。 在另外的实施例中，两个电极设置在填充有可电离气体的密封辉光放电室中，由此该装置与至少两个等离子体电极起作用。

公开(公告)号：US4159971A

公开(公告)日：1979-07-03

申请号：US764219

申请日：1977-01-31

Applicant: Arthur Gneupel

Inventor： Arthur Gneupel

IPC: C01B13/11 ,  H01T23/00

CPC classification number: C01B13/11 ,  H01T23/00 ,  C01B2201/14 ,  C01B2201/22 ,  C01B2201/24 ,  C01B2201/32 ,  C01B2201/34

Abstract: A substantially tubular-shaped ozone generator embodying an inner electrode, a coaxial outer electrode surrounding the inner electrode and a tube member formed of dielectric material arranged between the inner electrode and the outer electrode. Within the tube member formed of dielectric material there is arranged a substantially cylindrical core provided at its outer surface with one or a number of substantially helically-shaped grooves extending in the axial direction of the core and forming a throughpass channel for the medium to be ozonized and the ozone which is generated.

Abstract translation: 一个体积为管状的臭氧发生器，其包括内部电极，围绕内部电极的同轴外部电极和由内部电极和外部电极之间布置的电介质材料形成的管件。 在由电介质材料形成的管构件中，布置有基本上圆柱形的芯，其在其外表面处设置有沿芯的轴向方向延伸的一个或多个基本上为螺旋状的凹槽，并形成用于介质被臭化的通道 和产生的臭氧。

公开(公告)号：US4049707A

公开(公告)日：1977-09-20

申请号：US659929

申请日：1976-02-20

Applicant: Joseph William Harter ,  Stuart Wallace Beitzel

Inventor： Joseph William Harter ,  Stuart Wallace Beitzel

IPC: B01J19/08 ,  C01B13/11 ,  H01T19/00

CPC classification number: H01T19/00 ,  B01J19/088 ,  C01B13/11 ,  B01J2219/0849 ,  C01B2201/12 ,  C01B2201/34

Abstract: An effective, efficient apparatus for treating a fluid by electron emission or corona discharge having a prolonged useful life can be constructed so as to include a first electrode, a composite dielectric structure located along the side of and spaced from the first electrode so as to define a gap between the first electrode and the dielectric structure and a second electrode. In such a structure preferably the gap is closed off by a flexible seal permitting the thickness of the gap to be adjusted; preferably this thickness is related to the operating parameters of the equipment used to power the apparatus and to the characteristics of the product or products produced in the apparatus. Preferably the dielectric structure consists of at least one layer of a first dielectric material including overlapping flat plate-like particles of an inert dielectric material located directly against the second electrode. The dielectric structure should be free from any voids and there should be no voids of any type between it and the second electrode. Preferably the surfaces of the first electrode and of the dielectric structure exposed to the gap are coated with an inherent coating of a material which either catalyzes the formation of a desired reaction product within said apparatus or acts as a reverse catalyst to minimize the decomposition of such a product. A preferred apparatus embodying the invention is intended to be utilized in the production of ozone.

Abstract translation: 可以构造一种用于通过具有延长的使用寿命的电子发射或电晕放电来处理流体的有效，高效的装置，以便包括第一电极，沿着第一电极的侧面并与第一电极间隔开的复合电介质结构，以便限定 第一电极和电介质结构之间的间隙和第二电极。 在这样的结构中，优选地，间隙通过柔性密封封闭，允许间隙的厚度被调节; 优选地，该厚度与用于为设备供电的设备的操作参数以及设备中产生的产品或产品的特性相关。 优选地，电介质结构由至少一层第一电介质材料组成，包括直接位于第二电极上的惰性介电材料的重叠平板状颗粒。 电介质结构应无空隙，在其与第二电极之间不应有任何类型的空隙。 优选地，暴露于间隙的第一电极和电介质结构的表面涂覆有材料的固有涂层，其可以催化在所述装置内形成所需反应产物或用作反向催化剂以最小化这种分解 一个产品。 实施本发明的优选装置旨在用于生产臭氧。