Abstract:
The instant invention relates to the use of water-soluble polymers comprising structural elements of the formula 1 wherein each R is independently H or C1-5-alkyl; X is H, an alkaline or earth alkaline metal or a quarternary ammonium group; R1 is H or C1-18-alkyl; and R2 is C1-18-alkyl; and wherein the alkyl groups represented by R1 and R2 may carry a hydroxy or amino substituent; and, if desired, a minor proportion of structural elements of the formula 2 wherein R, R1, R2 and X may have the meaning as above, and Alk is a C1-C5-alkylene chain, as additives for inhibiting the formation of gas hydrates in connection with hydrocarbon production and transportation.
Abstract:
A method and system are described for heating natural gas in a station, such as a City Gate station. Natural gas from the field is generally transported via supply line at high pressure to the various distribution networks necessary for delivering the gas. However, before the natural gas can enter these distribution networks its pressure must be reduced to a usable level. City Gate stations employing pressure reducing (JT) valves are usually built for this purpose. The present invention provides a system and method for heating the natural gas, without combustion of the natural gas, by relying on the pre-existing pressure of the gas in the supply line along with particular equipment to provide heat to the gas passing through the station.
Abstract:
The process for slowing the growth and/or agglomeration of hydrates in a fluid comprising water and gases comprises adding gas hydrate growth and/or agglomeration inhibitors comprising an essentially water soluble polymer, characterized by a total number of rotational degrees of freedom per statistical repeat unit RDFTm of over 9, preferably over 10, and a degree of polymerization DP of a statistical repeat unit in the range 18/RDFTm to 200,000, preferably in the range 20/RDFTm to 100,000. The growth and/or agglomeration inhibitor(s) is/are generally incorporated into the fluid to be treated in a concentration of 0.05% to 5% by weight with respect to the amount of water in the medium.
Abstract:
Novel maleimide copolymers have at least two monomeric units, a maleimide unit and a vinyl unit having a pendant group, the pendant group having two to twenty-one carbon atoms, at least one nitrogen atom and at least one oxygen atom. The copolymer has an average molecular weight between about 1,000 and about 6,000,000. Preferred maleimide copolymers include acrylamide/maleimide copolymers, N-vinyl amide/maleimide copolymers, vinyl lactam/maleimide copolymers, alkenyl cyclic imino ether/maleimide copolymers, and acryloylamide/maleimide copolymers. The substantially water soluble maleimide copolymers are useful for inhibiting the formation of clathrate hydrates in a fluid having hydrate-forming constituents by reducing the rate of nucleation, growth, and/or agglomeration of gas hydrate crystals in a petroleum fluid stream, thereby inhibiting the formation of a hydrate blockage in the pipe conveying the petroleum fluid stream. The inhibitor can be used conveniently at low concentrations, for example in the range of from about 0.01% to about 5% by weight of the water present in the oil or gas stream, to effectively treat a petroleum fluid having a water phase.
Abstract:
A method includes providing a length of pipeline that has a housing defining a central bore extending the length of the pipe and a space formed within the housing and extending the length of the pipe. At least one condition within the space is continuously monitored within the space to detect in real time if a change in the housing occurs.
Abstract:
The present invention relates to a heater suitable for heating a flow of natural gas. There is provided a heater (1) suitable for heating a flow of natural gas, comprising a vessel (2) containing a heat transfer fluid, a heat source tube (3) passing through the vessel and being at least partially immersed in the heat transfer fluid, the heat source tube (3) being suppliable with heated gas to allow the heated gas to flow along the heat source tube (3) to evaporate the heat transfer fluid and at least one heat exchanger being connectable to a source of second fluid (9) to be heated, the heat exchanger being arranged so that the second fluid can be heated by the evaporated heat transfer fluid.
Abstract:
Method for dewatering, pressure testing, hydrotreating, suppressing methane hydrate formation and suppressing solution freezing point in pipeline operations have been disclosed, where the solution used in the operations includes an effective amount of a metal formate salt. The metal formate salt solutions have a low viscosity, have a high density, have a low metals corrosivity, are non-volatile, have a low solubility in hydrocarbons, are readily biodegradable, have a low toxicity, are non-hazardous, have a low environmental impact, have a freezing point depression property forming water/formate eutectic point mixtures, and have a water-structuring and water activity modification property.
Abstract:
The present invention relates to a method for reducing gas hydrate adhesion to the interior surface of a conduit and associated equipment transporting or processing a fluid stream in oil and gas exploration and production, petroleum refining and/or petrochemistry, by providing the conduit interior surface with a coating layer exhibiting a static contact angle of the sessile water drop on the coating layer in air higher than 75° at ambient air conditions, as measured according to ASTM D7334-08, wherein said coating layer comprises diamond like carbon (DLC) comprising fractions of one or more components selected from the group consisting of silicon (Si), oxygen (O) and fluor (F).
Abstract:
A gelled composition for pipeline, flowline, pipeline jumper or flowline jumper dewatering or preventing ingress of seawater into open pipeline systems or components during tie-in operations of jumpers or additional pipe, valving, manifolds, subsea pipeline architecture or flow conduits operations is disclosed, where the composition includes a concentrated metal formate solution and a hydratable polymer. The gelled formate compositions have improved dewatering properties with 100% or 360 pipe coverage. The gelled formate compositions have can also be reused by breaking and reformulation.