Thermally Stable IR-Transmitting Chalcogenide Glass
    24.
    发明申请
    Thermally Stable IR-Transmitting Chalcogenide Glass 有权
    热稳定的红外发射硫族化物玻璃

    公开(公告)号:US20100326136A1

    公开(公告)日:2010-12-30

    申请号:US12818185

    申请日:2010-06-18

    CPC classification number: C03B37/01265 C03B2201/86 C03C3/321 C03C13/043

    Abstract: A thermally stable chalcogenide glass, a process for making the same, and an optical fiber drawn therefrom are provided. A chalcogenide glass having the composition Ge(5−y)As(32−x)Se(59+x)Te(4+y) (0≦y≦1 and 0≦x≦2) is substantially free from crystallization when it is heated past the glass transition temperature Tg or drawn into optical fibers. A process for making the thermally stable chalcogenide glass includes purifying the components to remove oxides and scattering centers, batching the components in a preprocessed distillation ampoule, gettering oxygen impurities from the mixture, and heating the components to form a glass melt. An optical fiber formed from the chalcogenide glass is substantially free from crystallization and exhibits low signal loss in the near-infrared region, particularly at wavelengths of about 1.55 μm.

    Abstract translation: 提供了热稳定的硫族化物玻璃,其制造方法和从其中提取的光纤。 具有Ge(5-y)As(32-x)Se(59 + x)Te(4 + y)(0≦̸ y≦̸ 1和0≦̸ x≦̸ 2)组成的硫族化物玻璃基本上没有结晶 被加热超过玻璃化转变温度Tg或拉制成光纤。 制造热稳定的硫族化物玻璃的方法包括纯化组分以除去氧化物和散射中心,将组分在预处理的蒸馏安瓿中进行配料,从混合物中吸收氧杂质,并加热组分以形成玻璃熔体。 由硫族化物玻璃形成的光纤基本上没有结晶,并且在近红外区域特别是在约1.55μm的波长下表现出低信号损失。

    Microstructured Optical Fiber Draw Method with In-Situ Vacuum Assisted Preform Consolidation
    25.
    发明申请
    Microstructured Optical Fiber Draw Method with In-Situ Vacuum Assisted Preform Consolidation 审中-公开
    微结构光纤拉丝方法与原位真空辅助预成型固结

    公开(公告)号:US20100303429A1

    公开(公告)日:2010-12-02

    申请号:US12471668

    申请日:2009-05-26

    Abstract: A method and apparatus for making a substantially void-free microstructured optical fiber using a one-step process is provided. A preform for the optical fiber is prepared, comprising an outer jacket made of solid glass, a cladding having a plurality of microtubes and/or microcanes arranged in a desired pattern within the jacket, and a core which may be solid or hollow, with the cladding and the core extending above the top of the outer jacket. The thus-prepared preform is placed into a fiber draw tower. As the fiber is drawn, negative gas pressure is applied to draw the canes together and consolidate the interfacial voids between the canes while positive gas pressure is applied to the preform to keep the holes of the microcanes open during the fiber drawing. The apparatus includes a jig having support tubes that are connected to a vacuum pump for application of the negative gas pressure and a vent tube connected to a gas supply for application of the positive gas pressure. The interfaces between the support tube and the outer jacket and between the vent tube and the cladding are sealed to ensure that the appropriate application of negative or positive pressure during the draw step is obtained. The preforms according to the present invention can include one or more components fabricated from specialty non-silica glass.

    Abstract translation: 提供了使用一步法制造基本上无空隙的微结构光纤的方法和装置。 制备用于光纤的预制件,其包括由实心玻璃制成的外护套,具有多个微管和/或以夹套内所需图案排列的微孔的包层,以及可为实心或中空的芯, 包层,并且芯部延伸到外护套的顶部之上。 将如此制备的预成型件放入纤维拉制塔中。 当纤维被拉伸时,施加负气体压力以一起拉伸所述手杖,并且在将预压件施加正气体压力的同时巩固所述手杖之间的界面空隙,以在纤维拉伸期间保持微孔的孔打开。 该装置包括具有连接到用于施加负气体压力的真空泵的支撑管的夹具和连接到用于施加正气体压力的气体供应的通气管。 支撑管和外护套之间以及通气管和包层之间的界面被密封,以确保在拉伸步骤期间适当地施加负压或正压。 根据本发明的预成型件可以包括由特殊非石英玻璃制成的一个或多个部件。

    Method for fabricating IR-transmitting chalcogenide glass fiber
    26.
    发明授权
    Method for fabricating IR-transmitting chalcogenide glass fiber 有权
    制造红外透射硫族化物玻璃纤维的方法

    公开(公告)号:US07844162B2

    公开(公告)日:2010-11-30

    申请号:US12491264

    申请日:2009-06-25

    CPC classification number: C03B37/01265 C03B2201/86 C03C3/321 C03C13/043

    Abstract: A thermally stable chalcogenide glass, a process for making the same, and an optical fiber drawn therefrom are provided. A chalcogenide glass having the composition Ge(5−y)As(32−x)Se(59+x)Te(4+y) (0≦y≦1 and 0≦x≦2) is substantially free from crystallization when it is heated past the glass transition temperature Tg or drawn into optical fibers. A process for making the thermally stable chalcogenide glass includes purifying the components to remove oxides and scattering centers, batching the components in a preprocessed distillation ampoule, gettering oxygen impurities from the mixture, and heating the components to form a glass melt. An optical fiber formed from the chalcogenide glass is substantially free from crystallization and exhibits low signal loss in the near-infrared region, particularly at wavelengths of about 1.55 μm.

    Abstract translation: 提供了热稳定的硫族化物玻璃,其制造方法和从其中提取的光纤。 具有Ge(5-y)As(32-x)Se(59 + x)Te(4 + y)(0≦̸ y≦̸ 1和0≦̸ x≦̸ 2)组成的硫族化物玻璃基本上没有结晶 被加热超过玻璃化转变温度Tg或拉制成光纤。 制造热稳定的硫族化物玻璃的方法包括纯化组分以除去氧化物和散射中心,将组分在预处理的蒸馏安瓿中进行配料,从混合物中吸收氧杂质,并加热组分以形成玻璃熔体。 由硫族化物玻璃形成的光纤基本上没有结晶,并且在近红外区域特别是在约1.55μm的波长下表现出低信号损失。

    BARIUM COPPER SULFUR FLUORIDE TRANSPARENT CONDUCTIVE THIN FILMS AND BULK MATERIAL
    28.
    发明申请
    BARIUM COPPER SULFUR FLUORIDE TRANSPARENT CONDUCTIVE THIN FILMS AND BULK MATERIAL 失效
    铜铜硫化物透明导电薄膜和块状材料

    公开(公告)号:US20100072465A1

    公开(公告)日:2010-03-25

    申请号:US12250808

    申请日:2008-10-14

    Abstract: The present invention is generally directed to a bulk barium copper sulfur fluoride (BCSF) material made by combining Cu2S, BaS and BaF2, heating the ampoule between 400 and 550 ° C. for at least two hours, and then heating the ampoule at a temperature between 550 and 950 ° C. for at least two hours. The BCSF material may be doped with potassium, rubidium, or sodium. The present invention also provides for a BCSF transparent conductive thin film made by forming a sputter target by either hot pressing bulk BCSF or hot pressing Cu2S, BaS and BaF2 powders and sputtering a BCSF thin film from the target onto a substrate. The present invention is further directed to a p-type transparent conductive material comprising a thin film of BCSF on a substrate where the film has a conductivity of at least 1 S/cm. The substrate may be a plastic substrate, such as a polyethersulfone, polyethylene terephthalate, polyimide, or some other suitable plastic or polymeric substrate.

    Abstract translation: 本发明一般涉及通过组合Cu2S,BaS和BaF2制备的块状钡铜氟化硫(BCSF)材料,将安瓿在400和550℃之间加热至少2小时,然后在温度下加热安瓿 在550和950℃之间至少2小时。 BCSF材料可掺杂有钾,铷或钠。 本发明还提供了通过热压体BCSF或热压Cu2S,BaS和BaF2粉末形成溅射靶并将BCSF薄膜从靶溅射到衬底上而制成的BCSF透明导电薄膜。 本发明进一步涉及一种p型透明导电材料,其包括在衬底上的BCSF薄膜,其中该膜的导电率至少为1S / cm。 基底可以是塑料基底,例如聚醚砜,聚对苯二甲酸乙二醇酯,聚酰亚胺或一些其它合适的塑料或聚合物基材。

    Near-field optical microscope with infrared fiber probe
    30.
    发明授权
    Near-field optical microscope with infrared fiber probe 失效
    红外光纤探头近场光学显微镜

    公开(公告)号:US06285811B1

    公开(公告)日:2001-09-04

    申请号:US09267919

    申请日:1999-02-25

    CPC classification number: G01Q60/22 Y10S977/862

    Abstract: A near field optical microscope according to the present invention has (1) a single mode infrared optical fiber made from chalcogenide glass, chalcohalide glass, or a combination thereof, having a probe end adapted as a probe for near field optical microscopy, and further adapted for positioning within a near optical field of a sample; (2) a source of infrared light; for illuminating the sample; (3) a detector of infrared light; for detecting infrared light reflected from, emitted by, or transmitted through the sample, where at least one of the source of infrared light and the detector of infrared light are optically coupled to a distal end of the single mode infrared optical fiber.

    Abstract translation: 根据本发明的近场光学显微镜具有(1)由硫族化物玻璃,卤化铝玻璃或其组合制成的单模红外光纤,其具有适于作为近场光学显微镜的探针的探针端,并且还适于 用于在样品的近光场内定位; (2)红外光源; 用于照亮样品; (3)红外光检测器; 用于检测从所述样品反射,发射或透射的红外光,其中所述红外光源和所述红外光检测器中的至少一个光学耦合到所述单模红外光纤的远端。

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