公开(公告)号：US07632775B2

公开(公告)日：2009-12-15

申请号：US10990616

申请日：2004-11-17

Applicant: Bing Zhou ,  Sukesh Parasher ,  Michael Rueter

Inventor： Bing Zhou ,  Sukesh Parasher ,  Michael Rueter

IPC: B01J25/00 ,  B01J23/40 ,  B01J23/42 ,  C22C38/00 ,  C22C5/04 ,  B01J31/00

CPC classification number: B01J35/0013 ,  B01J21/18 ,  B01J23/8906 ,  B01J37/0211 ,  B01J37/0219 ,  Y10S977/81

Abstract: Disclosed are nanoparticles formed from a plurality of two or more different components. The two or more components are dispersed using a dispersing agent such that the nanoparticles have a substantially uniform distribution of the two or more components. The dispersing agents can be poly functional small organic molecules, polymers, or oligomers, or salts of these. The molecules of the dispersing agent bind to the particle atoms to overcome like-component attractions, thereby allowing different and/or dissimilar components to form heterogeneous nanoparticles. In one embodiment, dissimilar components such as iron and platinum are complexed using the dispersing agent to form substantially uniform heterogeneous nanoparticles. Methods are also disclosed for making the multicomponent nanoparticles. The methods include forming suspensions of two or more components complexed with the dispersing agent molecules. The suspensions can also be deposited on a support material and/or anchored to the support.

Abstract translation: 公开了由多个两个或多个不同组分形成的纳米颗粒。 使用分散剂分散两种或更多种组分，使得纳米颗粒具有基本均匀的两种或多种组分的分布。 分散剂可以是多官能的小有机分子，聚合物或低聚物或它们的盐。 分散剂的分子与颗粒原子结合以克服相同分子的吸引力，从而允许不同的和/或不同的组分形成不均匀的纳米颗粒。 在一个实施方案中，使用分散剂使异种组分如铁和铂复合以形成基本均匀的非均相纳米颗粒。 还公开了制备多组分纳米颗粒的方法。 所述方法包括形成与分散剂分子络合的两种或多种组分的悬浮液。 悬浮液也可以沉积在支撑材料上和/或锚固到载体上。

公开(公告)号：US07534741B2

公开(公告)日：2009-05-19

申请号：US11673552

申请日：2007-02-09

Applicant: Zhihua Wu ,  Zhenhua Zhou ,  Michael Rueter ,  Bing Zhou

Inventor： Zhihua Wu ,  Zhenhua Zhou ,  Michael Rueter ,  Bing Zhou

IPC: B01J23/00 ,  B01J31/00 ,  C01B15/01

CPC classification number: C01B15/029 ,  B01J23/44 ,  B01J35/0013 ,  Y10S977/775

Abstract: Methods for manufacturing supported catalysts and the use of these catalysts in, e.g., the direct synthesis of hydrogen peroxide. The nanocatalyst particles are manufactured from catalyst atoms complexed with organic agent molecules (e.g., polyacrylic acid). The complexed catalyst atoms are heated to cause formation of the nanocatalyst particles. The temperature used to cause formation of the particles is typically greater than 30° C., preferably greater than 50° C, and more preferably greater than 70° C.

Abstract translation: 用于制造负载型催化剂的方法以及这些催化剂在例如直接合成过氧化氢中的用途。 纳米催化剂颗粒由与有机试剂分子（例如聚丙烯酸）络合的催化剂原子制备。 络合的催化剂原子被加热以引起纳米催化剂颗粒的形成。 用于引起颗粒形成的温度通常大于30℃，优选大于50℃，更优选大于70℃。

公开(公告)号：US20070219084A1

公开(公告)日：2007-09-20

申请号：US11378877

申请日：2006-03-17

Applicant: Sukesh Parasher ,  Cheng Zhang ,  Michael Rueter ,  Bing Zhou

Inventor： Sukesh Parasher ,  Cheng Zhang ,  Michael Rueter ,  Bing Zhou

IPC: B01J31/00 ,  B01F3/12 ,  B01F17/00

CPC classification number: B01J35/0013 ,  B01J13/0043 ,  B01J23/40 ,  B01J37/18 ,  B82Y30/00

Abstract: Metal-containing colloids are manufactured by reacting a plurality of metal ions and a plurality of organic agent molecules to form metal complexes in a mixture having a pH greater than about 4.25. The metal complexes are reduced for at least 0.5 hour to form stable colloidal nanoparticles. The extended reduction time improves the stability of the colloidal particles as compared to shorter reduction times. The stability of the colloidal particles allows for colloids with higher concentrations of metal to be formed. The concentration of metal in the colloid is preferably at least about 150 ppm by weight.

Abstract translation: 含金属胶体通过使多种金属离子和多种有机试剂分子反应，在pH大于约4.25的混合物中形成金属络合物来制造。 将金属络合物还原至少0.5小时以形成稳定的胶体纳米颗粒。 与较短的还原时间相比，延长的还原时间提高了胶体颗粒的稳定性。 胶体颗粒的稳定性允许形成具有较高浓度金属的胶体。 胶体中金属的浓度优选为至少约150ppm重量。

公开(公告)号：US07144565B2

公开(公告)日：2006-12-05

申请号：US10897493

申请日：2004-07-23

Applicant: Michael Rueter ,  Bing Zhou ,  Sukesh Parasher

Inventor： Michael Rueter ,  Bing Zhou ,  Sukesh Parasher

IPC: C01B15/029

CPC classification number: C01B15/029

Abstract: A process is disclosed for the direct catalytic production of aqueous solutions of hydrogen peroxide from hydrogen and oxygen in the presence of a small amount of one or more water soluble organic additives (about 0.1–10% by weight). Suitable catalysts include nanometer-sized noble metal catalytic crystal particles. The catalyst particles preferably have a controlled surface coordination number of 2 to increase the selectivity of hydrogen peroxide production. The water soluble additive(s) increases catalytic activity causing significant increases in the apparent first order reaction rate constant for the direct production of aqueous hydrogen peroxide.

Abstract translation: 公开了一种在少量一种或多种水溶性有机添加剂（约0.1-10重量％）存在下从氢气和氧气直接催化生产过氧化氢水溶液的方法。 合适的催化剂包括纳米级的贵金属催化晶体颗粒。 催化剂颗粒优选具有受控的表面配位数2，以增加过氧化氢生产的选择性。 水溶性添加剂增加催化活性，导致直接生产过氧化氢水溶液的表观一级反应速率常数显着增加。

公开(公告)号：US07105143B2

公开(公告)日：2006-09-12

申请号：US11211283

申请日：2005-08-25

Applicant: Michael Rueter

Inventor： Michael Rueter

IPC: C01B15/029

CPC classification number: C01B15/029

Abstract: An improved catalytic process for producing hydrogen peroxide directly by reaction of hydrogen and oxygen is disclosed. The process employs staged or sequential feeding of portions of the hydrogen feedstream into zones in the catalytic reactor in amounts sufficient to maintain an essentially constant and preferred ratio of oxygen to hydrogen at the inlet to each of the vessel's zones whereby high selectivity for hydrogen peroxide production is achieved and excess oxygen recycle requirements are minimized.

公开(公告)号：US07067103B2

公开(公告)日：2006-06-27

申请号：US10401351

申请日：2003-03-28

Applicant: Michael Rueter

Inventor： Michael Rueter

IPC: C01B15/029

CPC classification number: C01B15/029

Abstract: An improved catalytic process for producing hydrogen peroxide directly by reaction of hydrogen and oxygen is disclosed. The process employs staged or sequential feeding of portions of the hydrogen feedstream into zones in the catalytic reactor in amounts sufficient to maintain an essentially constant and preferred ratio of oxygen to hydrogen at the inlet to each of the vessel's zones whereby high selectivity for hydrogen peroxide production is achieved and excess oxygen recycle requirements are minimized.

Abstract translation: 公开了通过氢和氧的反应直接生产过氧化氢的改进的催化方法。 该方法使用部分氢原料流在催化反应器中进行分段或顺序进料，其量足以在每个容器区域的入口处保持基本上恒定且优选的氧与氢的比例，从而对过氧化氢产生的高选择性 并使过量的氧气回收要求最小化。

公开(公告)号：US07011807B2

公开(公告)日：2006-03-14

申请号：US10618808

申请日：2003-07-14

Applicant: Bing Zhou ,  Michael Rueter ,  Sukesh Parasher

Inventor： Bing Zhou ,  Michael Rueter ,  Sukesh Parasher

IPC: C01B15/029 ,  C07D301/12 ,  C07D301/03 ,  C07D301/04 ,  C10G45/44

CPC classification number: H01M4/926 ,  H01M4/921

Abstract: Supported reactive catalysts having a controlled coordination structure and methods for their production are disclosed. The supported catalysts of the present invention are useful for the preparation of hydrogen peroxide with high selectivity in addition to other chemical conversion reactions. The supported catalyst comprises catalyst particles having top or outer layer of atoms in which at least a portion of the atoms exhibit a controlled coordination number of 2. The catalyst and methods may be used for the concurrent in situ and ex situ conversion of organic compounds. In addition, a process is provided for catalytically producing hydrogen peroxide from hydrogen and oxygen feeds by contacting them with the catalysts of the invention and a suitable organic liquid solvent having a Solvent Selection Parameter (SSP) between 0.14×10−4 and 5.0×10−4.

Abstract translation: 公开了具有受控配位结构的负载型反应催化剂及其制备方法。 除了其它化学转化反应之外，本发明的负载型催化剂可用于制备具有高选择性的过氧化氢。 载体催化剂包含具有顶部或外层原子的催化剂颗粒，其中至少一部分原子表现出受控的配位数2.催化剂和方法可用于有机化合物的原位和非原位转化。 此外，提供了一种通过使它们与本发明的催化剂接触的氢气和氧气进料催化产生过氧化氢的方法以及溶剂选择参数（SSP）在0.14×10 -4之间的合适的有机液体溶剂， SUP>和5.0×10 -4。

公开(公告)号：US06908873B2

公开(公告)日：2005-06-21

申请号：US10326042

申请日：2002-12-20

Applicant: Bing Zhou ,  Michael Rueter

Inventor： Bing Zhou ,  Michael Rueter

IPC: B01J23/44 ,  B01J23/96 ,  B01J35/10 ,  B01J38/12 ,  B01J38/52 ,  B01J38/62 ,  B01J38/66 ,  B01J38/68 ,  B01J38/72 ,  C01B15/023 ,  B01J20/34 ,  B01J38/50 ,  B01J38/56

CPC classification number: B01J38/68 ,  B01J23/44 ,  B01J23/96 ,  B01J35/1014 ,  B01J35/1061 ,  B01J38/12 ,  B01J38/52 ,  B01J38/62 ,  B01J38/66 ,  B01J38/72 ,  C01B15/023 ,  Y02P20/584

Abstract: A method for regenerating spent supported metal catalysts comprising treating the spent catalyst with an organo-metallic complex forming agent having an ionization constant pK1 of at least 2.5. The catalyst activity is restored to an activity level near to or greater than the fresh catalyst. The regeneration method is particularly useful for regenerating spent palladium catalysts on an alumina support as utilized for the hydrogenation of ethyl anthraquinone (EAQ) in the production of hydrogen peroxide.

Abstract translation: 一种用于再生耗费的负载金属催化剂的方法，包括用具有至少2.5的电离常数pK <1的有机金属络合物形成剂处理废催化剂。 催化剂活性恢复到接近或大于新鲜催化剂的活性水平。 再生方法特别可用于在氧化铝载体上再生废钯催化剂，用于在过氧化氢生产中氢化乙基蒽醌（EAQ）。

公开(公告)号：US20050014635A1

公开(公告)日：2005-01-20

申请号：US10618808

申请日：2003-07-14

Applicant: Bing Zhou ,  Michael Rueter ,  Sukesh Parasher

Inventor： Bing Zhou ,  Michael Rueter ,  Sukesh Parasher

IPC: B01J31/00 ,  H01M4/92

CPC classification number: H01M4/926 ,  H01M4/921

Abstract: Supported reactive catalysts having a controlled coordination structure and methods for their production are disclosed. The supported catalysts of the present invention are useful for the preparation of hydrogen peroxide with high selectivity in addition to other chemical conversion reactions. The supported catalyst comprises catalyst particles having top or outer layer of atoms in which at least a portion of the atoms exhibit a controlled coordination number of 2. The catalyst and methods may be used for the concurrent in situ and ex situ conversion of organic compounds. In addition, a process is provided for catalytically producing hydrogen peroxide from hydrogen and oxygen feeds by contacting them with the catalysts of the invention and a suitable organic liquid solvent having a Solvent Selection Parameter (SSP) between 0.14×10−4 and 5.0×10−4.

Abstract translation: 公开了具有受控配位结构的负载型反应催化剂及其制备方法。 除了其它化学转化反应之外，本发明的负载型催化剂可用于制备具有高选择性的过氧化氢。 载体催化剂包含具有顶部或外层原子的催化剂颗粒，其中至少一部分原子表现出受控的配位数2.催化剂和方法可用于有机化合物的原位和非原位转化。 另外，提供了一种从氢气和氧气进料中催化产生过氧化氢的方法，它们与本发明的催化剂和具有溶剂选择参数（SSP）的合适的有机液体溶剂在0.14×10 -4和5.0×10 <-4>。

公开(公告)号：US06500969B1

公开(公告)日：2002-12-31

申请号：US10014068

申请日：2001-12-11

Applicant: Bing Zhou ,  Michael Rueter

Inventor： Bing Zhou ,  Michael Rueter

IPC: C07D30112

CPC classification number: C01B15/029 ,  C07D301/06 ,  C07D301/12 ,  Y02P20/582

Abstract: A process for producing oxidized organic chemical products from various organic chemical feedstocks utilizing as oxidant hydrogen peroxide (H2O2) produced by noble metal nanocatalysis with high selectivity at low hydrogen concentration. The organic chemical oxidation process step can optionally be carried out in situ concurrent with the production of hydrogen peroxide or in a two stage process. In the two stage process, the hydrogen peroxide intermediate is directly produced by noble metal nanocatalysis from hydrogen and oxygen feeds plus a suitable solvent in a first catalytic reaction step. An organic chemical feedstock and the hydrogen peroxide intermediate and solvent solution are fed into a second catalytic reactor to produce an oxidized organic chemical product.

Abstract translation: 一种利用贵金属纳米催化作用的氧化剂过氧化氢（H 2 O 2）在低氢浓度下以高选择性生产的各种有机化学原料生产氧化有机化学产品的方法。 有机化学氧化工艺步骤可以任选地与过氧化氢的生产同时进行或在两阶段工艺中进行。 在二阶段过程中，过氧化氢中间体在第一催化反应步骤中通过贵金属纳米催化从氢气和氧气加上合适的溶剂直接生产。 将有机化学原料和过氧化氢中间体和溶剂溶液进料到第二催化反应器中以产生氧化的有机化学产物。